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Organotransition Metals In Organic Synthesis

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Organotransition Metal Chemistry Applications to Organic Synthesis

Organotransition Metal Chemistry  Applications to Organic Synthesis Book
Author : S. G. Davies
Publisher : Elsevier
Release : 2013-10-22
ISBN : 1483285847
Language : En, Es, Fr & De

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Book Description :

Although organotransition metal chemistry has been developing rapidly over the past 20 years, it is only recently that applications of transition metal complexes to organic synthesis have started to be exploited. This unique book provides an introduction to organometallic chemistry for chemists who have little or no experience in the field, describes the work that has already been done using organotransition metal complexes for synthesis, and indicates to organic and organometallic chemists the type of synthetic problems that can be solved using organometallic compounds. It covers all major advances that have been made in this rapidly expanding area of chemistry, including not only reactions that already have well established applications for synthesis but also many recently discovered potentially useful reactions, providing a survey of recent literature.

Organotransition Metal Chemistry From Bonding to Catalysis

Organotransition Metal Chemistry  From Bonding to Catalysis Book
Author : John F. Hartwig
Publisher : Univ Science Books
Release : 2010-02-10
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Based on Collman et al.'s best-selling classic book, Principles and Applications of Organotransition Metal Chemistry, Hartwig's text consists of new or thoroughly updated and restructured chapters and provides an in-depth view into mechanism, reaction scope, and applications. It covers the most important developments in the field over the last twenty years with great clarity with a selective, but thorough and authoritative coverage of the fundamentals of organometallic chemistry, the elementary reactions of these complexes, and many catalytic processes occurring through organometallic intermediates, making this the Organotransition Metal Chemistry text for a new generation of scientists.

Organotransition Metal Chemistry

Organotransition Metal Chemistry Book
Author : Stephen G. Davies
Publisher : Pergamon Press
Release : 1982
ISBN : 9780080307145
Language : En, Es, Fr & De

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Book Description :

Download Organotransition Metal Chemistry book written by Stephen G. Davies, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Transition Metals in the Synthesis of Complex Organic Molecules

Transition Metals in the Synthesis of Complex Organic Molecules Book
Author : Louis S. Hegedus
Publisher : University Science Books
Release : 1999
ISBN : 9781891389047
Language : En, Es, Fr & De

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Book Description :

This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.

Organotransition Metal Chemistry

Organotransition Metal Chemistry Book
Author : Akio Yamamoto
Publisher : Wiley-Interscience
Release : 1986
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

A systematic, readable treatment of organotransition metal chemistry that provides students, teachers, and practicing chemists with an understanding of basic concepts in catalysis and synthetic procedures using transition metal reagents. Covers basic principles of coordination chemistry, organometallic compounds of transition metals and non-transition metals, reactions, industrial applications, use in synthesis, methods of manipulation for air-sensitive compounds, and an overview of related topics. Well illustrated with figures and formulae.

Organotransition Metal Chemistry

Organotransition Metal Chemistry Book
Author : Yoshio Ishii
Publisher : Springer
Release : 2012-03-19
ISBN : 9781468421446
Language : En, Es, Fr & De

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Book Description :

In every generation the achievements in science have served mankind. The progress accomplished by one generation stimulates the next generation to even greater achievements, which may take the form of increasing, crystallizing, or detailing existing theo ries. Other forms, generally resulting from persistence and enlight ened fortune, open new areas of investigation previously unimagined and have an impact that may be felt for many years. An example of this latter form of achievement was the prepara tion and elucidation of the structures of dicyclopentadienyliron (ferrocene, reported in 1951) dibenzenechromium iodide, triphenyl chromium tristetrahydrofuranate, and numerous olefin-metal ~-com plexes which provided an introduction to new types of chemical bonds the sigma carbon-transition metal bond and the metal ~-complex bond. Initial progress in the field of organotransition-metal chemis try followed the lines of interest generated separately by organic and inorganic chemistry. However, it is becoming increasingly clear that organotransit10n-metal chemistry is not only bridging these two fields, but also crosslinking many other fields of science.

