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Pericyclic Chemistry

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Pericyclic Chemistry

Pericyclic Chemistry Book
Author : Dipak Kumar Mandal
Publisher : Elsevier
Release : 2018-03-26
ISBN : 0128149590
Language : En, Es, Fr & De

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Book Description :

Pericyclic Chemistry: Orbital Mechanisms and Stereochemistry is a complete guide to the topic that is ideal for graduate students, advanced undergraduate students and researchers in organic chemistry. An introduction to molecular orbital theory and relevant stereochemical concepts is provided as background, with all four classes of pericyclic reactions discussed and illustrated with orbital picture representations. Also included are chapters on cycloadditions, the most versatile class, and electrocyclic reactions, sigmatropic rearrangements and group transfer reactions. A separate chapter on the construction of correlation diagrams is also included, emphasizing a practical, hands on approach. Author Dipak Kumar Mandal brings over 30 years of teaching experience to the topic and illuminates pericyclic chemistry with a clear and fresh perspective. Comprehensive guide featuring unifying mechanistic approaches, stereochemical details and novel rules and mnemonics to delineate product stereochemistry Includes two background chapters on molecular orbitals and stereochemical concepts Emphasizes a theoretical understanding using perturbation theory (Salem-Klopman equation) and physical insights from orbital and state correlation analyses

Pericyclic Reactions

Pericyclic Reactions Book
Author : Sunil Kumar,Vinod Kumar,S.P. Singh
Publisher : Academic Press
Release : 2015-08-24
ISBN : 0128036699
Language : En, Es, Fr & De

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Book Description :

Pericyclic Reactions: A Mechanistic and Problem-Solving Approach provides complete and systematic coverage of pericyclic reactions for researchers and graduate students in organic chemistry and pharmacy programs. Drawing from their cumulative years of teaching in the area, the authors use a clear, problem-solving approach, supplemented with colorful figures and illustrative examples. Written in an accessible and engaging manner, this book covers electrocyclic reactions, sigmatropic reactions, cycloaddition reactions, 1,3-dipolar reactions, group transfer, and ene reactions. It offers an in-depth study of the basic principles of these topics, and devotes equal time to problems and their solutions to further explore those principles and aid reader understanding. Additional practice problems are provided for further study and course use. Comprehensive coverage of important topics such as 1,3 dipolar, pyrolytic, and cycloaddition reactions Problem-solving approach with clear figures and many worked and unworked problems Contents are applicable to advanced students and researchers in organic chemistry

Pericyclic Reactions

Pericyclic Reactions Book
Author : Alan P. Marchand,Roland E. Lehr
Publisher : Academic Press
Release : 2013-10-22
ISBN : 1483218651
Language : En, Es, Fr & De

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Book Description :

Pericyclic Reactions,Volume 35-II covers the theoretical approaches to pericyclic reactions and reviews of pericyclic reactions of reactive intermediates and of particular reaction types. The book discusses some of the experimental approaches used to establish the authenticity of an apparent pericyclic reaction; the transient and observable carbocation rearrangements; and orbital symmetry interactions which are “extra stabilizing or destabilizing. The text then describes the pericyclic reactions of cumulenes; the cheletropic reactions; the applications of frontier molecular orbital theory to pericyclic reactions. A general theoretical model accommodating concerted reaction profiles for forbidden thermal reactions is also encompassed. Chemists and people involved in the study of pericyclic reactions will find the book invaluable.

Pericyclic Reactions

Pericyclic Reactions Book
Author : Ian Fleming
Publisher : Oxford University Press, USA
Release : 2015
ISBN : 0199680906
Language : En, Es, Fr & De

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Book Description :

Key texts in the renowned Oxford Chemistry Primers series have been fully refreshed and updated to suit the needs of today's students, lecturers, and postgraduate researchers. The rigorous and yet accessible treatment of each subject area is ideal for those wanting to know more about a particular topic not covered comprehensively in existing undergraduate texts. Moreover, cutting-edge examples and applications throughout the texts show the relevance of thechemistry being described to the real world. Pericyclic reactions constitute a fundamental class of organic chemistry, including such commercially important synthetic reactions as theDiels-Alder reaction. This primer gives a concise and accessible account of these reactions, enabling students to recognise the different types of pericyclic reaction and understand their application in organic synthesis.

