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Physical Properties And Applications Of Polymer Nanocomposites

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Physical Properties and Applications of Polymer Nanocomposites

Physical Properties and Applications of Polymer Nanocomposites Book
Author : S C Tjong,Y.-W. Mai
Publisher : Elsevier
Release : 2010-10-29
ISBN : 0857090240
Language : En, Es, Fr & De

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Book Description :

Polymer nanocomposites are polymer matrices reinforced with nano-scale fillers. This new class of composite materials has shown improved mechanical and physical properties. The latter include enhanced optical, electrical and dielectric properties. This important book begins by examining the characteristics of the main types of polymer nanocomposites, then reviews their diverse applications. Part one focuses on polymer/nanoparticle composites, their synthesis, optical properties and electrical conductivity. Part two describes the electrical, dielectric and thermal behaviour of polymer/nanoplatelet composites, whilst polymer/nanotube composites are the subject of Part three. The processing and industrial applications of these nanocomposite materials are discussed in Part four, including uses in fuel cells, bioimaging and sensors as well as the manufacture and applications of electrospun polymer nanocomposite fibers, nanostructured transition metal oxides, clay nanofiller/epoxy nanocomposites, hybrid epoxy-silica-rubber nanocomposites and other rubber-based nanocomposites. Polymer nanocomposites: Physical properties and applications is a valuable reference tool for both the research community and industry professionals wanting to learn about the these materials and their applications in such areas as fuel cell, sensor and biomedical technology. Examines the characteristics of the main types of polymer nanocomposites and reviews their diverse applications Comprehensively assesses polymer/nanoparticle composites exploring experimental techniques and data associated with the conductivity and dielectric characterization A specific section on polymer/nanotube composites features electrical and dielectric behaviour of polymer/carbon nanotube composites

Polymer Nanocomposites Containing Graphene

Polymer Nanocomposites Containing Graphene Book
Author : Mostafizur Rahaman,Lalatendu Nayak,Ibnelwaleed A. Hussein,Narayan Chandra Das
Publisher : Woodhead Publishing
Release : 2021-08-22
ISBN : 0128216409
Language : En, Es, Fr & De

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Book Description :

Polymer Nanocomposites Containing Graphene: Preparation, Properties and Applications provides detailed up-to-date information on the characterization, synthesis, processing, properties and application of these materials. Key topics that are covered in the book include: the methods of synthesis and preparation of graphene as well as different processes and methods of functionalization and modification of graphene for improving composite properties. The preparation techniques focus on which method is advantageous for getting improvements in properties along with their drawbacks. The structure and property relationships are also discussed in detail. The issues related to graphene dispersion in polymer matrices is also addressed as well as the use of graphene as reinforcement in thermoset resins. The different properties of the composites like mechanical, electrical, dielectric, thermal, rheological, morphology, spectroscopy, electronic, optical, and toxicity are reviewed from the geometrical and functional point of view. Applications cover electrical and electronic fields, flame and fire retardancy, structural, sensing and catalysis, membrane, in fuel cell and solar energy, hydrogen production, aerospace engineering, packaging, and biomedical/bioengineering fields. Up-to-date patents on graphene-polymer nanocomposites are also covered. Those working in graphene-based materials will benefit from the detailed knowledge presented in this book on graphene synthesis, composite preparation methods, and the related problems associated with them. The book will enable researchers to select the appropriate composite as per their respective field of application. Presents novel approaches for the preparation of graphene, its modification and nanocomposites with enhanced properties for state-of-the-art applications Special attention is given to how graphene is synthesized through different routes, their functionality, dispersion related matters and structural aspects controlling the composite properties for various applications All synthesis methodology and functionalization procedure for graphene is discussed

Polymer Nanocomposites

Polymer Nanocomposites Book
Author : Aravind Dasari,Zhong-Zhen Yu,Yiu-Wing Mai
Publisher : Springer
Release : 2016-06-28
ISBN : 1447168097
Language : En, Es, Fr & De

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Book Description :

