Polymer Electrolytes

Book Description :

A comprehensive overview of the main characterization techniques of polymer electrolytes and their applications in electrochemical devices Polymer Electrolytes is a comprehensive and up-to-date guide to the characterization and applications of polymer electrolytes. The authors ? noted experts on the topic ? discuss the various characterization methods, including impedance spectroscopy and thermal characterization. The authors also provide information on the myriad applications of polymer electrolytes in electrochemical devices, lithium ion batteries, supercapacitors, solar cells and electrochromic windows. Over the past three decades, researchers have been developing new polymer electrolytes and assessed their application potential in electrochemical and electrical power generation, storage, and conversion systems. As a result, many new polymer electrolytes have been found, characterized, and applied in electrochemical and electrical devices. This important book: -Reviews polymer electrolytes, a key component in electrochemical power sources, and thus benefits scientists in both academia and industry -Provides an interdisciplinary resource spanning electrochemistry, physical chemistry, and energy applications -Contains detailed and comprehensive information on characterization and applications of polymer electrolytes Written for materials scientists, physical chemists, solid state chemists, electrochemists, and chemists in industry professions, Polymer Electrolytes is an essential resource that explores the key characterization techniques of polymer electrolytes and reveals how they are applied in electrochemical devices.

Book Description :

Polymer electrolytes are electrolytic materials that are widely used in batteries, fuel cells and other applications such as supercapacitors, photoelectrochemical and electrochromic devices. Polymer electrolytes: Fundamentals and applications provides an important review of this class of ionic conductors, their properties and applications. Part one reviews the various types of polymer electrolyte compounds, with chapters on ceramic polymer electrolytes, natural polymer-based polymer electrolytes, composite polymer electrolytes, lithium-doped hybrid polymer electrolytes, hybrid inorganic-organic polymer electrolytes. There are also chapters on ways of characterising and modelling polymer electrolytes. Part two discusses applications such as solar cells, supercapacitors, electrochromic and electrochemical devices, fuel cells and batteries. With its distinguished editors and international team of contributors, Polymer electrolytes: Fundamentals and applications is a standard reference for all those researching and using polymer electrolytes in such areas as battery and fuel cell technology for automotive and other applications. Provides an important review of this class of ionic conductors, their properties and applications in practical devices Explores categories of polymer electrolytes and conductivity measurements Features a comprehensive analysis of current developments in polymer electrolytes and highlights a new type of polymer electrolyte

Book Description :

Polymer Electrolytes for Energy Storage Devices, Volume I, offers a detailed explanation of recent progress and challenges in polymer electrolyte research for energy storage devices. The influence of these electrolyte properties on the performance of different energy storage devices is discussed in detail. Features: • Discusses a variety of energy storage systems and their workings and a detailed history of LIBs • Covers a wide range of polymer-based electrolytes including PVdF, PVdF-co-HFP, PAN, blend polymeric systems, composite polymeric systems, and polymer ionic liquid gel electrolytes • Provides a comprehensive review of biopolymer electrolytes for energy storage applications • Suitable for readers with experience in batteries as well as newcomers to the field This book will be invaluable to researchers and engineers working on the development of next-generation energy storage devices, including materials, chemical, electrical, and mechanical engineers, as well as those involved in related disciplines.

Book Description :

This thesis makes significant advances in the design of electrolytes and interfaces in electrochemical cells that utilize reactive metals as anodes. Such cells are of contemporary interest because they offer substantially higher charge storage capacity than state-of-the-art lithium-ion battery technology. Batteries based on metallic anodes are currently considered impractical and unsafe because recharge of the anode causes physical and chemical instabilities that produce dendritic deposition of the metal leading to catastrophic failure via thermal runaway. This thesis utilizes a combination of chemical synthesis, physical & electrochemical analysis, and materials theory to investigate structure, ion transport properties, and electrochemical behaviors of hybrid electrolytes and interfacial phases designed to prevent such instabilities. In particular, it demonstrates that relatively low-modulus electrolytes composed of cross-linked networks of polymer-grafted nanoparticles stabilize electrodeposition of reactive metals by multiple processes, including screening electrode electrolyte interactions at electrochemical interfaces and by regulating ion transport in tortuous nanopores. This discovery is significant because it overturns a longstanding perception in the field of nanoparticle-polymer hybrid electrolytes that only solid electrolytes with mechanical modulus higher than that of the metal electrode are able to stabilize electrodeposition of reactive metals.