Pericyclic Reactions

Pericyclic Reactions Book
Author : Alan P. Marchand,Roland E. Lehr
Publisher : Academic Press
Release : 2013-10-22
ISBN : 1483218643
Language : En, Es, Fr & De

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Book Description :

Pericyclic Reactions, Volume 1 covers the theoretical approaches to pericyclic reactions and pericyclic reactions of reactive intermediates and of particular reaction types. The book discusses the operational criteria for evaluation of concertedness in potential pericyclic reactions; and the Mobius-Hückel treatment of organic systems and reactions and molecular orbital following as a technique in organic chemistry. The text also describes some pericyclic reactions of carbenes and carbanions. Physicists and people involved in the study of pericyclic reactions will find the book invaluable.

Pericyclic Reactions

Pericyclic Reactions Book
Author : S. M. Mukherji
Publisher : Unknown
Release : 1979
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Pericyclic Reactions book written by S. M. Mukherji, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Overlap Determinant Method in the Theory of Pericyclic Reactions

Overlap Determinant Method in the Theory of Pericyclic Reactions Book
Author : Robert Ponec
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 3642468179
Language : En, Es, Fr & De

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Book Description :

The author summarizes the development and the applications of overlap determinant method in various fields of pericyclic reactivity. The greatest advantage of this new method lies in its remarkable simplicity and flexibility owing to which it opens an interesting possibility of the systematic investigation of important mechanistic problems of pericyclic reactivity which were so far beyond the scope of other existing techniques.

Pericyclic Reactions

Pericyclic Reactions Book
Author : G. Gill
Publisher : Springer
Release : 1974-05-23
ISBN : 9780412124907
Language : En, Es, Fr & De

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Book Description :

??1???1??orbita1 theory has had some notable successes in the ana1ysis of individua1 organic reactions and in corre1ations between reaction series. Gen­ ???ll? the theory has???? invoked to exp1ain known chemica1 phenomena, and rather infrequent1y [?? broad1y-based predictions. In 1965 Woodward and??????? published ? series of papers?? the??1???1??orbita1 inter­ pretation of various types of concerted cyc10-addition reactions, which hitherto had???? rather????1? understood. Because these processes (now known as pericyclic reactions) had great synthetic importance, and because the Woodward-Hoffmann theory was stated so explicit1y as to allow [?? usefu1 and far-reaching predictions to?? made, the genera1 acceptance of the so-called Woodward-Hoffmann Ru1es was very rapid. Judging from the vast number of publications that have appeared, ? great dea1 of experimentaleffort has???? channelled into this genera1 area since that time, the results of which provide ? vindication of the ru1es. The theoretica1 basis of Woodward and Hoffmann's method has, however,???? the subject of criticism and controversy, and ? ?????? of alternative theoretica1 methods have a1so appeared. ???? university departments (inc1uding?ur own) have for some time covered pericyclic reactions in their undergraduate and graduate courses. Because aims, teaching methods, and persona1 preferences differ wide1y, each of the various theoretica1 methods have achieved some currency. We have sought to?1??? these methods in some sort of perspective. The book is intended to?? introductory, being aimed primarily at fina1 year undergraduates and first year postgraduates.

Pericyclic Reactions

Pericyclic Reactions Book
Author : G. Gill
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 9400957181
Language : En, Es, Fr & De

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Book Description :

??1???1??orbita1 theory has had some notable successes in the ana1ysis of individua1 organic reactions and in corre1ations between reaction series. Gen???ll? the theory has???? invoked to exp1ain known chemica1 phenomena, and rather infrequent1y [?? broad1y-based predictions. In 1965 Woodward and??????? published? series of papers?? the??1???1??orbita1 inter pretation of various types of concerted cyc10-addition reactions, which hitherto had???? rather????1? understood. Because these processes (now known as pericyclic reactions) had great synthetic importance, and because the Woodward-Hoffmann theory was stated so explicit1y as to allow [?? usefu1 and far-reaching predictions to?? made, the genera1 acceptance of the so-called Woodward-Hoffmann Ru1es was very rapid. Judging from the vast number of publications that have appeared,? great dea1 of experimentaleffort has???? channelled into this genera1 area since that time, the results of which provide? vindication of the ru1es. The theoretica1 basis of Woodward and Hoffmann's method has, however,???? the subject of criticism and controversy, and??????? of alternative theoretica1 methods have a1so appeared.???? university departments (inc1uding?ur own) have for some time covered pericyclic reactions in their undergraduate and graduate courses. Because aims, teaching methods, and persona1 preferences differ wide1y, each of the various theoretica1 methods have achieved some currency. We have sought to?1??? these methods in some sort of perspective. The book is intended to?? introductory, being aimed primarily at fina1 year undergraduates and first year postgraduates.