This highlights ongoing research efforts on different aspects of polymer nanocomposites and explores their potentials to exhibit multi-functional properties. In this context, it addresses both fundamental and advanced concepts, while delineating the parameters and mechanisms responsible for these potentials. Aspects considered include embrittlement/toughness; wear/scratch behaviour; thermal stability and flame retardancy; barrier, electrical and thermal conductivity; and optical and magnetic properties. Further, the book was written as a coherent unit rather than a collection of chapters on different topics. As such, the results, analyses and discussions presented herein provide a guide for the development of a new class of multi-functional nanocomposites. Offering an invaluable resource for materials researchers and postgraduate students in the polymer composites field, they will also greatly benefit materials

Fundamentals Properties and Applications of Polymer Nanocomposites

Fundamentals  Properties  and Applications of Polymer Nanocomposites Book
Author : Joseph H. Koo
Publisher : Cambridge University Press
Release : 2016-10-31
ISBN : 1107029961
Language : En, Es, Fr & De

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Book Description :

Discusses polymer nanocomposites composed of a family of polymeric materials whose properties are capable of being tailored to meet specific applications.

Clay Polymer Nanocomposites

Clay Polymer Nanocomposites Book
Author : Khouloud Jlassi,Mohamed M. Chehimi,Sabu Thomas
Publisher : Elsevier
Release : 2017-07-26
ISBN : 0323461611
Language : En, Es, Fr & De

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Book Description :

Clay–Polymer Nanocomposites is a complete summary of the existing knowledge on this topic, from the basic concepts of synthesis and design to their applications in timely topics such as high-performance composites, environment, and energy issues. This book covers many aspects of synthesis such as in- situ polymerization within the interlamellar spacing of the clays or by reaction of pristine or pre-modified clays with reactive polymers and prepolymers. Indeed, nanocomposites can be prepared at industrial scale by melt mixing. Regardless the synthesis method, much is said in this book about the importance of theclay pre-modification step, which is demonstrated to be effective, on many occasions, in obtaining exfoliated nanocomposites. Clay–Polymer Nanocomposites reports the background to numerous characterization methods including solid state NMR, neutron scattering, diffraction and vibrational techniques as well as surface analytical methods, namely XPS, inverse gas chromatography and nitrogen adsorption to probe surface composition, wetting and textural/structural properties. Although not described in dedicated chapters, numerous X-ray diffraction patterns of clay–polymer nanocomposites and reference materials are displayed to account for the effects of intercalation and exfoliations of layered aluminosilicates. Finally, multiscale molecular simulation protocols are presenting for predicting morphologies and properties of nanostructured polymer systems with industrial relevance. As far as applications are concerned, Clay–Polymer Nanocomposites examines structural composites such as clay–epoxy and clay–biopolymers, the use of clay–polymer nanocomposites as reactive nanocomposite fillers, catalytic clay-(conductive) polymers and similar nanocomposites for the uptake of hazardous compounds or for controlled drug release, antibacterial applications, energy storage, and more. The most comprehensive coverage of the state of the art in clay–polymer nanocomposites, from synthesis and design to opportunities and applications Covers the various methods of characterization of clay–polymer nanocomposites - including spectroscopy, thermal analyses, and X-ray diffraction Includes a discussion of a range of application areas, including biomedicine, energy storage, biofouling resistance, and more

Properties and Applications of Polymer Nanocomposites

Properties and Applications of Polymer Nanocomposites Book
Author : Deba Kumar Tripathy,Bibhu Prasad Sahoo
Publisher : Springer
Release : 2017-05-07
ISBN : 3662535173
Language : En, Es, Fr & De

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Book Description :

The aim of the present edited book is to furnish scientific information about manufacturing, properties, and application of clay and carbon based polymer nanocomposites. It can be used as handbook for undergraduate and post graduate courses (for example material science and engineering, polymer science and engineering, rubber technology, manufacturing engineering, etc.) as well as as reference book for research fellows and professionals. Polymer nanocomposites have received outstanding importance in the present decade because of their broad range of high-performance applications in various areas of engineering and technology due to their special material properties. A great interest is dedicated to nanofiller based polymeric materials, which exhibit excellent enhancement in macroscopic material properties (mechanical, thermal, dynamic mechanical, electrical and many more) at very low filler contents and can therefore be used for the development of next-generation composite materials.

