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Stereochemistry

Stereochemistry Book
Author : Anil V. Karnik,Mohammed Hasan
Publisher : Elsevier
Release : 2021-07-21
ISBN : 012821063X
Language : En, Es, Fr & De

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Book Description :

Stereochemistry: The Three-Dimensional Chemistry draws on the knowledge of its expert authors, providing a systematic treatment on the fundamental aspects of stereochemistry, covering conformational aspects, configurational aspects, effects of bulkiness, stereoelectronic effects on properties of molecules, and the genesis of enantiomerism, among other topics. Visuals and exercises are included to consolidate the principles learned, and the contents are carefully structured to prepare readers for predicting and organizing reaction components to obtain desired stereochemical outcomes. This book is an indispensable guide for all those exploring stereochemistry within their work. The principles of stereochemistry are fundamental to understanding chemical behavior and can provide insights into a whole range of problems, from unusual selectivity and unexpected behaviors, to abnormally fast reactions and surprising biochemical preferences. However, understanding and exploring these 3D effects can be difficult within a 2D medium. This book has been designed to address this problem, providing foundational guidance on the principles and applications of stereochemistry that are fully supported by multimedia visuals. Combines foundational concepts and definitions with examples of stereochemistry in practice Highlights the conformational and configurational impact of atomic arrangement on chemical behavior Outlines methods of analysis Provides practical exercises and detailed multimedia visuals to support learning

Stereochemistry and Organic Reactions

Stereochemistry and Organic Reactions Book
Author : Dipak Kumar Mandal
Publisher : Academic Press
Release : 2021-04-21
ISBN : 0128240938
Language : En, Es, Fr & De

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Book Description :

Stereochemistry and Organic Reactions: Conformation, Configuration, Stereoelectronic Effects and Asymmetric Synthesis provides coverage on the stereochemistry of reactions of all mechanistic types, ranging from ionic, pericyclic and transition metal-catalyzed to radical and photochemical. Chapters cover acyclic molecules, cyclic molecules, the stereochemistry of organic reactions, the perturbation molecular orbital theory for the origin of stereoelectronic effects, and an introduction to the principles of stereoselectivity and hierarchical levels of asymmetric synthesis. Each chapter includes problems that reinforce main themes, making it valuable to students, teachers and researchers working in organic, biological and medicinal chemistry, as well as biologists, pharmacologists, polymer chemists and chemists. Presents a holistic and unified approach to stereochemical understanding and predictions, covering reactions of all mechanistic classes Includes two background chapters on perturbation theory and stereoselective principles, along with asymmetric designs Features novel rules and mnemonics to delineate product stereochemistry Includes up-to-date coverage with over 1300 selective references

Introduction to Stereochemistry

Introduction to Stereochemistry Book
Author : Torsten Schmiermund
Publisher : Springer Nature
Release : 2021-06-07
ISBN : 3658320354
Language : En, Es, Fr & De

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Book Description :

Conformal, diastereomers, rotamers, tautomers, anomers: The multitude of terms used in stereochemistry quickly makes this subfield of chemistry confusing. In addition, there are different nomenclatures and different forms of representation (Fischer projection, Haworth ring formula, Newman projection). This essential deals with basic static stereochemistry and gives an overview of the different isomeric forms and nomenclatures. It is thus both a help and a reference book. This Springer essential is a translation of the original German 1st edition essentials, Einführung in die Stereochemie by Torsten Schmiermund, published by Springer Fachmedien Wiesbaden GmbH, part of Springer Nature in 2019. The translation was done with the help of artificial intelligence (machine translation by the service DeepL.com). A subsequent human revision was done primarily in terms of content, so that the book will read stylistically differently from a conventional translation. Springer Nature works continuously to further the development of tools for the production of books and on the related technologies to support the authors.

Stereochemistry of Organic Compounds

Stereochemistry of Organic Compounds Book
Author : Ernest L. Eliel,Samuel H. Wilen
Publisher : John Wiley & Sons
Release : 1994-09-30
ISBN : 0471016705
Language : En, Es, Fr & De

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Book Description :

Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.

