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Organotransition Metals In Organic Synthesis

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Organotransition Metal Chemistry Applications to Organic Synthesis

Organotransition Metal Chemistry  Applications to Organic Synthesis Book
Author : S. G. Davies
Publisher : Elsevier
Release : 2013-10-22
ISBN : 1483285847
Language : En, Es, Fr & De

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Book Description :

Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.

Organotransition Metal Chemistry

Organotransition Metal Chemistry Book
Author : Yoshio Ishii
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 1468421425
Language : En, Es, Fr & De

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Book Description :

Synthesis of Organotransition Metals.- Metallocarboranes: Past, Present, and Future.- Novel Rhodium and Palladium Complexes with Benzoyl and Thiobenzoyl Isocyanates as Ligands.- Polycyanovinyl Transition Metal Derivatives.- A New Preparation of Organocopper(I)-Isonitrile Complexes and Their Reactions.- An Unusual Behavior of?-Vinyl Alcohol Complexes of Transition Metals.- The Mode of Formation of Transition Metal to Carbon Bonds by Oxidative Addition.- Organoactinides: Coordination Patterns and Chemical Reactivity.- Recent Developments in Chemistry of Organolanthanides and Organoactinides.- C.

Transition Metals in the Synthesis of Complex Organic Molecules

Transition Metals in the Synthesis of Complex Organic Molecules Book
Author : Louis S. Hegedus
Publisher : University Science Books
Release : 1999
ISBN : 9781891389047
Language : En, Es, Fr & De

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Book Description :

This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.

Organotransition Metal Chemistry

Organotransition Metal Chemistry Book
Author : Akio Yamamoto
Publisher : Wiley-Interscience
Release : 1986
ISBN :
Language : En, Es, Fr & De

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Book Description :

A systematic, readable treatment of organotransition metal chemistry that provides students, teachers, and practicing chemists with an understanding of basic concepts in catalysis and synthetic procedures using transition metal reagents. Covers basic principles of coordination chemistry, organometallic compounds of transition metals and non-transition metals, reactions, industrial applications, use in synthesis, methods of manipulation for air-sensitive compounds, and an overview of related topics. Well illustrated with figures and formulae.

Organotransition Metal Chemistry

Organotransition Metal Chemistry Book
Author : Anthony F. Hill,A. Hill
Publisher : Royal Society of Chemistry
Release : 2002
ISBN : 9780854046225
Language : En, Es, Fr & De

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Book Description :

This book aims to introduce undergraduates to the utility of organotransition metal chemistry, a discipline of importance to scientists in a variety of industry sectors.

Principles and Applications of Organotransition Metal Chemistry

Principles and Applications of Organotransition Metal Chemistry Book
Author : James Paddock Collman,Louis S. Hegedus,Jack R. Norton,Richard G. Finke
Publisher : Univ Science Books
Release : 1987
ISBN :
Language : En, Es, Fr & De

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Book Description :

This textbook introduces students and experienced chemists to a rapidly growing interdisciplinary subject. It incorporates a thorough revision of the earlier edition, and includes all new developments.

Organo Transition Metal Compounds and Related Aspects of Homogeneous Catalysis

Organo Transition Metal Compounds and Related Aspects of Homogeneous Catalysis Book
Author : B. L. Shaw,N. I. Tucker
Publisher : Elsevier
Release : 2013-10-22
ISBN : 1483159698
Language : En, Es, Fr & De

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Book Description :

Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis deals with the chemistry of organo-transition metal complexes and their uses as homogeneous catalysts and as intermediates in organic synthesis. The compounds are classified mainly from the number of carbon atoms that are actually bonded to the metal and to each other. This volume is comprised of eight chapters and begins with a discussion on alkyls, aryls, acetylides, fluorocarbon complexes, and carbides, along with olefin, allene, and acetylene complexes. The reader is then introduced to π-allylic and related complexes such as fluoroallyl complexes; complexes with conjugated diolefins including fluorodiolefins but excluding cyclobutadienes; cyclopentadienyl-metal, pentadienyl-metal, and related complexes; and arene complexes, related complexes with conjugated trienes, and thiophene complexes such as benzenoid-metal or arene-metal complexes, cyclopheptatriene complexes, and complexes with other six electron donors. Cycloheptatrienyl or tropylium complexes are also considered, along with cyclo-octatetraene, azulene complexes, and carborane complexes. This book will be a valuable source of information for inorganic chemists.

Transition Metal Reagents and Catalysts

Transition Metal Reagents and Catalysts Book
Author : Jiro Tsuji
Publisher : John Wiley & Sons
Release : 2002-08-16
ISBN : 9780471560272
Language : En, Es, Fr & De

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Book Description :

Transition Metal Reagents and Catalysts Innovations in Organic Synthesis Jiro Tsuji Emeritus Professor, Tokyo Institute of Technology, Japan Numerous innovative and practical synthetic methods using transition metal complexes as either catalysts or reagents have been developed over the last 35 years. Transition Metal Reagents and Catalysts combines the varied applications of transition metal complexes in a unique and timely book in this rapidly advancing area of organic synthesis. This text is an easily understandable and enjoyable read for organic chemists who are not yet familiar with organo-transition metal chemistry. Transition Metal Reagents and Catalysts presents: * Complete coverage of nearly 35 years of transition metal complex chemistry * An in-depth treatment of many innovative synthetic methodologies * A rational classification of all reactions according to substrates and reaction mechanisms * Examples of important applications of transition metal catalysed reactions. A knowledge of organic synthesis using transition metal complexes is a must for all synthetic organic chemists. Written for chemists who wish to apply novel synthetic methods using transition metal complexes to solve problems in organic and pharmaceutical chemistry, such as synthesis of fine and bulk chemicals and natural products, Transition Metal Reagents and Catalysts is an essential reference source and an indispensible research companion.