Conducting Polymer Based Nanocomposites

Conducting Polymer Based Nanocomposites Book
Author : Ayesha Kausar
Publisher : Elsevier
Release : 2021-04-22
ISBN : 0128224649
Language : En, Es, Fr & De

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Book Description :

Conducting Polymer-Based Nanocomposites: Fundamentals and Applications delivers an up-to-date overview on cutting-edge advancements in the field of nanocomposites derived from conjugated polymeric matrices. Design of conducting polymers and resultant nanocomposites has instigated significant addition in the field of modern nanoscience and technology. Recently, conducting polymer-based nanocomposites have attracted considerable academic and industrial research interest. The conductivity and physical properties of conjugated polymers have shown dramatic improvement with nanofiller addition. Appropriate fabrication strategies and the choice of a nanoreinforcement, along with a conducting matrix, may lead to enhanced physicochemical features and material performance. Substantial electrical conductivity, optical features, thermal stability, thermal conductivity, mechanical strength, and other physical properties of the conducting polymer-based nanocomposites have led to high-performance materials and high-tech devices and applications. This book begins with a widespread impression of state-of-the-art knowledge in indispensable features and processing of conducting polymer-based nanocomposites. It then discusses essential categories of conducting polymer-based nanocomposites such as polyaniline, polypyrrole, polythiophene, and derived nanomaterials. Subsequent sections of this book are related to the potential impact of conducting polymer-based nanocomposites in various technical fields. Significant application areas have been identified for anti-corrosion, EMI shielding, sensing, and energy device relevance. Finally, the book covers predictable challenges and future opportunities in the field of conjugated nanocomposites. Integrates the fundamentals of conducting polymers and a range of multifunctional applications Describes categories of essential conducting polymer-based nanocomposites for polyaniline, polypyrrole, polythiophene, and derivative materials Assimilates the significance of multifunctional nanostructured materials of nanocomposite nanofibers Portrays current and future demanding technological applications of conjugated polymer-based nanocomposites, including anti-corrosion coatings, EMI shielding, sensors, and energy production and storage devices

Metal Polymer Nanocomposites

Metal Polymer Nanocomposites Book
Author : Luigi Nicolais,Gianfranco Carotenuto
Publisher : John Wiley & Sons
Release : 2004-11-11
ISBN : 0471695424
Language : En, Es, Fr & De

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Book Description :

A unique guide to an essential area of nanoscience Interest in nano-sized metals has increased greatly due to theirspecial characteristics and suitability for a number of advancedapplications. As technology becomes more refined-including theability to effectively manipulate and stabilize metals at thenanoscale-these materials present ever-more workable solutions to agrowing range of problems. Metal-Polymer Nanocomposites provides the first guidesolely devoted to the unique properties and applications of thisessential area of nanoscience. It offers a truly multidisciplinaryapproach, making the text accessible to readers in physical,chemical, and materials science as well as areas such asengineering and topology. The thorough coverage includes: The chemical and physical properties of nano-sized metals Different approaches to the synthesis of metal-polymernanocomposites (MPN) Advanced characterization techniques and methods for study ofMPN Real-world applications, including color filters, polarizers,optical sensors, nonlinear optical devices, and more An extensive list of references on the topics covered A unique, cutting-edge resource for a vital area of nanosciencedevelopment, Metal-Polymer Nanocomposites is an invaluabletext for students and practitioners of materials science,engineering, polymer science, chemical engineering, electricalengineering, and optics.

Carbon based Polymer Nanocomposites for Environmental and Energy Applications

Carbon based Polymer Nanocomposites for Environmental and Energy Applications Book
Author : Ahmad Fauzi Ismail,Pei Sean Goh
Publisher : Elsevier
Release : 2018-03-28
ISBN : 0128135751
Language : En, Es, Fr & De

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Book Description :

Carbon-Based Polymer Nanocomposites for Environmental and Energy Applications provides the fundamental physico-chemical characterizations of recently explored carbon-based polymer nanocomposites, such as carbon nanotubes, graphene and its derivatives, nanodiamond, fullerenes and other nano-sized carbon allotropes. The book also covers the applications of carbon-based polymer nanocomposite in the environmental and energy fields. Topics range from the various approaches that have been explored and developed for the fabrication of carbon-based polymer nanocomposite, to their applications in tackling environmental and energy related issues. Provides a clear picture of the current state-of-the-art and future trends in carbon-based polymer nanomaterials Explains the interactions between nanofiller-polymer matrices and mechanisms related to applications in environmental pollution and energy shortage Includes computational and experimental studies of the physical and chemical properties of carbon-based polymer nanocomposites Features chapters written by world leading experts