Introduction to Stereochemistry

Introduction to Stereochemistry Book
Author : Andrew Clark,Russ Kitson,Nimesh Mistry,Paul Taylor,Matthew Taylor,Michael Lloyd,Caroline Akamune
Publisher : Royal Society of Chemistry
Release : 2020-10-30
ISBN : 1839161825
Language : En, Es, Fr & De

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Book Description :

CHEMISTRY STUDENT GUIDES. GUIDED BY STUDENTS Why did the drug thalidomide cause birth defects? What is the chemical difference between sucrose and lactose in your food? Stereochemistry holds the answer and is essential to the understanding of the chemistry of life. Stereochemistry is an important concept that often causes confusion amongst students when they learn it for the first time. Unlike most other areas of chemistry, it requires the chemist to visualise molecules in 3D, which can be difficult. In this book we deal with tricky concepts like conformation and configuration, how to represent them accurately and how to use the correct terms to describe them in both organic and inorganic chemistry. We involved students in the writing process to ensure we deal with areas that you find difficult, in an understandable language. With problems designed to focus on common errors and misconceptions, real life examples, and practical hands-on exercises coupled with visualisation tips, our intention is to give you the tools to become confident in stererochemistry. Complementing mainstream organic textbooks, or self-study, this book is for anyone who has struggled with describing alkenes as E or Z, assigning R and S absolute configurations, drawing Newman projections or chair representations of cyclohexanes, axial chirality, understanding the stereochemistry of octahedral metal complexes and indeed explaining complexities observed in NMR spectra. Chemistry Student Guides are written with current students involved at every stage, guiding the books towards the most challenging aspects of the topic. Student co-authors for Introduction to Stereochemistry are Caroline Akamune, Michael Lloyd and Matthew Taylor.

Stereochemistry

Stereochemistry Book
Author : Ogden Bertrand Ramsay
Publisher : Unknown
Release : 1981
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Stereochemistry book written by Ogden Bertrand Ramsay, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Stereochemistry

Stereochemistry Book
Author : Giulio Natta,Mario Farina
Publisher : Unknown
Release : 1973
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Stereochemistry book written by Giulio Natta,Mario Farina, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Stereochemistry

Stereochemistry Book
Author : M. Nógrádi
Publisher : Elsevier
Release : 2013-10-22
ISBN : 1483278654
Language : En, Es, Fr & De

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Book Description :

Stereochemistry: Basic Concepts and Applications is a three-chapter text that introduces the basic principles and concepts of stereochemistry, as well as its application to organic chemistry application. Chapter 1 describes first the stereochemistry of the ground state, specifically the configuration and conformation of organic compounds, as well as the most important methods for its investigation. This chapter also deals with the kinetics of conformational changes and provides an overview of the so-called "applied stereochemistry". Chapter 2 focuses on the analysis of the internal motions of the molecules and of the corresponding activation energies. This chapter also examines the principles of intramolecular symmetry. Chapter 3 considers the stereochemical aspect of several enzymic processes and the stereoisomerism of monotonic polymers and inorganic complexes. This book will be of great value to organic chemists and organic chemistry graduate students.

Principles and Applications of Stereochemistry

Principles and Applications of Stereochemistry Book
Author : Michael North
Publisher : Routledge
Release : 2017-10-19
ISBN : 1351422057
Language : En, Es, Fr & De

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Book Description :

A thorough understanding of stereochemistry is essential for the comprehension of almost all aspects of modern organic chemistry. It is also of great significance in many biochemical and medicinal disciplines, since the stereoisomers of a compound can have dramatically different biological properties. This text explains how the different properties of stereoisomers of a compound arise, and what processes can be used to prepare and analyze stereoisomerically pure compounds. It also presents prominent coverage of the stereochemistry of inorganic and organometallic compounds, which is likely to increase in importance, as these compounds are used as symmetric catalysts in asymmetric synthesis. Modern stereochemical terminology is used throughout, although reference is also made to older terms which are still widely used. A set of problems at the end of each chapter aims to further the reader's understanding of how the content can be applied. The book is designed mainly as a textbook for undergraduate students and as a reference source for more advanced levels, but is also intended for academic and professional organic chemists.

