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Adsorption from Solution at the Solid liquid Interface

Adsorption from Solution at the Solid liquid Interface Book
Author : G. D. Parfitt,Colin H. Rochester,C. C. Rochester
Publisher : Unknown
Release : 1983
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Non-electrolytes. Adsorption of small molecules. Adsorption from mixtures of miscible liquids. Adsorption of nonionic surfactants. Adsorption of polymers. Electrolytes. Adsorption of small ions. Adsorption of ionic surfactants. Adsorption of dyes. Adsorption of polyelectrolytes from dilute solution.

Adsorption of Inorganics at Solid liquid Interfaces

Adsorption of Inorganics at Solid liquid Interfaces Book
Author : Marc A. Anderson,Alan J. Rubin
Publisher : Ann Arbor Science Publishers
Release : 1981
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Adsorption of Inorganics at Solid liquid Interfaces book written by Marc A. Anderson,Alan J. Rubin, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Adsorption at the Solid liquid Interface

Adsorption at the Solid liquid Interface Book
Author : Winifred Jean Lewis
Publisher : Unknown
Release : 1963
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Adsorption at the Solid liquid Interface book written by Winifred Jean Lewis, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Physical Adsorption at Solid liquid Interfaces

Physical Adsorption at Solid liquid Interfaces Book
Author : Rameshbhai Manibhai Patel
Publisher : Unknown
Release : 1970
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Physical Adsorption at Solid liquid Interfaces book written by Rameshbhai Manibhai Patel, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Adsorption From Solution

Adsorption From Solution Book
Author : R. H. Ottewill,C.H. Rochester,A.L. Smith
Publisher : Elsevier
Release : 2012-12-02
ISBN : 0323155642
Language : En, Es, Fr & De

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Book Description :

Adsorption From Solution discusses the significance of adsorption behavior in thermodynamic terms, with emphasis on the interplay between enthalpic and entropic contributions to the free energy. This book examines the role of simple models and of elementary thermodynamic and statistical mechanical arguments in relation to the concept of surface phase. Organized into 22 chapters, this book starts with an overview of the theoretical model for the solid/liquid interface. This text then proceeds with a discussion of the general thermodynamic treatment of adsorption from mixed solvents, which is designed to apply in situations where adsorbed species may be regarded as distinct from their bulk counterparts. Other chapters discuss the adsorption from solutions of various interfaces of liquid/gas, liquid/liquid, or liquid/solid. The final chapter deals with the roles of adsorption from solution in controlling other phenomena, such as liquid–liquid displacement, wetting, and the forces between colloidal particles. Physicists, chemists, and materials scientists will find this book extremely useful.

Fundamentals of Interface and Colloid Science

Fundamentals of Interface and Colloid Science Book
Author : J. Lyklema
Publisher : Elsevier
Release : 1995-10-17
ISBN : 9780080507125
Language : En, Es, Fr & De

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Book Description :

Interface and colloid science is an important, though often under-valued, branch of science. It has applications and ramifications in domains as disparate as agriculture, mineral dressing, oil recovery, chemical industry, biotechnology, medical science, and many more. Proper application of interface and colloid science requires factual knowledge and insight into the many basic laws of physics and chemistry upon which it is based. Fundamentals of Interface and Colloid Science is the first book to cover this field in the depth neccessary to be a valuable reference and an excellent textbook. From the beginning to the end of the book, systems of growing complexity are treated gradually. The presentation is particularly suited to emphasize that interfaces are not autonomous phases. As a rule, interfacial properties can be varied only by changing the adjoining phases, so that the properties of these bulk phases must be understood first. The text also recognizes common principles behind a variety of phenomena, and helps the reader to understand them and to develop and improve processes. The systematic treatment of the material in the book makes this clear, and makes the text itself an important contribution to the field. Systematic treatment of information An excellent addition to volume I Two chapters contributed by other experts in the field Uses a deductive approach to increase the order of complexity Written by a leading expert in the field Two chapters contributed by other outstanding scientists Uses a systematic and deductive approach First comprehensive review of the topic

Adsorption

Adsorption Book
Author : Jozsef Toth
Publisher : CRC Press
Release : 2002-05-10
ISBN : 0824744497
Language : En, Es, Fr & De

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Book Description :

This text offers an overview of the recent theoretical and practical results achieved in gas-solid, liquid-solid and gas-liquid adsorption research.

