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Organometallic Luminescence

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Organometallic Luminescence

Organometallic Luminescence Book
Author : Giuseppe Baldacchini
Publisher : Woodhead Publishing
Release : 2020-10-30
ISBN : 0128209305
Language : En, Es, Fr & De

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Book Description :

Organometallic Luminescence: A Case Study of Alq3, an OLED Reference Material contains many discoveries on Alq3, an important organometallic material to the optoelectronics community that includes insights that can be applied to other organic compounds. The book contains groundbreaking research from the author’s own investigation into the Alq3 material that is based on years of experiments, the results of which initially escaped any logical explanation. The book describes a simple method based on photoluminescence to observe optical properties in Alq3, also covering the optical properties of absorption and long decay from theoretical and experimental perspectives. Considers both theoretical and experimental measurements and an analysis of the optical properties of a key OLED reference material Includes detailed experimental data and a large number of tables and figures Describes and applies the photoluminescence method of considering the optical properties of Alq3 that can be applied to other optoelectronics materials

Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells

Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells Book
Author : Kenneth Kam-Wing Lo
Publisher : Academic Press
Release : 2016-12-30
ISBN : 012803887X
Language : En, Es, Fr & De

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Book Description :

Inorganic and Organometallic Transition Metal Complexes with Biological Molecules and Living Cells provides a complete overview of this important research area that is perfect for both newcomers and expert researchers in the field. Through concise chapters written and edited by esteemed experts, this book brings together a comprehensive treatment of the area previously only available through scattered, lengthy review articles in the literature. Advanced topics of research are covered, with particular focus on recent advances in the biological applications of transition metal complexes, including inorganic medicine, enzyme inhibitors, antiparasital agents, and biological imaging reagents. Geared toward researchers and students who seek an introductory overview of the field, as well as researchers working in advanced areas Focuses on the interactions of inorganic and organometallic transition metal complexes with biological molecules and live cells Foscuses on the fundamentals and their potential therapeutic and diagnostic applications Covers recent biological applications of transition metal complexes, such as anticancer drugs, enzyme inhibitors, bioconjugation agents, chemical biology tools, and bioimaging reagents

Spectroscopic Properties of Inorganic and Organometallic Compounds

Spectroscopic Properties of Inorganic and Organometallic Compounds Book
Author : Jack Yarwood,Richard Douthwaite,Simon Duckett
Publisher : Royal Society of Chemistry
Release : 2010-08-01
ISBN : 1849730857
Language : En, Es, Fr & De

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Book Description :

Spectroscopic Properties of Inorganic and Organometallic Compounds: Techniques, Materials and Applications provides a unique source of information in an important area of chemistry.

Organometallic Magnets

Organometallic Magnets Book
Author : Vadapalli Chandrasekhar,Fabrice Pointillart
Publisher : Springer Nature
Release : 2019-11-22
ISBN : 3030260097
Language : En, Es, Fr & De

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Book Description :

This volume highlights the recent advances and state of art in the experimental and theoretical studies of organometallic magnets. A plethora of organic ligands such as Mannich-base derivatives, redox-active chromophores, cyanides, Schiff base among others are used to coordinate to 3d transition metals, 4f lanthanides and 5f actinides to design the molecular magnets. Deep analysis of the coordination sphere symmetry, electronic distribution, luminescence are investigated to perform magneto-structural correlation leading to a better understanding of the magnetic properties. Furthermore, the rationalization of the magnetic behavior can be reached using ab initio calculations. The multiple applications that these molecular magnets offer could revolutionize the high-density data storage, spintronics and quantum computing technologies. This volume provides a discussion of these topics from leading international experts and will be a useful reference for researchers working in this field.

Molecular Organometallic Materials for Optics

Molecular Organometallic Materials for Optics Book
Author : Zuqiang Bian
Publisher : Springer Science & Business Media
Release : 2009-11-10
ISBN : 3642018653
Language : En, Es, Fr & De

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Book Description :

Aimed at a multidisciplinary scientific readership, this publication covers a number of specific topics in what is now a rapidly developing field, including coordination and organometallic complexes as second-order nonlinear optical molecular materials.

Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds

Photosensitization and Photocatalysis Using Inorganic and Organometallic Compounds Book
Author : K. Kalyanasundaram,M. Grätzel
Publisher : Springer Science & Business Media
Release : 1993-05-31
ISBN : 9780792322610
Language : En, Es, Fr & De

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Book Description :

Photosensitization and photocatalysis refer to processes by which permanent chemical transformations are induced on substrates (organic/inorganic) by radiation to which the substrates themselves are transparent. Such transformations can be highly specific, very efficient, and occur under mild conditions. Herein lies the power of photochemical methods for possible applications in the field of conversion and storage of solar energy. This book provides a recent survey of the progress in this important area in catalysis, with an emphasis on inorganic complexes and organometallic compounds as the key light aborbers. The book is organized in three parts: fundamentals, followed by applications. Discussions cover a wide variety of photosensitized or photocatalyzed reactions: decomposition of water, reduction of CO2 and CO; spectral sensitization in photoelectrochemical cells; transformations (oxidation, reduction, isomerization, hydrogenation, dehydrogenation, carbonylation, etc.) of organics such as alkanes, alkenes, alcohols, etc. In view of the variety of systems (sensitizers, substrates) and the topics covered, the volume is unique in the field of photochemistry and will appeal to academic and industrial researchers in various subdisciplines of chemistry, material science and catalysis.

Organometallic Pincer Chemistry

Organometallic Pincer Chemistry Book
Author : Gerard van Koten,David Milstein
Publisher : Springer
Release : 2012-09-17
ISBN : 3642310818
Language : En, Es, Fr & De

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Book Description :

Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of 13 - 15 Main Group Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in Organic Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications.- Jennifer Hawk and Steve Craig: Physical Applications of Pincer Complexes.

Advances in Organometallic Chemistry

Advances in Organometallic Chemistry Book
Author : N.A
Publisher : Academic Press
Release : 1995-10-20
ISBN : 9780080580395
Language : En, Es, Fr & De

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Book Description :

This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. In basic research, organometallics have contributed inter alia to: Metal cluster chemistry Surface chemistry The stabilization of highly reactive species by metal coordination Chiral synthesis The formulation of multiple bonds between carbon and the other elements and between the elements themselves

Luminescent Organometallic Nanomaterials with Aggregation Induced Emission

Luminescent Organometallic Nanomaterials with Aggregation Induced Emission Book
Author : N.A
Publisher :
Release : 2018
ISBN :
Language : En, Es, Fr & De

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Book Description :

ABSTRACT: Recent researches in metal nanoclusters (NCs) have prompted their promising practical applications in biomedical fields as novel inorganic luminophores. More recently, to further improve the photoluminescence (PL) performance of NCs, the aggregation-induced emission (AIE) effect has been introduced to develop highly luminescent metal NCs and metal complex materials. In this review, we start our discussion from recent progresses on AIE materials developments. Then, we address our understandings on the PL properties of thiolated metal NCs. Subsequently, we link thiolated metal NCs with AIE effect. We also highlight some recent advances in synthesizing the AIE-type metal complex nanomaterials. We finally discuss visions and directions for future development of AIE-type metal complex nanomaterials.

Inorganic and Organometallic Macromolecules

Inorganic and Organometallic Macromolecules Book
Author : Alaa S. Abd-El-Aziz,Charles E. Carraher,Charles U. Pittman,Martel Zeldin
Publisher : Springer Science & Business Media
Release : 2007-12-19
ISBN : 9780387729473
Language : En, Es, Fr & De

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Book Description :

This important work is based on the editors’ symposium at the 2005 ACS meeting in Washington, DC. The contents include an emphasis on main-group polymers, including boron. The chapters are not simply journal articles, but have real added value as the editors have reviewed the general area by placing the work into a larger perspective. This book will be required reading for scientists in a number of disciplines including chemical engineers and physics researchers.

Spectroscopic Properties of Inorganic and Organometallic Compounds

Spectroscopic Properties of Inorganic and Organometallic Compounds Book
Author : Richard Douthwaite,Simon Duckett ,Jack Yarwood
Publisher : Royal Society of Chemistry
Release : 2014-07-30
ISBN : 1849739196
Language : En, Es, Fr & De

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Book Description :

This series provides an unequalled source of information on an area of chemistry that continues to grow in importance. Divided into sections mainly according to the particular spectroscopic technique used, coverage in each volume includes: NMR (with reference to stereochemistry, dynamic systems, paramagnetic complexes, solid state NMR and Groups 13-18); nuclear quadrupole resonance spectroscopy; vibrational spectroscopy of main group and transition element compounds and coordinated ligands; and electron diffraction. Reflecting the growing volume of published work in the field, researchers will find this an invaluable source of information on current methods and applications.

