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Organosilicon Compounds

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Organosilicon Compounds

Organosilicon Compounds Book
Author : Vladimir Ya Lee
Publisher : Academic Press
Release : 2017-08-22
ISBN : 0128019913
Language : En, Es, Fr & De

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Book Description :

Organosilicon Compounds: Theory and Experiment (Synthesis), volume 1, comprises two parts. The first part, Theory, covers state-of-the-art computational treatments of unusual nonstandard organosilicon compounds that classical bonding theory fails to describe adequately. The second part, Experiment (Synthesis), describes recent synthetic advances in the preparation of a variety of organosilicon compounds with different coordination numbers of the central silicon: from tetracoordinate to low-coordinate to hypercoordinate derivatives. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts that cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry Covers important breakthroughs in the field, along with the historically significant achievements of the past Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) Ideal reference for those working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields, such as polymer, material science, and nanotechnology

Organosilicon Compounds Two volume set

Organosilicon Compounds  Two volume set Book
Author : Vladimir Ya Lee
Publisher : Academic Press
Release : 2017-10-01
ISBN : 0128143630
Language : En, Es, Fr & De

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Book Description :

Organosilicon Compounds provides readers with the state-of-the-art status of organosilicon chemistry, including its theoretical, synthetic, physico-chemical and applied aspects. By including high quality content in a key strategic signing area, this work is a strong addition to chemistry offerings in organic, main group and organometallic research. Organosilicon chemistry deals with compounds containing carbon–silicon bonds, an essential part of organic and organometallic chemistry. This book presents the many milestone in the field that have been discovered during the last few years, also detailing its usage in commercial products, such as sealants, adhesives and coatings. Features valuable contributions from prominent experts who cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects Covers important breakthroughs in the field, along with historically significant achievements Includes applied information for a wide range of specialists, from junior and senior researchers (from both academia and industry) working in organometallic, organosilicon, main group element, transition metal, industrial silicon chemistry, and more

Silicon in Organic Synthesis

Silicon in Organic Synthesis Book
Author : Ernest W. Colvin
Publisher : Butterworth-Heinemann
Release : 2013-10-22
ISBN : 148314223X
Language : En, Es, Fr & De

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Book Description :

Silicon in Organic Synthesis provides an introduction to the organic chemistry of silicon. This book places particular emphasis on the concept of silicon as a “ferryman, mediating the transformation of one wholly organic molecule into another. The book begins by reviewing the discovery and development of organosilicon compounds. This is followed by separate chapters on the physical properties of organosilicon compounds; the preparation of α-metallated organosilanes, which play a key role in preparative organosilicon chemistry; migration/rearrangement reactions of silicon; the preparation and chemistry of vinylsilanes, allylsilanes, arylsilanes, and organosilyl metallic compounds. Subsequent chapters cover the synthesis of compounds such as alkene, alkynylsilanes, allenylsilanes, silylketenes, alkyl silyl ethers, acyloxysilanes, and silyl enol ethers. This book aims to serve as a timely introduction to organic chemistry for students and practitioners of synthetic organic chemistry, as well as provide a source of useful information and possibly of new ideas to those already experienced in the area.

Organometallic Compounds

Organometallic Compounds Book
Author : B. J. Aylett
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 9400957297
Language : En, Es, Fr & De

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Book Description :

A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.

Official Gazette of the United States Patent and Trademark Office

Official Gazette of the United States Patent and Trademark Office Book
Author : Anonim
Publisher : Unknown
Release : 2004
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Official Gazette of the United States Patent and Trademark Office book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Scientific and Technical Aerospace Reports

Scientific and Technical Aerospace Reports Book
Author : Anonim
Publisher : Unknown
Release : 1980
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Scientific and Technical Aerospace Reports book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Organosilicon Chemistry

Organosilicon Chemistry Book
Author : Stephan Pawlenko
Publisher : Walter de Gruyter
Release : 1986-01-01
ISBN : 3110862387
Language : En, Es, Fr & De

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Book Description :

Download Organosilicon Chemistry book written by Stephan Pawlenko, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Ruthenium Catalysts and Fine Chemistry

Ruthenium Catalysts and Fine Chemistry Book
Author : Christian Bruneau,Pierre H. Dixneuf
Publisher : Springer Science & Business Media
Release : 2004-06-30
ISBN : 9783540205432
Language : En, Es, Fr & De

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Book Description :

With contributions by numerous experts

Comprehensive Organometallic Analysis

Comprehensive Organometallic Analysis Book
Author : T.R. Crompton
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 1461594987
Language : En, Es, Fr & De

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Book Description :