Modern Physical Organic Chemistry

Modern Physical Organic Chemistry Book
Author : Eric V. Anslyn,Dennis A. Dougherty
Publisher : University Science Books
Release : 2006
ISBN : 9781891389313
Language : En, Es, Fr & De

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Book Description :

Making explicit the connections between physical organic chemistry and critical fields such as organometallic chemistry, materials chemistry, bioorganic chemistry and biochemistry, this book escorts the reader into an area that has been thoroughly updated in recent times.

Pericyclic Reactions A Textbook

Pericyclic Reactions   A Textbook Book
Author : S. Sankararaman
Publisher : Wiley-VCH
Release : 2005-09-12
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Based on twelve years of teaching a graduate course, this long awaited textbook presents Diels-Alder reactions, electrocyclic reactions, sigmatropic rearrangements plus many more topics in a highly didactic way. Throughout the focus is on the important facts and aspects, with both classical and new examples explained in detail. The only up-to-date work of its kind on the market, this is an invaluable tool for students and lecturers in chemistry, organic chemists, and libraries. With a foreword by Nobel Laureate Roald Hoffmann.

Photochemistry And Pericyclic Reactions

Photochemistry And Pericyclic Reactions Book
Author : J. Singh
Publisher : New Age International
Release : 2005-01-01
ISBN : 8122416942
Language : En, Es, Fr & De

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Book Description :

This Book Is Especially Designed According To The Model Curriculum Of M.Sc. (Prev.) (Pericyclic Reactions) And M.Sc. (Final) (Photochemistry Compulsory Paper Viii) Suggested By The University Grants Commission, New Delhi. As Far As The Ugc Model Curriculum Is Concerned, Most Of The Indian Universities Have Already Adopted It And The Others Are In The Process Of Adopting The Proposed Curriculum. In The Present Academic Scenario, We Strongly Felt That A Comprehensive Book Covering Modern Topics Like Pericyclic Reactions And Photochemistry Of The Ugc Model Curriculum Was Urgently Needed. This Book Is A Fruitful Outcome Of Our Aforesaid Strong Feeling. Besides M.Sc. Students, This Book Will Also Be Very Useful To Those Students Who Are Preparing For The Net (Csir), Slet, Ias, Pcs And Other Competitive Examinations.The Subject Matter Has Been Presented In A Comprehensive, Lucid And Systematic Manner Which Is Easy To Understand Even By Self Study. The Authors Believe That Learning By Solving Problems Gives More Competence And Confidence In The Subject. Keeping This In View, Sufficiently Large Number Of Varied Problems For Self Assessment Are Given In Each Chapter. Hundred Plus Problems With Solutions In The Last Chapter Is An Important Feature Of This Book.

Advanced Organic Chemistry

Advanced Organic Chemistry Book
Author : Francis A. Carey,Richard J. Sundberg
Publisher : Springer Science & Business Media
Release : 2007-06-13
ISBN : 0387448977
Language : En, Es, Fr & De

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Book Description :

The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and selectivity for students and exercise solutions for instructors.

Advanced Organic Chemistry Reactions And Mechanisms

Advanced Organic Chemistry  Reactions And Mechanisms Book
Author : Maya Shankar Singh,Singh
Publisher : Pearson Education India
Release : 2004-09
ISBN : 9788131711071
Language : En, Es, Fr & De

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Book Description :

Advanced Organic Chemistry: Reactions and Mechanisms covers the four types of reactions -- substitution, addition, elimination and rearrangement; the three types of reagents -- nucleophiles, electrophiles and radicals; and the two effects -- electroni.