Organometallic Chemistry

Organometallic Chemistry Book
Author : Ian J. S. Fairlamb,Jason M. Lynam
Publisher : Royal Society of Chemistry
Release : 2012-06-01
ISBN : 1849733767
Language : En, Es, Fr & De

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Book Description :

A series of critical reviews and perspectives focussing on specific aspects of organometallic chemistry interfacing with other fields of study are provided. For this volume, the critical reviews cover topics such as the activation of "inert" carbon-hydrogen bonds, ligand design and organometallic radical species. For example, Charlie O'Hara discusses how mixed-metal compounds may perform the highly selective activation of C-H bonds and, in particular, how synergic relationships between various metals are crucial to this approach. The chemistry of a remarkable series of air-stable chiral primary phosphine ligands is discussed in some depth by Rachel Hiney, Arne Ficks, Helge M ller-Bunz, Declan Gilheany and Lee Higham. This article focuses on the preparation of these ligands and also how they may be applied in various catalytic applications. Bas De Bruin reports on how ligand radical reactivity can be employed in synthetic organometallic chemistry and catalysis to achieve selectivity in radical-type transformations. As well as highlighting ligand-centered radical transformations in open-shell transition metals, an overview of the catalytic mechanism of Co(II)-catalysed olefin cyclopropanation is given, showing that enzyme-like cooperative metal-ligand-radical reactivity is no longer limited to real enzymes. Valuable and informative comprehensive reviews in the field of organometallic chemistry are also covered in this volume. For example, organolithium and organocuprate chemistry are reviewed by Joanna Haywood and Andrew Wheatley; aspects in Group 2 (Be-Ba) and Group 12 (Zn-Hg) compounds by Robert Less, Rebecca Melen and Dominic Wright; metal clusters by Mark Humphrey and Marie Cifuentes; and recent developments in the chemistry of the elements of Group 14 - focusing on low-coordination number compounds by Richard Layfield. This volume therefore covers many synthetic and applied aspects of modern organometallic chemistry which ought to be of interest to inorganic, organic and applied catalysis fields."

Photophysics of Organometallics

Photophysics of Organometallics Book
Author : Alistair J. Lees
Publisher : Springer Science & Business Media
Release : 2010-02-04
ISBN : 3642047289
Language : En, Es, Fr & De

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Book Description :

Arvind Kumar, Shih-Sheng Sun, and Alistair J. Lees: Photophysics and Photochemistry of Organometallic Rhenium Diimine Complexes; Conor Long: Photophysics of CO Loss from Simple Metal Carbonyl Complexes; Antonín Vlcek Jr: Ultrafast Excited-State Processes in Re(I) Carbonyl-Diimine Complexes: From Excitation to Photochemistry; Kenneth Kam-Wing Lo: Exploitation of Luminescent Organometallic Rhenium(I) and Iridium(III) Complexes in Biological Studies; Maria L. Muro , Aaron A. Rachford , Xianghuai Wang, and Felix N. Castellano: Platinum II Acetylide Photophysics; Andreas F. Rausch, Herbert H. H. Homeier, and Hartmut Yersin: Organometallic Pt(II) and Ir(III) Triplet Emitters for OLED Applications and the Role of Spin–Orbit Coupling: A Study Based on High-Resolution Optical Spectroscopy.

Organometallic and Coordination Clusters and Polymers

Organometallic and Coordination Clusters and Polymers Book
Author : Alaa S. Abd-El-Aziz,Pierre D. Harvey
Publisher : Weinheim, Germany : Wiley-VCH
Release : 2004
ISBN :
Language : En, Es, Fr & De

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Book Description :

This volume is a compilation of articles written by some of the leading scientists presented at the Organometallic and Coordination Clusters and Polymers: Syntheses and Applications Symposium, the 87th Canadian Chemistry Conference and Exhibition in May, 2004, in London, Ontario, Canada.

Organometallic Chemistry

Organometallic Chemistry Book
Author : Royal Society of Chemistry,M. Green
Publisher : Royal Society of Chemistry
Release : 2001
ISBN : 9780854043286
Language : En, Es, Fr & De

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Book Description :

This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.

Comprehensive Organometallic Chemistry III

Comprehensive Organometallic Chemistry III Book
Author : N.A
Publisher : Elsevier Science
Release : 2006-12-26
ISBN : 9780080445908
Language : En, Es, Fr & De

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Book Description :

Comprehensive Organometallic Chemistry, (COMC-III), Third Edition, 13 Volume Set is aimed at the specialist and non-specialist alike. It covers the major developments in the field in a carefully presented way with extensive cross-references. COMC-III provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field over the next ten years. Applications of organometallic chemistry continue to expand and this has been reflected by the significant increase in the number of volumes devoted to applications in COMC-III. Organic chemists have edited the volumes on organometallic chemistry towards organic synthesis - this is now organized by reaction type so as to be readily accessible to the organic community. Like its predecessors, COMC (1982) and COMC-II (1995), this new work is the essential reference text for any chemist or technologist who needs to use or apply organometallic compounds. Also available online via ScienceDirect (2006) - featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. Presents a comprehensive overview of the major developments in the field since 1993 providing general and significant insights Highlights the expansion of applications in organometallic chemistry with a strong organic synthesis focus Provides a structured first point of entry to the key literature and background material for those planning research, teaching and writing about the area