Organotransition Metal Chemistry A Mechanistic Approach

Organotransition Metal Chemistry A Mechanistic Approach Book
Author : Richard Heck
Publisher : Elsevier
Release : 2012-12-02
ISBN : 0323154700
Language : En, Es, Fr & De

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Book Description :

Organotransition Metal Chemistry: A Mechanistic Approach describes a mechanistic approach to the study of the chemistry of organotransition metals. Organotransition metals are discussed in relation to their reactions with specific functional groups or types of compounds rather than by metals. Topics covered include the formation of hydrogen and carbon bonds to transition metals; reactions of transition metal δ- and π-bonded derivatives; and addition and elimination reactions of olefinic compounds. This book is comprised of 10 chapters and begins with a historical overview of organotransition metal chemistry, together with the unique chemistry of transition metals and mechanisms of ligand replacements. The following chapters discuss the methods of preparation of hydrido complexes and carbon-transition metal bonds; homogeneous hydrogenation reactions; isomerization, dimerization, oligomerization, and polymerization of olefins; and reactions of dienes, trienes, and tetraenes with transition metal compounds. Transition metal reactions with acetylenes and carbon monoxide as well as organic carbonyl compounds are also examined. This monograph should be of value to organic chemists as well as students and researchers of organic chemistry.

Organotransition Metals in Organic Synthesis

Organotransition Metals in Organic Synthesis Book
Author : Sugata Chatterjee
Publisher : Elsevier
Release : 2020-12-15
ISBN : 9780128184776
Language : En, Es, Fr & De

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Book Description :

Organotransition Metals in Organic Synthesis: Fundamentals and Applications provides a fundamental understanding on how to use transition and main group metals to synthesize simple and complex molecules with a high degree of selectivity. This book details the basic concepts, elementary reactions, and latest developments of organometallic chemistry surrounding the transition metals. Topics covered include electronic configuration and structural, methods for carbon-transition metal bond creation, cleavage of metal-carbon bonds to form new carbon-carbon bonds, chemo-, region-, stereo- and enantio- control, and heterogeneous organometallic reactions. This book is an ideal resource for researchers and students working with metals in organic synthesis and organometallic chemistry, including those having no prior exposure to organometallic chemistry in synthesis. Includes extensive coverage of methods for creating carbon-transition metal bonds, such as oxidative addition, oxidative coupling, hydro and carbometallation, carbonyl insertion, transmetallation and metal carbenes and metathesis Ideal for students and researchers new to the pharmaceutical industry or organometallic chemistry in general, covering foundational information as well as select advanced applications Covers metals in organic synthesis, unprecedented selectivity, clean reactions, mild conditions, high yields, along with improvisation methods for existing synthesis methods

The Organometallic Chemistry of the Transition Metals

The Organometallic Chemistry of the Transition Metals Book
Author : Robert H. Crabtree
Publisher : John Wiley & Sons
Release : 2005-06-14
ISBN : 0471718750
Language : En, Es, Fr & De

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Book Description :

Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.

Transition Metal Reagents and Catalysts

Transition Metal Reagents and Catalysts Book
Author : Jiro Tsuji
Publisher : John Wiley & Sons
Release : 2002-08-16
ISBN : 9780471560272
Language : En, Es, Fr & De

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Book Description :

Transition Metal Reagents and Catalysts Innovations in Organic Synthesis Jiro Tsuji Emeritus Professor, Tokyo Institute of Technology, Japan Numerous innovative and practical synthetic methods using transition metal complexes as either catalysts or reagents have been developed over the last 35 years. Transition Metal Reagents and Catalysts combines the varied applications of transition metal complexes in a unique and timely book in this rapidly advancing area of organic synthesis. This text is an easily understandable and enjoyable read for organic chemists who are not yet familiar with organo-transition metal chemistry. Transition Metal Reagents and Catalysts presents: * Complete coverage of nearly 35 years of transition metal complex chemistry * An in-depth treatment of many innovative synthetic methodologies * A rational classification of all reactions according to substrates and reaction mechanisms * Examples of important applications of transition metal catalysed reactions. A knowledge of organic synthesis using transition metal complexes is a must for all synthetic organic chemists. Written for chemists who wish to apply novel synthetic methods using transition metal complexes to solve problems in organic and pharmaceutical chemistry, such as synthesis of fine and bulk chemicals and natural products, Transition Metal Reagents and Catalysts is an essential reference source and an indispensible research companion.