Book Description :

Lithium (Li) deposition is a problem in Li batteries (LB) – both Li metal (LMB) and Li-ion (LIB) batteries – which limits their performance in terms of power and energy density. Two trends can be identified in the advancement of LBs concerning the problem of Li deposition: optimization of the existing system (the state-of-the-art LIBs) and further development of cell components such as electrolytes. This work addresses both approaches. In the first part, this study investigates Li deposition in LMB and LIBs. A novel method to study the Li-based transport mechanisms in LIBs is introduced. Later the kinetic deviations between anode and cathode as a consequence of aging and the relation of these deviations to the occurrence of Li-plating are discussed. In the second part, the applicability of PEO-based solid polymer electrolytes for LMBs to overcome the Li plating issue is investigated. The introduction of various interfacial interlayers at the cathode/electrolyte interphase was studied to improve the electrochemical stability of the cells. Cells with an in-situ electro-deposited interlayer showed the best cyclability.

Book Description :

Polymer and Ceramic Electrolytes for Energy Storage Devices features two volumes that focus on the most recent technological and scientific accomplishments in polymer, ceramic, and specialty electrolytes and their applications in lithium-ion batteries. These volumes cover the fundamentals in a logical and clear manner for students, as well as researchers from different disciplines, to follow. The set includes the following volumes: Polymer Electrolytes for Energy Storage Devices, Volume I, offers a detailed explanation of recent progress and challenges in polymer electrolyte research for energy storage devices. Ceramic and Specialty Electrolytes for Energy Storage Devices, Volume II, investigates recent progress and challenges in a wide range of ceramic solid and quasi-solid electrolytes and specialty electrolytes for energy storage devices. These volumes will be invaluable to researchers and engineers working on the development of next-generation energy storage devices, including materials and chemical engineers, as well as those involved in related disciplines.

Book Description :

For full market implementation of PEM fuel cells to become a reality, two main limiting technical issues must be overcome- cost and durability. This cutting-edge volume directly addresses the state-of-the-art advances in durability within every fuel cell stack component. [...] chapters on durability in the individual fuel cell components -- membranes, electrodes, diffusion media, and bipolar plates -- highlight specific degradation modes and mitigation strategies. The book also includes chapters which synthesize the component-related failure modes to examine experimental diagnostics, computational modeling, and laboratory protocol"--Back cover.

Book Description :

Ceramic and Specialty Electrolytes for Energy Storage Devices, Volume II, investigates recent progress and challenges in a wide range of ceramic solid and quasi-solid electrolytes and specialty electrolytes for energy storage devices. The influence of these electrolyte properties on the performance of different energy storage devices is discussed in detail. Features: • Offers a detailed outlook on the performance requirements and ion transportation mechanism in solid polymer electrolytes • Covers solid-state electrolytes based on oxides (perovskite, anti-perovskite) and sulfide-type ion conductor electrolytes for lithium-ion batteries followed by solid-state electrolytes based on NASICON and garnet-type ionic conductors • Discusses electrolytes employed for high-temperature lithium-ion batteries, low-temperature lithium-ion batteries, and magnesium-ion batteries • Describes sodium-ion batteries, transparent electrolytes for energy storage devices, non-platinum-based cathode electrocatalyst for direct methanol fuel cells, non-platinum-based anode electrocatalyst for direct methanol fuel cells, and ionic liquid-based electrolytes for supercapacitor applications • Suitable for readers with experience in batteries as well as newcomers to the field This book will be invaluable to researchers and engineers working on the development of next-generation energy storage devices, including materials and chemical engineers, as well as those involved in related disciplines.

Book Description :

Electroactive polymers have been the object of increasing academic and industrial interest and in the past ten to fifteen years substantial progress has been achieved in the development and the characterization of this important new class of conducting materials. These materials are usually classified in two large groups, according to the mode of their electric transport. One group includes polymers having transport almost exclusively of the ionic type and they are often called 'polymer electrolytes' or, in a broader way, 'polymer ionics'. The other group includes polymeric materials where the transport mechanism is mainly electronic in nature and which are commonly termed 'conducting polymers'. Ionically conducting polymers or polymer ionics may be typically described as polar macromolecular solids in which one or more of a wide range of salts has been dissolved. The most classic example is the combina tion of poly(ethylene oxide), PEO, and lithium salts, LiX. These PEO-LiX polymer ionics were first described and proposed for applications just over ten years ago. The practical relevance of these new materials was im mediately recognized and in the course of a few years the field expanded tremendously with the involvement of many academic and industrial lab oratories. Following this diversified research activity, the ionic transport mechanism in polymer ionics was soon established and this has led to the development of new host polymers of various types, new salts and advanced polymer architectures which have enabled room temperature conductivity to be raised by several orders of magnitude.