Organotransition Metal Chemistry From Bonding to Catalysis

Organotransition Metal Chemistry  From Bonding to Catalysis Book
Author : John F. Hartwig
Publisher : Univ Science Books
Release : 2010-02-10
ISBN :
Language : En, Es, Fr & De

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Book Description :

Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates, making this the Organotransition Metal Chemistry text for a new generation of scientists.

New Pathways for Organic Synthesis

New Pathways for Organic Synthesis Book
Author : H.M. Colquhoun,J. Holton,D.J. Thompson,M.V. Twigg
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 1461326516
Language : En, Es, Fr & De

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Book Description :

The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.

Organotransition Metal Chemistry A Mechanistic Approach

Organotransition Metal Chemistry A Mechanistic Approach Book
Author : Richard Heck
Publisher : Elsevier
Release : 2012-12-02
ISBN : 0323154700
Language : En, Es, Fr & De

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Book Description :

Organotransition Metal Chemistry: A Mechanistic Approach describes a mechanistic approach to the study of the chemistry of organotransition metals. Organotransition metals are discussed in relation to their reactions with specific functional groups or types of compounds rather than by metals. Topics covered include the formation of hydrogen and carbon bonds to transition metals; reactions of transition metal δ- and π-bonded derivatives; and addition and elimination reactions of olefinic compounds. This book is comprised of 10 chapters and begins with a historical overview of organotransition metal chemistry, together with the unique chemistry of transition metals and mechanisms of ligand replacements. The following chapters discuss the methods of preparation of hydrido complexes and carbon-transition metal bonds; homogeneous hydrogenation reactions; isomerization, dimerization, oligomerization, and polymerization of olefins; and reactions of dienes, trienes, and tetraenes with transition metal compounds. Transition metal reactions with acetylenes and carbon monoxide as well as organic carbonyl compounds are also examined. This monograph should be of value to organic chemists as well as students and researchers of organic chemistry.

Transition Metals for Organic Synthesis

Transition Metals for Organic Synthesis Book
Author : Matthias Beller,Carsten Bolm
Publisher : Wiley-VCH
Release : 1998-09-17
ISBN :
Language : En, Es, Fr & De

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Book Description :

This two volume set presents contemporary research and application in the economically and scientifically important area of transition metals for organic synthesis and fine chemicals production.

Landmarks in Organo Transition Metal Chemistry

Landmarks in Organo Transition Metal Chemistry Book
Author : Helmut Werner
Publisher : Springer Science & Business Media
Release : 2008-12-16
ISBN : 0387098488
Language : En, Es, Fr & De

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Book Description :

Since the discovery of ferrocene and the sandwich-type complexes, the development of organometallic chemistry took its course like an avalanche and became one of the scientific success stories of the second half of the twentieth century. Based on this development, the traditional boundaries between inorganic and organic chemistry gradually disappeared and a rebirth of the nowadays highly important field of homogeneous catalysis occurred. It is fair to say that despite the fact that the key discovery, which sparked it all off, was made more than 50 years ago, organometallic chemistry remains a young and lively discipline.

The Organometallic Chemistry of the Transition Metals

The Organometallic Chemistry of the Transition Metals Book
Author : Robert H. Crabtree
Publisher : John Wiley & Sons
Release : 2009-04-06
ISBN : 0470257628
Language : En, Es, Fr & De

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Book Description :

"One impressive and compressive book. . . . This review would have to be book size to do full justice to all the insights in this volume." —Journal of Metals Online Fully updated and expanded to reflect recent advances, this Fifth Edition of the classic text provides students and professional chemists with a comprehensive introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and?detailed descriptions of contemporary applications. With increased focus on organic synthesis applications, nanoparticle science, and green chemistry, the Fifth Edition brings this vital resource up to date. New to the Fifth Edition: Chapters have been updated with relevant examples in the field, modern trends, and new applications; the organic applications chapter has been completely rewritten New end-of-chapter problems, along with their solutions Coverage enhanced with developments in nanoparticle science Increased focus on green chemistry An unparalleled pedagogic resource as well as a valuable working reference for professional chemists, with comprehensive coverage and up-to-date information, students and researchers?in organic and organometallic chemistry will turn to The Organometallic Chemistry of the Transition Metals, Fifth Edition for the critical information they need on organometallic compounds, their preparation, and their use in synthesis.