It is now some sixteen years since the author's first series of books on the analysis of organometallic compounds. Many developments in the subject have occurred since that time and a new book on the subject is now overdue. The present book aims to provide a comprehensive review of the subject. It covers not only all aspects of the analysis of organometallic compounds but also contains two additional chapters, dealing with environmental analysis and the use of chelates of metals in the determination of very low concentrations of organic metals. Whilst reviewing the literature for the present book, it was observed that whereas papers published prior to 1973 dealt almost exclusively with various forms of analysis, a high proportion of those published during the past ten years were concerned with the application of proven or newly developed methods to the determination of organometallic compounds in environmental samples such as water, air, soil, river and ocean sediments, fish life and biota samples. An increasing range of elements including mercury, lead, arsenic, tin, antimony, selenium and manganese are now being found in organically bound forms in the environment, some resulting from pollution, others formed in nature by bacterial processes. As many of these substances have appreciable implications to human and animal health and the ecosystem as a whole, it was considered that it would be timely to include a separate chapter in the book devoted entirely to this subject.

The chemistry of organic silicon compounds

The chemistry of organic silicon compounds Book
Author : Saul Patai,Zvi Rappoport
Publisher : Unknown
Release : 1989
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download The chemistry of organic silicon compounds book written by Saul Patai,Zvi Rappoport, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Gas Chromatography of Organometallic Compounds

Gas Chromatography of Organometallic Compounds Book
Author : T. R. Crompton
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 1468442260
Language : En, Es, Fr & De

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Book Description :

Since its introduction into the armoury of the analytical chemist approximately two decades ago the technique of gas chroma tography has found very extensive applications in the analysis of most types of organic compounds. One of the few remaining limitations of the technique when applied to such compounds, namely the analysis of very highly boiling and or thermally unstable substances, has been overcome in many instances by the introduction of techniques such as silation for the conversion of sample components to lower boiling or more stable substances which can be gas chromatographed at reasonably low temperatures. All of this has been extensively dealt with in many books published during recent years dealing with the theory and practice of applying gas chromatography to the analysis and preparative separation of organic compounds. In parallel with these developments there has occurred, particu larly over the past decade, a growing interest in the application of gas chromatography to the analysis of organometallic compounds. Indeed, for many types of organometallic compounds, gas chromatography is the analytical method of choice particularly, as so often happens, when the sample is a mixture. To the author's knowledge no complete review exists of the published work in this very interesting new field; a situation it is hoped the present volume will rectify.

Organosilicon Compounds

Organosilicon Compounds Book
Author : Vladimir Ya Lee
Publisher : Academic Press
Release : 2017-09-25
ISBN : 0128142146
Language : En, Es, Fr & De

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Book Description :

Organosilicon Compounds: Experiment (Physico-Chemical Studies) and Applications, volume 2, also contains two parts. In its first part, Experiment (Physico-Chemical Studies), the application of modern instrumental tools (such as X-ray crystallography, 29Si NMR spectroscopy, UV-Photoelectron Spectroscopy, and other methods) for assessing the structures of organosilicon compounds is described. The second part, Applications, reviews the current research in the field of material science, specifically the use of organosilicon compounds in synthetic chemistry directed towards the creation of new materials. Organosilicon Compounds: From Theory to Synthesis to Applications provides a comprehensive overview of this important area of organic and organometallic chemistry, dealing with compounds containing carbon–silicon bonds. This field, which includes compounds that are widely encountered in commercial products such as in the fabrication of sealants, adhesives, and coatings, has seen many milestone discoveries reported during the last two decades. Beginning with the theoretical aspects of organosilicon compounds’ structure and bonding, the book then explores their synthetic aspects, including main group element organosilicon compounds, transition metal complexes, silicon cages and clusters, low-coordinate organosilicon derivatives (cations, radicals, anions, multiple bonds to silicon, silaaromatics), and more. Next, readers will find valuable sections that explore physical and chemical properties of organosilicon compounds by means of X-ray crystallography, 29Si NMR spectroscopy, photoelectron spectroscopy, and other methods. Finally, the work delves into applications for industrial uses and in many related fields, such as polymers, material science, nanotechnology, bioorganics, and medicinal silicon chemistry. Features valuable contributions from prominent experts cover both fundamental (theoretical, synthetic, physico-chemical) and applied (material science, applications) aspects of modern organosilicon chemistry Covers important breakthroughs in the field as well as with the historically significant achievements of the past Includes applied information for a wide range of specialists from junior and senior researchers (from both academia and industry), working in organometallic, organosilicon, main group element, transition metal, and industrial silicon chemistry, as well as those from interdisciplinary fields such as polymer, material science, nanotechnology

Organic Silicon Compounds

Organic Silicon Compounds Book
Author : Kuzʹma Andrianovich Andrianov
Publisher : Unknown
Release : 1955
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Organic Silicon Compounds book written by Kuzʹma Andrianovich Andrianov, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Basic Organometallic Chemistry

Basic Organometallic Chemistry Book
Author : Ionel Haiduc,Jerry J. Zuckerman
Publisher : Walter de Gruyter
Release : 1985-01-01
ISBN : 3110847884
Language : En, Es, Fr & De