Functional and Physical Properties of Polymer Nanocomposites

Functional and Physical Properties of Polymer Nanocomposites Book
Author : Aravind Dasari,James Njuguna
Publisher : John Wiley & Sons
Release : 2016-06-13
ISBN : 1118542320
Language : En, Es, Fr & De

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Book Description :

The first book to extensively cover nanoparticles, this addresses some of the key issues in nanocomposites. Polymer nanocomposites (polymers reinforced with nanoparticles), are of great interest due to their remarkable mechanical, thermal, chemical properties as well as optical, electronic, and magnetic applications Potential applications include automobile body parts, high-barrier packaging materials, flame-retardants, scratch-resistant composites, and biodegradable nanocomposites Combines basic theory as well as advanced and in-depth knowledge of these properties Broad audience includes researchers in Materials Science, Physics, Polymer Chemistry, and Engineering, and those in industry

Functional and Physical Properties of Polymer Nanocomposites

Functional and Physical Properties of Polymer Nanocomposites Book
Author : Aravind Dasari,James Njuguna
Publisher : John Wiley & Sons
Release : 2016-03-24
ISBN : 1118542290
Language : En, Es, Fr & De

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Book Description :

The first book to extensively cover nanoparticles, this addresses some of the key issues in nanocomposites. Polymer nanocomposites (polymers reinforced with nanoparticles), are of great interest due to their remarkable mechanical, thermal, chemical properties as well as optical, electronic, and magnetic applications Potential applications include automobile body parts, high-barrier packaging materials, flame-retardants, scratch-resistant composites, and biodegradable nanocomposites Combines basic theory as well as advanced and in-depth knowledge of these properties Broad audience includes researchers in Materials Science, Physics, Polymer Chemistry, and Engineering, and those in industry

Nanomaterials and Polymer Nanocomposites

Nanomaterials and Polymer Nanocomposites Book
Author : Niranjan Karak
Publisher : Elsevier
Release : 2018-10-24
ISBN : 0128146168
Language : En, Es, Fr & De

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Book Description :

Nanomaterials and Polymer Nanocomposites: Raw Materials to Applications brings together the most recent research in nanoparticles and polymer nanocomposites for a range of applications. The book's coverage is comprehensive, starting with synthesis techniques, then moving to characterization and applications of several different classes of nanomaterial and nanoparticle in nanocomposites. By presenting different nanomaterials, such as metal and metal oxides, clay and POSS, carbon nanotubes, cellulose and bio-based polymers in a structured manner, the book enables an efficient comparison of properties and capabilities for these advanced materials, making it relevant both for researchers in an academic environment and also industrial R&D. This book is particularly distinctive because it centers on the raw materials on which the nanocomposites are based, the biological properties of the range of materials discussed, and the environmental and economic considerations of different polymer systems. Presents a thorough, up-to-date review of the latest advances and developments in the field of nanomaterials and polymer nanocomposites, with a particular focus on raw materials Includes comprehensive coverage from historical backgrounds, synthesis techniques, characterization, and a detailed look at new and emerging applications for polymer nanocomposites Provides a range of different material classes, including metal and metal oxides, biopolymers, graphene and cellulose, among others

Liquid Crystal Polymer Nanocomposites

Liquid Crystal Polymer Nanocomposites Book
Author : P. M. Visakh,Artem Semkin,Zeynep Guven Ozdemir
Publisher : Woodhead Publishing
Release : 2022-01-21
ISBN : 0128221631
Language : En, Es, Fr & De

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Book Description :

Liquid Crystal Polymer Nanocomposites summarizes, in a comprehensive manner, numerous modern technical research accomplishments on the development of nanocomposites from liquid crystalline polymers. It emphasizes various studies at the nano-scale, including discussions of liquid crystalline block copolymers, liquid crystalline epoxy nanocomposites, barrier property studies of liquid crystalline epoxy and their nanocomposites, liquid crystalline polymer-based microfibrillar and nanofibrillar composites, liquid crystalline polymer/nanoplatelet nanocomposites, liquid-crystalline elastomer/graphene oxide nanocomposites, and thermotropic liquid crystalline polymers. It provides detailed information on methods of preparation, the properties of these materials and a discussion on the structure-properties relationship. With an emphasis on data and experimental results, the book's authors illustrate how the liquid crystal structure can have an impact on the final properties of nanocomposite. Contains contributions from leading experts working in this specialized field of research Provides detailed information on the preparation, characterization and application of nanocomposites of liquid crystalline polymers Presents solutions to both fundamental and applied problems