Essentials of Pericyclic and Photochemical Reactions

Essentials of Pericyclic and Photochemical Reactions Book
Author : Biswanath Dinda
Publisher : Springer
Release : 2016-11-18
ISBN : 3319459341
Language : En, Es, Fr & De

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Book Description :

This book provides a concise introduction to pericyclic and photochemical reactions for organic synthesis. In the first part about pericyclic reactions, the author explains electrocyclic reactions, cycloaddition reactions, sigmatropic rearrangements, and group transfer reactions. The second part on photochemistry is dedicated to photochemical reactions of a variety of compound classes, including alkenes, dienes, and polyenes, carbonyl compounds, and aromatic compounds. Additionally, photofragmentation reactions are described in a dedicated chapter. The last chapter gives an outlook on applications of photochemistry and natural photochemical phenomena. Both parts start with a comprehensive presentation of the general principles of the pericyclic and photochemical reactions. All chapters are rich in examples, which help illustrate the explained principles and establish ties to results and trends in recent research. Additionally, each chapter offers exercises for students, and solutions to the problems are provided in a separate appendix. This book nicely illustrates the utility of pericyclic and photochemical reactions and provides students and researchers with the tools to apply them routinely for an efficient synthesis of complex organic molecules. It will therefore appeal to advanced undergraduate students, graduate and postgraduate students, and even to practitioners and scientists in the field of organic synthesis. The rich examples and exercises will also make it a versatile tool for teachers and lecturers.

Organic Chemistry

Organic Chemistry Book
Author : J. David Rawn,Robert J. Ouellette
Publisher : Academic Press
Release : 2018-02-03
ISBN : 0128128399
Language : En, Es, Fr & De

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Book Description :

Organic Chemistry: Structure, Mechanism, Synthesis, Second Edition, provides basic principles of this fascinating and challenging science, which lies at the interface of physical and biological sciences. Offering accessible language and engaging examples and illustrations, this valuable introduction for the in-depth chemistry course engages students and gives future and new scientists a new approach to understanding, rather than merely memorizing the key concepts underpinning this fundamental area. The book builds in a logical way from chemical bonding to resulting molecular structures, to the corresponding physical, chemical and biological properties of those molecules. The book explores how molecular structure determines reaction mechanisms, from the smallest to the largest molecules—which in turn determine strategies for organic synthesis. The book then describes the synthetic principles which extend to every aspect of synthesis, from drug design to the methods cells employ to synthesize the molecules of which they are made. These relationships form a continuous narrative throughout the book, in which principles logically evolve from one to the next, from the simplest to the most complex examples, with abundant connections between the theory and applications. Featuring in-book solutions and instructor PowerPoint slides, this Second Edition offers an updated and improved option for students in the two-semester course and for scientists who require a high quality introduction or refresher in the subject. Offers improvements for the two-semester course sequence and valuable updates including two new chapters on lipids and nucleic acids Features biochemistry and biological examples highlighted throughout the book, making the information relevant and engaging to readers of all backgrounds and interests Includes a valuable and highly-praised chapter on organometallic chemistry not found in other standard references

The Essence of Pericyclic Reaction

The Essence of Pericyclic Reaction Book
Author : Khushal M. Kapadiya Kapadiya, 1st,Ranjan C Khunt, 2nd
Publisher : Unknown
Release : 2021-08-25
ISBN : 9781956102611
Language : En, Es, Fr & De

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Book Description :

Organic chemistry is a vibrant and growing scienti?c discipline that touches a vast number of scienti?c areas. This first edition of ''The Essence of Pericyclic Reactions'' has been thoroughly updated to re?ect new areas of Organic chemistry, as well as new advances in well-known areas of Organic chemistry. Every topic retained from the ?fth edition has been brought up to date. Changes include theThe goal, as in the first edition is to give equal weight to the four fundamental aspects of the study of pericyclic chemistry. A student who has completed a course based on this book should be able to approach the literature directly, with a sound knowledge of modern basic organic chemistry. The organization is based on reaction types, so the student can be shown that despite the large number of organic reactions, a relatively few principles suf?ce to explain nearly all of them.