Organotransition Metal Chemistry

Organotransition Metal Chemistry Book
Author : Anthony F. Hill,A. Hill
Publisher : Royal Society of Chemistry
Release : 2002
ISBN : 9780854046225
Language : En, Es, Fr & De

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Book Description :

What do a pharmaceutical, polymer and solid state chemist have in common? Organometallic chemistry of course, since progress in their diverse fields has at many times relied on this. It is a discipline which stands at the crossroads of so many branches of chemistry, with industrial applications ranging from the gram to megatonne scale. This book aims to introduce undergraduates to the utility of organotransition metal chemistry, a discipline of importance to scientists and technologists in a variety of industry sectors. The main focus will be on the reactivity of organometallic compounds of the transition metals, supported by discussion of structure and bonding and their implications. The aim, on completion of the course, is that a student will be equipped to recognize the key classes of organometallic compounds, their methods of characterization, possible synthetic routes and anticipated reactivity. Ideal for the needs of undergraduate chemistry students, Tutorial Chemistry Texts is a major series consisting of short, single topic or modular texts concentrating on the fundamental areas of chemistry taught in undergraduate science courses. Each book provides a concise account of the basic principles underlying a given subject, embodying an independent-learning philosophy and including worked examples.

Transition Metal Organometallics in Organic Synthesis

Transition Metal Organometallics in Organic Synthesis Book
Author : Howard Alper
Publisher : Academic Press
Release : 2016-01-21
ISBN : 148321592X
Language : En, Es, Fr & De

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Book Description :

Transition Metal Organometallics in Organic Synthesis, Volume II covers chapters on the applications of arene and alkyne complexes, as well as cluster compounds, in organic synthesis. The book discusses the potential utility of transition metal-alkyne complexes and derived cluster compounds as reagents in organic synthesis, as well as the complexation reactions of arenes. The text also describes the oxidation, reduction, rearrangement, and other synthetically useful processes. Chemists will find the book invaluable.

New Pathways for Organic Synthesis

New Pathways for Organic Synthesis Book
Author : H.M. Colquhoun,J. Holton,D.J. Thompson,M.V. Twigg
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 1461326516
Language : En, Es, Fr & De

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Book Description :

The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.

New Pathways for Organic Synthesis

New Pathways for Organic Synthesis Book
Author : H.M. Colquhoun,J. Holton,M.V. Twigg
Publisher : Springer
Release : 1984-01-31
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.

Organometallic Chemistry

Organometallic Chemistry Book
Author : Royal Society of Chemistry (Great Britain)
Publisher : Royal Society of Chemistry
Release : 2007
ISBN : 0854043489
Language : En, Es, Fr & De

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Book Description :

Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry.Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry.For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'.Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Organometallic Chemistry

Organometallic Chemistry Book
Author : Ian J. S. Fairlamb,Jason M. Lynam
Publisher : Royal Society of Chemistry
Release : 2012-06
ISBN : 1849733767
Language : En, Es, Fr & De

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Book Description :

A series of critical reviews and perspectives focussing on specific aspects of organometallic chemistry interfacing with other fields of study are provided. For this volume, the critical reviews cover topics such as the activation of "inert" carbon-hydrogen bonds, ligand design and organometallic radical species. For example, Charlie O'Hara discusses how mixed-metal compounds may perform the highly selective activation of C-H bonds and, in particular, how synergic relationships between various metals are crucial to this approach. The chemistry of a remarkable series of air-stable chiral primary phosphine ligands is discussed in some depth by Rachel Hiney, Arne Ficks, Helge M³ller-Bunz, Declan Gilheany and Lee Higham. This article focuses on the preparation of these ligands and also how they may be applied in various catalytic applications. Bas De Bruin reports on how ligand radical reactivity can be employed in synthetic organometallic chemistry and catalysis to achieve selectivity in radical-type transformations. As well as highlighting ligand-centered radical transformations in open-shell transition metals, an overview of the catalytic mechanism of Co(II)-catalysed olefin cyclopropanation is given, showing that enzyme-like cooperative metal-ligand-radical reactivity is no longer limited to real enzymes. Valuable and informative comprehensive reviews in the field of organometallic chemistry are also covered in this volume. For example, organolithium and organocuprate chemistry are reviewed by Joanna Haywood and Andrew Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by Mark Humphrey and Marie Cifuentes; and recent developments in the chemistry of the elements of Group 14 - focusing on low-coordination number compounds by Richard Layfield. This volume therefore covers many synthetic and applied aspects of modern organometallic chemistry which ought to be of interest to inorganic, organic and applied catalysis fields.