Book Description :

Functional Polymers for Metal-Ion Batteries Unique and useful book covering fundamental knowledge and practical applications of polymer materials in energy storage systems In Functional Polymers for Metal-Ion Batteries, the recent development and achievements of polymer-based materials are comprehensively analyzed in four directions, including electrode materials, binders, separators, and solid electrolytes, highlighting the working mechanisms, classification, design strategies, and practical applications of these polymer materials in mental-ion batteries. Specific sample topics covered in Functional Polymers for Metal-Ion Batteries include: Prominent advantages of various solid-state electrolytes, such as low flammability, easy processability, more tolerance to vibration, shock, and mechanical deformation Why and how functional polymers present opportunities to maximize energy density and pursue the sustainability of the battery industry How the application of functional polymers in metal-ion batteries helps enhance the high energy density of energy storage devices and reduce carbon footprint during production How development of functional separators could significantly lower the cost of battery manufacturing Providing a comprehensive understanding of the role of polymers in the whole configuration of metal-ion batteries from electrodes to electrolytes, Functional Polymers for Metal-Ion Batteries is an ideal resource for materials scientists, electrochemists, and polymer, solid state, and physical chemists who wish to understand the latest developments of this technology.

Book Description :

Electrochemical Polymer Electrolyte Membranes covers PEMs from fundamentals to applications, describing their structure, properties, characterization, synthesis, and use in electrochemical energy storage and solar energy conversion technologies. Featuring chapters authored by leading experts from academia and industry, this authoritative text: Discusses cutting-edge methodologies in PEM material selection and fabrication Points out important challenges in developing PEMs and recommends mitigation strategies to improve PEM performance Analyzes the current integration of PEMs with primary power devices and explores research trends for the next generation of PEMs Electrochemical Polymer Electrolyte Membranes provides a systematic overview of the state of the art of PEM development, making the book a beneficial resource for researchers, students, industrial professionals, and manufacturers.

Book Description :

Biopolymer Electrolytes: Fundamentals and Applications in Energy Storage provides the core fundamentals and applications for polyelectrolytes and their properties with a focus on biopolymer electrolytes. Increasing global energy and environmental challenges demand clean and sustainable energy sources to support the modern society. One of the feasible technologies is to use green energy and green materials in devices. Biopolymer electrolytes are one such green material and, hence, have enormous application potential in devices such as electrochemical cells and fuel cells. Features a stable of case studies throughout the book that underscore key concepts and applications Provides the core fundamentals and applications for polyelectrolytes and their properties Weaves the subject of biopolymer electrolytes across a broad range of disciplines, including chemistry, chemical engineering, materials science, environmental science, and pharmaceutical science

Book Description :

Highlighting solutions to more recently identified problems, this work focuses on the chemistry and technology involved in the functionalization of monomers, and the preparation and processing of polymers to serve specific material needs. It reflects the advances that have occurred in the field since the publication of the first edition.

Book Description :

This book provides a comprehensive overview of engineering nanostructures mediated by functional polymers in combination with optimal synthesis and processing techniques. The focus is on polymer-engineered nanostructures for advanced energy applications. It discusses a variety of polymers that function as precursors, templates, nano-reactors, surfactants, stabilizers, modifiers, dopants, and spacers for directing self-assembly, assisting organization, and templating growth of numerous diverse nanostructures. It also presents a wide range of polymer processing techniques that enable the efficient design and optimal fabrication of nanostructured polymers, inorganics, and organic–inorganic nanocomposites using in-situ hybridization and/or ex-situ recombination methodologies. Combining state-of-the-art knowledge from polymer-guided fabrication of advanced nanostructures and their unique properties, it especially highlights the new, cutting-edge breakthroughs, future horizons, and insights into such nanostructured materials in applications such as photovoltaics, fuel cells, thermoelectrics, piezoelectrics, ferroelectrics, batteries, supercapacitors, photocatalysis, and hydrogen generation and storage. It offers an instructive and approachable guide to polymer-engineered nanostructures for further development of advanced energy materials to meet ever-increasing global energy demands. Interdisciplinary and broad perspectives from internationally respected contributors ensure this book serves as a valuable reference source for scientists, students, and engineers working in polymer science, renewable energy materials, materials engineering, chemistry, physics, surface/interface science, and nanotechnology. It is also suitable as a textbook for universities, institutes, and industrial institutions.