Polyurethane Polymers Composites and Nanocomposites

Polyurethane Polymers  Composites and Nanocomposites Book
Author : Sabu Thomas,Janusz Datta,Jozef Haponiuk,Arunima Reghunadhan
Publisher : Elsevier
Release : 2017-08-17
ISBN : 0128041021
Language : En, Es, Fr & De

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Book Description :

Polyurethane Polymers: Composites and Nanocomposites concentrates on the composites and nanocomposites of polyurethane based materials. Polyurethane composites are a very important class of materials widely used in the biomedical and industrial field that offer numerous potential applications in many areas. This book discusses current research and identifies future research needs in the area. Provides an elaborate coverage of the chemistry of polyurethane, its synthesis, and properties Includes available characterization techniques Relates types of polyurethanes to their potential properties Discusses composites, nanocomposites options, and PU recycling

Advances in Polymer Nanocomposites

Advances in Polymer Nanocomposites Book
Author : Fengge Gao
Publisher : Elsevier
Release : 2012-10-19
ISBN : 0857096249
Language : En, Es, Fr & De

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Book Description :

The addition of nanoparticles to polymer composites has led to a new generation of composite materials with enhanced and novel properties. Advances in polymer nanocomposites reviews the main types of polymer nanocomposites and their applications. Part one reviews types of polymer nanocomposites according to fillers. Processing of carbon nanotube-based nanocomposites, layered double hydroxides (LDHs) and cellulose nanoparticles as functional fillers and reinforcement are discussed, alongside calcium carbonate and metal-polymer nanocomposites. Part two focuses on types of polymer nanocomposites according to matrix polymer, with polyolefin-based, (PVC)-based, nylon-based, (PET)-based and thermoplastic polyurethane (TPU)-based polymer nanocomposites discussed. Soft, gel and biodegradable polymer nanocomposites are also considered. Part three goes on to investigate key applications, including fuel cells, aerospace applications, optical applications, coatings and flame-retardant polymer nanocomposites. With its distinguished editor and international team of expert contributors, Advances in polymer nanocomposites is an essential guide for professionals and academics involved in all aspects of the design, development and application of polymer nanocomposites. Reviews the main types of polymer nanocomposites and their applications Discusses processing of carbon nanotube-based nanocomposites, layered double hydroxides (LDHs) and cellulose nanoparticles as functional fillers and reinforcement Discusses polyolefin-based, (PVC)-based, nylon-based, (PET)-based and thermoplastic polyurethane (TPU)-based polymer nanocomposites

Fundamentals of Conjugated Polymer Blends Copolymers and Composites

Fundamentals of Conjugated Polymer Blends  Copolymers and Composites Book
Author : Parveen Saini
Publisher : John Wiley & Sons
Release : 2015-04-24
ISBN : 111913711X
Language : En, Es, Fr & De

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Book Description :

Since their discovery in 1977, the evolution of conducting polymers has revolutionized modern science and technology. These polymers enjoy a special status in the area of materials science yet they are not as popular among young readers or common people when compared to other materials like metals, paper, plastics, rubber, textiles, ceramics and composites like concrete. Most importantly, much of the available literature in the form of papers, specific review articles and books is targeted either at advanced readers (scientists/technologists/engineers/senior academicians) or for those who are already familiar with the topic (doctoral/postdoctoral scholars). For a beginner or even school/college students, such compilations are bit difficult to access/digest. In fact, they need proper introduction to the topic of conducting polymers including their discovery, preparation, properties, applications and societal impact, using suitable examples and already known principles/knowledge/phenomenon. Further, active participation of readers in terms of “question & answers”, “fill-in-the-blanks”, “numerical” along with suitable answer key is necessary to maintain the interest and to initiate the “thought process”. The readers also need to know about the drawbacks and any hazards of such materials. Therefore, I believe that a comprehensive source on the science/technology of conducting polymers which maintains a link between grass root fundamentals and state-of-the-art R&D is still missing from the open literature.