Understanding the Adsorption at Solid Liquid Interface and Its Consequences on Interfacial Phenomena

Understanding the Adsorption at Solid Liquid Interface and Its Consequences on Interfacial Phenomena Book
Author : Nishad Dhopatkar
Publisher : Unknown
Release : 2017
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Physical adsorption at solid-liquid interface is an effective way to dynamically alter the surface properties text/italics{in-situ} and is prevalent in biology, geoscience, biotechnology, catalysis, food processing, agriculture, textiles, coatings, adhesives and lubricants, and cosmetics Over the last century an extensive framework of the thermodynamics and kinetics of adsorption as well as the intermolecular forces that govern the physical interactions between the substrate, solute, and solvent has been established, helping elucidate the structure of adsorbates. However, there lacks an understanding of the connection between the local conformation of the adsorbed molecules and its influence on the macroscopic interfacial phenomena. In this research we have employed vibrational spectroscopy techniques namely the interface-selective non-linear sum frequency generation (SFG) and linear attenuated total reflectance Fourier transform infrared (ATR-FTIR) in conjugation with contact mechanics to develop the molecular level insights into macroscopic phenomena of wetting, adhesion, and sliding friction. We study the interfacial structure of small molecules (surfactants and solvents) as well as macromolecules adsorbed on model surfaces of sapphire (aluminum oxide) and silicone dioxide. Using SFG, we discovered a strongly coordinated ice-like water layer confined between two charged surfaces, under hydration pressures, formed by the adsorption of a cationic surfactant (cetyl trimethyl ammonium bromide, CTAB) on dissimilar hydrophobic surfaces (phenylethyl trichlorosilane, PETS self-assembled monolayer, and polydimethylsiloxane elastomer, PDMS). This strongly coordinated water structure forms past the surfactant concentration needed for a monolayer surface coverage and is observed to reduce the sliding friction. Correlating interface-selective spectroscopy with hydration forces, and their macroscopic manifestation on adhesion and friction requires us to reconsider how we understand water under confinement and its significance in more complicated interfacial processes prevalent in biology, chemistry, and engineering. To investigate the adsorption of a basic polymer (PMMA) on acidic surfaces in carbon tetrachloride (neutral), Chloroform (acidic), and acetone (basic) solvents, we used SFG and ATR-FTIR to build on to the established concept of acid-base interactions that explains limited adsorption from basic and acidic solutions compared to neutral solution due to competitive interactions. We show that besides the differences in adsorbed amount, chains adsorbed from an acidic solvent adopt a flat conformation with a much smaller ratio of segments of loops and tails to trains compared to those adsorbed from a neutral solvent. Surface interaction parameters alone cannot predict the differences in conformation of chains adsorbed from acidic or neutral solvents. Such differences in the static and dynamic conformations have consequences in understanding the exchange kinetics, colloidal stabilization, chromatographic separations, adhesion and friction, and stabilization of nanocomposites. The adsorption of polyelectrolytes driven by Coulombic interactions becomes complicated when mixed with oppositely charged surfactant which modulates the net charge and solubility of polyelectrolytes in water resulting in a characteristic bulk phase diagram. We have investigated the adsorption from pre-mixed solutions of a cationic polysaccharide (PQ10) and the anionic surfactant sodium dodecyl sulfate (SDS), on an amphoteric alumina surface using quartz crystal microbalance with dissipation (QCMD). By tuning the surface charge of the amphoteric alumina, we confirmed the importance of electrostatic interactions on the adsorption on a hydrophilic charged surface, a suggestion that was made earlier solely based on the measurements on negatively charged surfaces. We also directly correlate the bulk phase transitions at the interface adsorption by observing a maximum extent of adsorption on both negatively and positively charged surfaces from a solution corresponding to the maximum turbidity. Using the Voight based viscoelastic model, QCMD also provided information on the viscosity, shear modulus, and thickness of the adsorbed polymeric complex, findings of which were corroborated by underwater atomic force microscopy (AFM) measurements. Shifting gears from adsorption to understanding the polymer thin films surface structure in different environments, we used SFG to observe the surface restructuring of an amphiphilic glassy homopolymer poly(alpha-hydroxy-n-butyl acrylate, PHNB) from hydrophobic to aqueous environment. We observed relative changes in ordering of hydrophobic and hydroxyl pendant groups upon going from air to water at different temperatures showing their impact on wetting of the polymer surface observed by means of dynamic contact angles measurement.