Book Description :

Metal–organic frameworks (MOFs) are porous crystalline polymers constructed by metal sites and organic building blocks. Since the discovery of MOFs in the 1990s, they have received tremendous research attention for various applications due to their high surface area, controllable morphology, tunable chemical properties, and multifunctionalities, including MOFs as precursors and self-sacrificing templates for synthesizing metal oxides, heteroatom-doped carbons, metal-atoms encapsulated carbons, and others. Thus, awareness and knowledge about MOFs and their derived nanomaterials with conceptual understanding are essential for the advanced material community. This breakthrough new volume aims to explore down-to-earth applications in fields such as biomedical, environmental, energy, and electronics. This book provides an overview of the structural and fundamental properties, synthesis strategies, and versatile applications of MOFs and their derived nanomaterials. It gives an updated and comprehensive account of the research in the field of MOFs and their derived nanomaterials. Whether as a reference for industry professionals and nanotechnologists or for use in the classroom for graduate and postgraduate students, faculty members, and research and development specialists working in the area of inorganic chemistry, materials science, and chemical engineering, this is a must-have for any library.

Book Description :

Polymer-Based Nanocomposites for Energy and Environmental Applications provides a comprehensive and updated review of major innovations in the field of polymer-based nanocomposites for energy and environmental applications. It covers properties and applications, including the synthesis of polymer based nanocomposites from different sources and tactics on the efficacy and major challenges associated with successful scale-up fabrication. The chapters provide cutting-edge, up-to-date research findings on the use of polymer based nanocomposites in energy and environmental applications, while also detailing how to achieve material’s characteristics and significant enhancements in physical, chemical, mechanical and thermal properties. It is an essential reference for future research in polymer based nanocomposites as topics such as sustainable, recyclable and eco-friendly methods for highly innovative and applied materials are current topics of importance. Covers a wide range of research on polymer based nanocomposites Provides updates on the most relevant polymer based nanocomposites and their prodigious potential in the fields of energy and the environment Demonstrates systematic approaches and investigations from the design, synthesis, characterization and applications of polymer based nanocomposites Presents a useful reference and technical guide for university academics and postgraduate students (Masters and Ph.D.)

Book Description :

The 21 chapters in this book presents a comprehensive overview of flexible supercapacitors using engineering nanoarchitectures mediated by functional nanomaterials and polymers as electrodes, electrolytes, and separators, etc. for advanced energy applications. The various aspects of flexible supercapacitors, including capacitor electrochemistry, evaluating parameters, operating conditions, characterization techniques, different types of electrodes, electrolytes, and flexible substrates are covered. This is probably the first book of its type which systematically describes the recent developments and progress in flexible supercapacitor technology, and will be very helpful for generating new and innovative ideas in the field of energy storage material for wearable/flexible industry applications.

Book Description :

This Brief reviews contemporary research conducted in university and industry laboratories on thermal management in electrochemical energy storage systems (capacitors and batteries) that have been widely used as power sources in many practical applications, such as automobiles, hybrid transport, renewable energy installations, power backup and electronic devices. Placing a particular emphasis on supercapacitors, the authors discuss how supercapacitors, or ultra capacitors, are complementing and replacing, batteries because of their faster power delivery, longer life cycle and higher coulombic efficiency, while providing higher energy density than conventional electrolytic capacitors. Recent advances in both macro- and micro capacitor technologies are covered. The work facilitates systematic understanding of thermal transport in such devices that can help develop better power management systems.

Book Description :

The first book in the RSC Materials Monographs Series, Polymer Electrolytes brings together the latest research in this important subject. The emphasis is on practical materials and it includes an excellent classification of polymer electrolytes, a comprehensive look at material types and an important discussion of the commercial prospects. The text is designed for research workers from a variety of disciplines and looks at some of the history as well as the future of the subject, including reference to computer simulation. Overall, Polymer Electrolytes is an important review of the structural, physical and electrical properties of the materials which are competing for a place in the future energy generation, storage and distribution markets.

Book Description :

Download Light Scattering in Polymer Electrolytes book written by Staffan Schantz, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.