Topics in Stereochemistry

Topics in Stereochemistry Book
Author : Norman L. Allinger,Ernest Ludwig Eliel,Scott E. Denmark
Publisher : Wiley-Interscience
Release : 1967
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

This volume is devoted entirely to inorganic and organometallic stereochemical subjects. Discusses the systematic notations that have been developed to satisfy the needs for a rational and systematic stereochemical nomenclature. Reviews the stereochemical aspects of the changes of bonding at carbon centers induced by metals, either catalytically or stoiciometrically. Also reviews the major achievements in current stereochemical research--the synthesis of asymmetric compounds mediated by transition metals. Discusses the structures of transition metal carbonyl clusters, summarizing recent progress in this expanding area and providing a semiquantitative rationalization of the structures for these clusters.

Organic Stereochemistry

Organic Stereochemistry Book
Author : Hua-Jie Zhu
Publisher : John Wiley & Sons
Release : 2015-08-10
ISBN : 3527338225
Language : En, Es, Fr & De

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Book Description :

Adopting a novel approach to the topic by combining theoretical knowledge and practical results, this book presents the most popular and useful computational and experimental methods applied for studying the stereochemistry of chemical reactions and compounds. The text is clearly divided into three sections on fundamentals, spectroscopic and computational techniques, and applications in organic synthesis. The first part provides a brief introduction to the field of chirality and stereochemistry, while the second part covers the different methodologies, such as optical rotation, electronic circular dichroism, vibrational circular dicroism, and Raman spectroscopy. The third section then goes on to describe selective examples in organic synthesis, classified by reaction type, i.e. enantioselective, chemoselective and stereoselective reactions. A final chapter on total synthesis of natural products rounds off the book. A valuable reference for researchers in academia and industry working in the field of organic synthesis, computational chemistry, spectroscopy or medicinal chemistry.

Stereochemistry

Stereochemistry Book
Author : David G. Morris
Publisher : Royal Society of Chemistry
Release : 2001
ISBN : 9780854046027
Language : En, Es, Fr & De

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Book Description :

This text for undergraduate students presents an introduction to stereochemistry--the study of the three-dimensional structure of molecules--with a focus on organic chemistry. In eight chapters, Morris (U. of Glasgow) discusses topics such as the hybridization, conformation, and configuration of simple molecules; chiral molecules; molecules with two or more stereogenic centers; stereoisomerism in cyclic structures; and substitution reactions at saturated carbon. Coverage extends to the use of NMR spectroscopy in stereochemistry. c. Book News Inc.

Principles and Applications of Stereochemistry

Principles and Applications of Stereochemistry Book
Author : Michael North
Publisher : CRC Press
Release : 1998-10-23
ISBN : 9780748739943
Language : En, Es, Fr & De

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Book Description :

A thorough understanding of stereochemistry is essential for the comprehension of almost all aspects of modern organic chemistry. It is also of great significance in many biochemical and medicinal disciplines, since the stereoisomers of a compound can have dramatically different biological properties. This text explains how the different properties of stereoisomers of a compound arise, and what processes can be used to prepare and analyze stereoisomerically pure compounds. It also presents prominent coverage of the stereochemistry of inorganic and organometallic compounds, which is likely to increase in importance, as these compounds are used as symmetric catalysts in asymmetric synthesis. Modern stereochemical terminology is used throughout, although reference is also made to older terms which are still widely used. A set of problems at the end of each chapter aims to further the reader's understanding of how the content can be applied. The book is designed mainly as a textbook for undergraduate students and as a reference source for more advanced levels, but is also intended for academic and professional organic chemists.