Organic Synthesis via Organometallics OSM 4

Organic Synthesis via Organometallics  OSM 4  Book
Author : Dieter Enders
Publisher : Vieweg + Teubner Verlag
Release : 1993
ISBN :
Language : En, Es, Fr & De

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Book Description :

Organometallics playa key role in organic synthesis. Carbon carbon bond formation without main group and transition metal based reagents as well as catalysts is hardly imaginable, and the tremendous success in recent years in the field of stereoselective synthesis of complex biologically active com­ pounds would have been impossible without the advances in organometallic chemistry. From the wealth of carbon carbon bond forming reactions in organotransition metal chemistry many new methods have evolved. This was aided considerably by a deepening of our understanding of the relevant reaction mechanisms. Organometallic chemistry is the bridge par excellence between the traditional fields of inorganic and organiC chemistry. It was the intention of the "Volkswagen-Stiftung" to broaden this bridge by starting in 1986 the new interdisciplinary program "Organic Synthesis via Organo­ metallics". From its very beginning this program grew up after 6 years to now more than 60 projects and its encompasses besides its main topic "Organic Synthesis" mechanistic and structural aspects of organometallic chemistry as well. In a series of symposia sponsored by the "Volkswagen-Stiftung", the former of which were held in Hamburg (February 1986), Wiirzburg (October 1988) and Marburg (July 1990), a forum for intensive discussions and SCientific exchange was established. There, scientists participating in the program met with other experts form academia and from industry. The forth symposium was held in Aachen from July 15 to 18, 1992.

Organometallic Chemistry

Organometallic Chemistry Book
Author : Ian J. S. Fairlamb,Jason M. Lynam
Publisher : Royal Society of Chemistry
Release : 2012-06-01
ISBN : 1849733767
Language : En, Es, Fr & De

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Book Description :

A series of critical reviews and perspectives focussing on specific aspects of organometallic chemistry interfacing with other fields of study are provided. For this volume, the critical reviews cover topics such as the activation of "inert" carbon-hydrogen bonds, ligand design and organometallic radical species. For example, Charlie O'Hara discusses how mixed-metal compounds may perform the highly selective activation of C-H bonds and, in particular, how synergic relationships between various metals are crucial to this approach. The chemistry of a remarkable series of air-stable chiral primary phosphine ligands is discussed in some depth by Rachel Hiney, Arne Ficks, Helge M ller-Bunz, Declan Gilheany and Lee Higham. This article focuses on the preparation of these ligands and also how they may be applied in various catalytic applications. Bas De Bruin reports on how ligand radical reactivity can be employed in synthetic organometallic chemistry and catalysis to achieve selectivity in radical-type transformations. As well as highlighting ligand-centered radical transformations in open-shell transition metals, an overview of the catalytic mechanism of Co(II)-catalysed olefin cyclopropanation is given, showing that enzyme-like cooperative metal-ligand-radical reactivity is no longer limited to real enzymes. Valuable and informative comprehensive reviews in the field of organometallic chemistry are also covered in this volume. For example, organolithium and organocuprate chemistry are reviewed by Joanna Haywood and Andrew Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by Mark Humphrey and Marie Cifuentes; and recent developments in the chemistry of the elements of Group 14 - focusing on low-coordination number compounds by Richard Layfield. This volume therefore covers many synthetic and applied aspects of modern organometallic chemistry which ought to be of interest to inorganic, organic and applied catalysis fields."

Organometallic Chemistry

Organometallic Chemistry Book
Author : M. Green,Turpin
Publisher : Royal Society of Chemistry
Release : 2000
ISBN : 9780854043231
Language : En, Es, Fr & De

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Book Description :

This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.

Organic Synthesis Highlights

Organic Synthesis Highlights Book
Author : Hans-Josef Altenbach,Hans-Ulrich Reißig,Karsten Krohn,Manfred Braun,Johann Mulzer
Publisher : John Wiley & Sons
Release : 2008-11-20
ISBN : 3527621393
Language : En, Es, Fr & De

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Book Description :

This unusual collection of 49 essays gives an overview of the trends and accomplishments of synthetic organic chemistry in recent years. Unique in its approach, it deals with almost every aspect of modern synthesis. The first part of the book describes methods and reagents, with particular emphasis on rapidly developing organometallic and biooriented procedures. In the second part, these tools are applied to the syntheses of interesting target compounds and natural compounds with remarkable physiological properties. Mechanistic discussions and retrosynthetic analyses are included. More than 1000 up-to-date references help the reader to pursue the topics highlighted here. This book gives both the active researcher and the advanced student insight into the competitive atmosphere, creativity, and resourcefulness so characteristic of organic synthesis today.

Metallo Organic Chemistry

Metallo Organic Chemistry Book
Author : Anthony J. Pearson
Publisher : John Wiley & Sons Incorporated
Release : 1985-05-27
ISBN :
Language : En, Es, Fr & De

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Book Description :

Presents the basic chemistry of organo-transition metal complexes in the context of real synthetic applications. Examples of de novo syntheses of natural product molecules are used to illustrate the application of established reactivity patterns to organic synthesis. Explains reactivity phenomena by using frontier molecular orbital approaches. Discusses fundamental reactivity and bonding patterns while giving broad coverage of organometallic chemistry.