Graphene to Polymer Graphene Nanocomposites

Graphene to Polymer Graphene Nanocomposites Book
Author : Ayesha Kausar
Publisher : Elsevier
Release : 2021-09-23
ISBN : 0323909388
Language : En, Es, Fr & De

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Book Description :

Graphene to Polymer/Graphene Nanocomposites: Emerging Research and Opportunities brings together the latest advances and cutting-edge methods in polymer/graphene nanocomposites that offer attractive properties and features, leading to a broad range of valuable applications. The initial chapters of this book explain preparation, properties, modification, and applications of graphene and graphene-based multifunctional polymeric nanocomposites. Later, the state-of-the-art potential of polymer/graphene nanocomposites for hierarchical nanofoams, graphene quantum dots, graphene nanoplatelets, graphene nanoribbons, etc., has been elucidated. The subsequent chapters focus on specific innovations and applications including stimuli-responsive graphene-based materials, anticorrosive coatings, applications in electronics and energy devices, gas separation and filtration membrane applications, aerospace applications, and biomedical applications. Throughout the book, challenges, and future opportunities in the field of polymer/graphene nanocomposites are discussed and analyzed. This is an important resource for researchers, scientists, and students/academics working with graphene and across the fields of polymer composites, nanomaterials, polymer science, chemistry, chemical engineering, biomedical engineering, materials science, and engineering, as well those in an industrial setting who are interested in graphene or innovative materials. Explores the fundamentals, preparation, properties, processing, and applications of graphene and multifunctional polymer-graphene nanocomposites. Focuses on the state of the art including topics such as nano-foam architectures, graphene quantum dots, graphene nanoplatelets, graphene nanoribbons, and other graphene nanostructures. Provides advanced applications including shape memory materials, anticorrosion materials, electronics and energy devices, gas separation and filtration membranes, aerospace relevance, and biomedical applications.

Polymer Nanocomposites for Advanced Engineering and Military Applications

Polymer Nanocomposites for Advanced Engineering and Military Applications Book
Author : Ramdani, Noureddine
Publisher : IGI Global
Release : 2019-04-01
ISBN : 1522578390
Language : En, Es, Fr & De

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Book Description :

The field of polymer nanocomposites has become essential for engineering and military industries over the last few decades as it applies to computing, sensors, biomedical microelectronics, hard coating, and many other domains. Due to their outstanding mechanical and thermal features, polymer nanocomposite materials have recently been developed and now have a wide range of applications. Polymer Nanocomposites for Advanced Engineering and Military Applications provides emerging research on recent advances in the fabrication methods, properties, and applications of various nano-fillers including surface-modification methods and chemical functionalization. Featuring coverage on a broad range of topics such as barrier properties, biomedical microelectronics, and matrix processing, this book is ideally designed for engineers, industrialists, chemists, government officials, military professionals, practitioners, academicians, researchers, and students.

Handbook of Polymer Nanocomposites for Industrial Applications

Handbook of Polymer Nanocomposites for Industrial Applications Book
Author : Chaudhery Mustansar Hussain
Publisher : Elsevier
Release : 2020-10-29
ISBN : 0128226692
Language : En, Es, Fr & De

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Book Description :

Handbook of Polymer Nanocomposites for Industrial Applications summarizes the properties of polymer nanocomposites, discusses their industrial scale fabrication methods, and presents their applications for various industrial sectors at both experimental and theoretical models scales. The book also addresses existing challenges for the use of polymer nanocomposites in major industrial sectors. Overall, the aim of this book is to summarize the recent advancements in the use of PNCs in a variety of industry sectors. Particular attention is paid to those approaches that enable green and sustainable industrial developments. The legal, economical and toxicity aspects of polymer nanocomposite are also presented in detail. Comprehensively explores how polymer nanocomposites are being used to create more efficient products and devices in a variety of industry sectors Explores the environmental, legal, health and safety issues of using polymer nanocomposites in an industrial context Develops a roadmap to the wider commercial utilization of polymer nanocomposites Emphasizes the use of polymer nanocomposites in green and sustainable technologies

Polymer Nanocomposites

Polymer Nanocomposites Book
Author : Giuliana Gorrasi
Publisher : MDPI
Release : 2018-11-13
ISBN : 3038973262
Language : En, Es, Fr & De

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Book Description :

This book is a printed edition of the Special Issue "Polymer Nanocomposites" that was published in Nanomaterials