Organic Chemistry

Organic Chemistry Book
Author : Allan D. Headley
Publisher : John Wiley & Sons
Release : 2020-01-02
ISBN : 1119504589
Language : En, Es, Fr & De

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Book Description :

Provides an in-depth study of organic compounds that bridges the gap between general and organic chemistry Organic Chemistry: Concepts and Applications presents a comprehensive review of organic compounds that is appropriate for a two-semester sophomore organic chemistry course. The text covers the fundamental concepts needed to understand organic chemistry and clearly shows how to apply the concepts of organic chemistry to problem-solving. In addition, the book highlights the relevance of organic chemistry to the environment, industry, and biological and medical sciences. The author includes multiple-choice questions similar to aptitude exams for professional schools, including the Medical College Admissions Test (MCAT) and Dental Aptitude Test (DAT) to help in the preparation for these important exams. Rather than categorize content information by functional groups, which often stresses memorization, this textbook instead divides the information into reaction types. This approach bridges the gap between general and organic chemistry and helps students develop a better understanding of the material. A manual of possible solutions for chapter problems for instructors and students is available in the supplementary websites. This important book: • Provides an in-depth study of organic compounds with division by reaction types that bridges the gap between general and organic chemistry • Covers the concepts needed to understand organic chemistry and teaches how to apply them for problem-solving • Puts a focus on the relevance of organic chemistry to the environment, industry, and biological and medical sciences • Includes multiple choice questions similar to aptitude exams for professional schools Written for students of organic chemistry, Organic Chemistry: Concepts and Applications is the comprehensive text that presents the material in clear terms and shows how to apply the concepts to problem solving.

Encyclopedia of Physical Organic Chemistry 6 Volume Set

Encyclopedia of Physical Organic Chemistry  6 Volume Set Book
Author : Zerong Wang
Publisher : John Wiley & Sons
Release : 2017-04-17
ISBN : 1118470451
Language : En, Es, Fr & De

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Book Description :

Winner of 2018 PROSE Award for MULTIVOLUME REFERENCE/SCIENCE This encyclopedia offers a comprehensive and easy reference to physical organic chemistry (POC) methodology and techniques. It puts POC, a classical and fundamental discipline of chemistry, into the context of modern and dynamic fields like biochemical processes, materials science, and molecular electronics. Covers basic terms and theories into organic reactions and mechanisms, molecular designs and syntheses, tools and experimental techniques, and applications and future directions Includes coverage of green chemistry and polymerization reactions Reviews different strategies for molecular design and synthesis of functional molecules Discusses computational methods, software packages, and more than 34 kinds of spectroscopies and techniques for studying structures and mechanisms Explores applications in areas from biology to materials science The Encyclopedia of Physical Organic Chemistry has won the 2018 PROSE Award for MULTIVOLUME REFERENCE/SCIENCE. The PROSE Awards recognize the best books, journals and digital content produced by professional and scholarly publishers. Submissions are reviewed by a panel of 18 judges that includes editors, academics, publishers and research librarians who evaluate each work for its contribution to professional and scholarly publishing. You can find out more at: proseawards.com Also available as an online edition for your library, for more details visit Wiley Online Library

Survey of Progress in Chemistry

Survey of Progress in Chemistry Book
Author : Arthur Scott
Publisher : Elsevier
Release : 2012-12-02
ISBN : 0323154603
Language : En, Es, Fr & De

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Book Description :

Survey of Progress in Chemistry, Volume 6 is a five-chapter text that covers the developments of some areas in chemistry. Chapter 1 describes the unusual reactivity of ruthenium(II) amines and outlines some qualitative ideas that help in understanding the chemistry of Ru(II) in relation to that of comparison ions. This text also examines the affinity of Ru(II) for unsaturated ligands and the chemical effects of back-bonding on the properties of ligands. Chapter 2 investigates the concept of the so-called “chemical evolution and its role in the origins of life on Earth. Chapter 3 presents the various methods that have been applied to follow the rates of ionization of carbon acids. Chapter 4 focuses on the mechanisms of pericyclic reactions and orbital symmetry. This chapter specifically tackles cycloadditions, electrocyclizations, sigmatropic shifts, chelotropic reactions, group transfers, and some types of addition and elimination reactions. Chapter 5 discusses the fundamentals of polypeptide conformation and the conformation and function of selected peptides. This book is an ideal source for chemistry teachers and students.