Organometallic Chemistry

Organometallic Chemistry Book
Author : I. Fairlamb,Jason M. Lynam
Publisher : Organometallic Chemistry
Release : 2009
ISBN : 9780854043583
Language : En, Es, Fr & De

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Book Description :

This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.

Pincer and Pincer Type Complexes

Pincer and Pincer Type Complexes Book
Author : Kálmán J. Szabó,Ola F. Wendt
Publisher : John Wiley & Sons
Release : 2014-06-10
ISBN : 3527681337
Language : En, Es, Fr & De

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Book Description :

This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis. A must-have for every synthetic chemist in both academia and industry intending to develop new catalysts and improved synthetic protocols.

Organometallic Chemistry

Organometallic Chemistry Book
Author : Hiroshi Nakazawa,Julian Koe
Publisher : Royal Society of Chemistry
Release : 2021-07-09
ISBN : 1839164212
Language : En, Es, Fr & De

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Book Description :

Designed for teaching, this English translation of the tried and tested Organometallic Chemistry 2/e textbook from the Japan Society of Coordination Chemistry can be used as an introductory text for chemistry undergraduates and also provide a bridge to more advanced courses. The book is split into two parts, the first acts as a concise introduction to the field, explaining fundamental organometallic chemistry. The latter covers cutting edge theories and applications, suitable for further study. Beginning with fundamental reaction patterns concerning bonds between transition metals and carbon atoms, the authors show how these may be combined to achieve a desired reaction and/or construct a catalytic cycle. To understand the basics and make effective use of the knowledge, numerous practice questions and model answers to encourage the reader’s deeper understanding are included. The advanced section covers the chemistry relating to bonds between transition metals and main group elements, such as Si, N, P, O and S, is described. This chemistry has some similarities to transition metal-carbon chemistry, but also many differences and unique aspects, which the book explains clearly. Organometallic complexes are now well known and widely used. In addition, transition metal complexes with main group element other than carbon as a ligating atom are becoming more important. It is thus important to have a bird’s-eye view of transition metal complexes, regardless of the ligand type. This book acts as solid introduction for chemistry students and newcomers in various fields who need to deal with transition metal complexes.

Principles of Organometallic Chemistry

Principles of Organometallic Chemistry Book
Author : G. E. Coates
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 9401096813
Language : En, Es, Fr & De

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Book Description :

The second edition of Organometallic Compounds (1960) was used not only by specialists but also as an undergraduate textbook. The third edition, recently published in two volumes, is about three times the length of the second and contains considerably more factual material than is appropriate for a student textbook. Therefore we believe that a shorter treatment would be welcome. In planning this book the authors have emphasized matters more of prin ciple than of detail, and have included in the first two chapters some general discussion of the properties and syntheses of organometallic compounds that is not to be found in the larger work. Some aspects of the organic chemistry of arsenic, and of silicon with particular reference to silicone polymers, are also included. Most university teachers of chemistry are becoming seriously concerned about the relentless increase in the amount and complexity of the material that is squeezed into undergraduate chemistry courses. With this in mind the authors have tried to cut detail to a minimum, but readers will find that the relative amount presented varies considerably between the various topics discussed. In general the treatment is more extensive than usual only if either or both of these conditions are met: (1), the subject has significant bearing on other major branches of chemistry including im portant industrial processes; (2), the topic is commonly misunderstood or found to be confusing.