Proteins at Solid Liquid Interfaces

Proteins at Solid Liquid Interfaces Book
Author : Philippe Déjardin
Publisher : Springer Science & Business Media
Release : 2006-09-28
ISBN : 3540326588
Language : En, Es, Fr & De

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Book Description :

This book opens with a description of fundamental aspects of protein adsorption to surfaces, a phenomenon that plays a key role in biotechnological applications, especially at solid-liquid interfaces. Presented here are methods for studying adsorption kinetics and conformational changes such as optical waveguide lightmode spectroscopy (OWLS). Also described are sensitive bench techniques for measuring the orientation and structure of proteins at solid-liquid interfaces, including total internal reflection ellipsometry (TIRE), dual polarisation interferometry (DPI) and time of flight - secondary ion mass spectrometry (TOF–SIMS). A model study of fibronectin at polymer surfaces is included, as are studies using microporous membranes and textiles with immobilized enzymes for large-scale applications. Biocompatibility, anti-fouling properties and surface modification to modulate the adsorption and activity of biomolecules are among the other topics addressed in this invaluable book.

Surface and Interface Science Volumes 7 and 8

Surface and Interface Science  Volumes 7 and 8 Book
Author : Klaus Wandelt
Publisher : John Wiley & Sons
Release : 2020-02-10
ISBN : 3527411593
Language : En, Es, Fr & De

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Book Description :

In ten volumes, this unique handbook covers all fundamental aspects of surface and interface science and offers a comprehensive overview of this research area for scientists working in the field, as well as an introduction for newcomers. Volume 1: Concepts and Methods Volume 2: Properties of Elemental Surfaces Volume 3: Properties of Composite Surfaces: Alloys, Compounds, Semiconductors Volume 4: Solid-Solid Interfaces and Thin Films Volume 5: Solid-Gas Interfaces I Volume 6: Solid-Gas Interfaces II Volume 7: Liquid and Biological Interfaces Volume 8: Interfacial Electrochemistry Volume 9: Applications of Surface Science I Volume 10: Applications of Surface Science II Content of Volumes 7 & 8: * Probing Liquid/Solid Interfaces at the Molecular Level * Structure and Dynamics of Liquid-Solid Interfaces * Adsorption of Biomolecules * Liquid Surfaces * Surfaces of Ionic Liquids * Superhydrophobicity * Cell Penetrating Peptides Targeting and Distorting Biological Membranes * Theory of Solid/Electrolyte Interfaces * Metal/Electrolyte Interfaces: An Atomic View * X-Ray Spectroscopy at Electro-Catalytic Interfaces * Fundamental Aspects of Electro-Catalysis * Non-Linear Processes at Solid/Liquid Interfaces

Verification of the Gibbs Adsorption Equation at the Solid liquid Interface and a Study of Electrochemically induced Spreading of Aqueous Solutions of Redox active Surfactant