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Book Description :

Download Basic Organometallic Chemistry book written by Ionel Haiduc,Jerry J. Zuckerman, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

The Chemistry of Organic Silicon Compounds Volume 2 Parts 1 2 and 3 3 Part Set

The Chemistry of Organic Silicon Compounds  Volume 2  Parts 1  2  and 3  3 Part Set  Book
Author : Zvi Rappoport,Yitzhak Apeloig,Saul Patai
Publisher : John Wiley & Sons
Release : 1998-09-16
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Organosilicon compounds are key organometallic compounds (R-Si)which have many uses in materials science and in metallurgy. Theirapplications include the synthesis of sugars and in the synthesisof organic compounds for the pharmaceutical industry. This volumewill contain both updated chapters on key topics included in theoriginal volumes as well as a number of new chapters reflecting therapid developments made in silicon chemistry and its applicationsto organometallic chemistry, materials science, and semiconductors,over the last five years. As for the majority of volumes in thisseries, chapters will be prepared by leading scientists in thefield. This volume is now available in electronic format from BooksOnline.

Chemistry and Technology of Silicones

Chemistry and Technology of Silicones Book
Author : Walter Noll
Publisher : Elsevier
Release : 2012-12-02
ISBN : 0323141404
Language : En, Es, Fr & De

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Book Description :

Chemistry and Technology of Silicones retains the nature of a monograph despite its expanded scope, giving the reader in condensed form not only a wide-ranging but also a thorough review of this rapidly growing field. In contrast to some other monographs on organosilicon compounds that have appeared in the interim, the silicones occupy in this edition the central position, and the technological part of the work is entirely devoted to them. This book comprises 12 chapters, and begins with a general discussion of the chemistry and molecular structure of the silicones. The following chapters then discuss preparation of silanes with nonfunctional organic substituents; monomeric organosilicon compounds RnSiX4-n; and organosilanes with organofunctional groups. Other chapters cover preparation of polyorganosiloxanes; the polymeric organosiloxanes; other organosilicon polymers; production of technical silicone products from polyorganosiloxanes; properties of technical products; applications of technical silicone products in various branches of industry; esters of silicic acid; and analytical methods. This book will be of interest to practitioners in the fields of molecular chemistry.

Vinyl Compounds Advances in Research and Application 2013 Edition

Vinyl Compounds   Advances in Research and Application  2013 Edition Book
Author : Anonim
Publisher : ScholarlyEditions
Release : 2013-06-21
ISBN : 1481693387
Language : En, Es, Fr & De

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Book Description :

Vinyl Compounds—Advances in Research and Application: 2013 Edition is a ScholarlyBrief™ that delivers timely, authoritative, comprehensive, and specialized information about ZZZAdditional Research in a concise format. The editors have built Vinyl Compounds—Advances in Research and Application: 2013 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about ZZZAdditional Research in this book to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Vinyl Compounds—Advances in Research and Application: 2013 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.

An Introduction Chemistry Of The Silicones

An Introduction Chemistry Of The Silicones Book
Author : Eugene G. Rochow
Publisher : Read Books Ltd
Release : 2013-04-16
ISBN : 1446546101
Language : En, Es, Fr & De

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Book Description :

The organic compounds of silicon, which have been the subject of many scholarly researches during the past 80 years, at last show promise of emerging from the laboratory and finding a place in industry. An understanding of the behaviour of organosilicon materials is necessary to their intelligent use and, inasmuch as the chemistry of these substances ordinarily is not treated in our textbooks, it is possible that a compact yet comprehensive survey of our present knowledge in this field would be of service to chemists, engineers, and industrial designers. This volume has just such a purpose. The first few chapters review the silanes and their derivatives in some detail, in order to provide an understanding of the fundamental chemistry of the nonsilicate compounds of silicon. The later chapters emphasize the silicone polymers which have achieved commercial importance and deal with the methods for their preparation, their chemical and physical properties, and their possible uses. The processes available for large-scale production are treated separately, and a review of methods of analysis is included.

Hydrosilylation

Hydrosilylation Book
Author : Bogdan Marciniec
Publisher : Springer Science & Business Media
Release : 2008-11-09
ISBN : 1402081723
Language : En, Es, Fr & De

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Book Description :

For fifty years, Hydrosilylation has been one of the most fundamental and elegant methods for the laboratory and industrial synthesis of organosilicon and silicon related compounds. Despite the intensive research and continued interest generated by organosilicon compounds, no comprehensive book incorporating its various aspects has been published this century. The aim of this book is to comprehensively review the advances of hydrosilylation processes since 1990. The survey of the literature published over the last two decades enables the authors to discuss the most recent aspects of hydrosilylation advances (catalytic and synthetic) and to elucidate the reaction mechanism for the given catalyst used and the reaction utilization. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. This monograph shows the extensive development in the application of hydrosilylation in organic and asymmetric syntheses and in polymer and material science.