Topics in Stereochemistry

Topics in Stereochemistry Book
Author : Scott E. Denmark,Jay A. Siegel
Publisher : John Wiley & Sons
Release : 2006-04-27
ISBN : 0471785083
Language : En, Es, Fr & De

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Book Description :

Topics in Stereochemistry, previously edited by "the father ofstereochemistry" Ernest L. Eliel, is a longstanding, successfulseries covering the most important advances in the field. Themuch-anticipated Volume 25 includes chapters on the followingtopics: * Stereochemistry of Molecules in Inclusion Crystals * Torsional Motion of Stilbene-type Molecules in Crystals * Supramolecular Networks of Porphyrins * Homo- and Heterochirality in Crystals * Supramolecular Synthesis of 1D Chains and 2D Layers in HydrogenBond Networks of Ureas and 2-D Pyrimidinones * Chiral Auxiliaries Powerful for Both Enantioresolution andDetermination of Absolutely Stereochemistry by X-RayCrystallograph * Engineering Stereospecific Reactoins in Crystals: Synthesis ofCompounds with Adjacent Stereogenic Quaternary Centers byPhotodecarbonylation of Crystalline Ketones * The CH/ Hydrogen Bond: An Important Molecular Force inControlling the Crystal Conformation of Organic Compounds andThree-Dimensional Structure of Biopolymers * Stereoselective Thermal Solid-State Reactions * Crystal Structures and Functionalities of Platinum (II) ComplexesControlled by Various Intermolecular Interactions

Stereochemistry Fundamentals and Methods

Stereochemistry  Fundamentals and Methods Book
Author : Jean Jacques,Claude Gros,Simone Bourcier
Publisher : Unknown
Release : 1977
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Stereochemistry Fundamentals and Methods book written by Jean Jacques,Claude Gros,Simone Bourcier, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

The Stereochemistry of Electrophilic Aliphatic Substitution

The Stereochemistry of Electrophilic Aliphatic Substitution Book
Author : Laird Housel Gale
Publisher : Unknown
Release : 1959
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download The Stereochemistry of Electrophilic Aliphatic Substitution book written by Laird Housel Gale, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

The Stereochemistry of the Enolate Michael Addition

The Stereochemistry of the Enolate Michael Addition Book
Author : David Arthur Oare
Publisher : Unknown
Release : 1988
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download The Stereochemistry of the Enolate Michael Addition book written by David Arthur Oare, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Introduction to Stereochemistry

Introduction to Stereochemistry Book
Author : Kurt Mislow
Publisher : Courier Corporation
Release : 2012-06-11
ISBN : 0486151158
Language : En, Es, Fr & De

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Book Description :

Introductory text reviews molecular architecture, classifies stereoisomers according to symmetry properties and nature of barriers, and explores conceptual basis of asymmetric syntheses and kinetic resolutions. Exercises with answers. 1965 edition.

Topics in Stereochemistry

Topics in Stereochemistry Book
Author : Ernest L. Eliel,Samuel H. Wilen,Norman L. Allinger
Publisher : John Wiley & Sons
Release : 2009-09-17
ISBN : 0470147482
Language : En, Es, Fr & De

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Book Description :

This seminal series, first edited by Ernest Eliel, responsible for some of the major advances in stereochemistry and the winner of the ACS Priestley Medal in 1996, provides coverage of the major developments of the field of stereochemistry. The scope of this series is broadly defined to encompass all fields of chemical and biological sciences that are founded on molecular and supramolecular interactions. Insofar as chemical, physical, and biological properties are determined by molecular shape and structure, the importance of stereochemistry is fundamental to and consequential for all natural sciences. Topics in Stereochemistry serves as a multidisciplinary series that enriches all of chemistry. Aimed at advanced students, university professors and teachers as well as researchers in pharmaceutical, agricultural, biotechnological, polymer, materials, and fine chemical industries, Topics in Stereochemistry publishes definitive and scholarly reviews in stereochemistry and has long been recognized as the gold standard reference work in this field. Covering the effect of chirality on all aspects of molecular interaction from the fundamental physical chemical properties of molecules and their molecular physics to the application of chirality in new areas such as its applications in materials science, Topics in Stereochemistry explores a wide variety of properties, both physical and chemical of isomers with a view to their applications in a number of disciplines from biochemistry to materials science.

Dynamic Stereochemistry of Chiral Compounds

Dynamic Stereochemistry of Chiral Compounds Book
Author : Christian Wolf
Publisher : Royal Society of Chemistry
Release : 2008
ISBN : 0854042466
Language : En, Es, Fr & De

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Book Description :

A comprehensive overview of fundamental concepts of asymmetric synthesis along with in-depth discussion. Recent developments that address important synthetic challenges are presented and highlighted with hundreds of examples.