Verification of the Gibbs Adsorption Equation at the Solid liquid Interface and a Study of Electrochemically induced Spreading of Aqueous Solutions of Redox active Surfactant Book
Author : Lei Yin
Publisher : Unknown
Release : 2002
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Verification of the Gibbs Adsorption Equation at the Solid liquid Interface and a Study of Electrochemically induced Spreading of Aqueous Solutions of Redox active Surfactant book written by Lei Yin, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Adsorption Science and Technology

Adsorption Science and Technology Book
Author : D. Do Duong
Publisher : World Scientific
Release : 2000
ISBN : 9789810242633
Language : En, Es, Fr & De

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Book Description :

This book is the proceedings of the second Pacific Basin Conference on Adsorption Science and Technology that was held May 14-18, 2000 in Brisbane, Australia.

Protein Adsorption at Solid liquid Interfaces

Protein Adsorption at Solid liquid Interfaces Book
Author : Gaurav Anand
Publisher : Unknown
Release : 2010
ISBN : 9781124351148
Language : En, Es, Fr & De

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Book Description :

Download Protein Adsorption at Solid liquid Interfaces book written by Gaurav Anand, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Solid Liquid Interfaces

Solid Liquid Interfaces Book
Author : Klaus Wandelt,Stephen Thurgate
Publisher : Springer Science & Business Media
Release : 2003-07-01
ISBN : 3540448179
Language : En, Es, Fr & De

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Book Description :

Using combinations of in situ and ex situ experimental methods, fundamental and relevant phenomena such as adsorption and desorption of ions and molecules, restructuring of surfaces, thin film and nanocluster growth, and electrochemical reactions on the micrometer scale are addressed. The overview includes a wide range of experimental techniques and examples of solid-liquid interfaces and aims at stimulating an expansion of this important type of interface science.

Physical Adsorption

Physical Adsorption Book
Author : Jacques P. Fraissard,Curt W. Conner
Publisher : Springer Science & Business Media
Release : 1997
ISBN : 9780792345473
Language : En, Es, Fr & De

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Book Description :

The study of physical adsorption has economic and technical value, while continuing to present scientific challenges. During recent years three significant trends have become manifest: significant theoretical advances; instrumental developments allowing detailed characterization of materials, including microporous solids; and the realization that closer coupling of scientific and technological lines of enquiry can lead to both greater scientific understanding and better technology.

Surface Chemistry

Surface Chemistry Book
Author : J. J. Bikerman
Publisher : Elsevier
Release : 2013-09-03
ISBN : 1483274489
Language : En, Es, Fr & De

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Book Description :

Surface Chemistry Theory and Applications focuses on liquid-gas, liquid-liquid, solid-gas, solid-liquid, and solid-solid surfaces. The book first offers information on liquid-gas surfaces, including surface tension, measurement of surface tension, rate of capillarity rise, capillary attraction, bubble pressure and pore size, and surface tension and temperature. The text then ponders on liquid-liquid and solid-gas surfaces. Discussions focus on surface energy of solids, surface roughness and cleanness, adsorption of gases and vapors, adsorption hysteresis, interfacial tension, and interfacial tension in multicomponent systems. The manuscript takes a look at solid-liquid surfaces, as well as stagnant layers at solid-liquid interfaces, heat transfer, surface roughness or electrodes, adsorption of liquids heat of wetting, and thin metal films condensed from vapor. The text also examines solid-liquid-gas and solid-liquid-liquid surfaces and electric surface phenomena. The book is a vital source of information for readers interested in surface chemistry.

Kinetics of Surfactant Adsorption at the Solid liquid Interface

Kinetics of Surfactant Adsorption at the Solid liquid Interface Book
Author : Thomas Daniel Curwen
Publisher : Unknown
Release : 2006
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Kinetics of Surfactant Adsorption at the Solid liquid Interface book written by Thomas Daniel Curwen, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.