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Modern Synthesis Processes And Reactivity Of Fluorinated Compounds

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Modern Synthesis Processes and Reactivity of Fluorinated Compounds

Modern Synthesis Processes and Reactivity of Fluorinated Compounds Book
Author : Henri Groult,Frederic Leroux,Alain Tressaud
Publisher : Elsevier
Release : 2016-11-04
ISBN : 0128037903
Language : En, Es, Fr & De

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Book Description :

Modern Synthesis Processes and Reactivity of Fluorinated Compounds focuses on the exceptional character of fluorine and fluorinated compounds. This comprehensive work explores examples taken from all classes of fluorine chemistry and illustrates the extreme reactivity of fluorinating media and the peculiar synthesis routes to fluorinated materials. The book provides advanced and updated information on the latest synthesis routes to fluorocompounds and the involved reaction mechanisms. Special attention is given to the unique reactivity of fluorine and fluorinated media, along with the correlation of those properties to valuable applications of fluorinated compounds. Contains quality content edited, and contributed, by leading scholars in the field Presents applied guidance on the preparation of original fluorinated compounds, potentially transferable from the lab scale to industrial applications Provides practical synthesis information for a wide audience interested in fluorine compounds in many branches of chemistry, materials science, and physics

Fluorine in Life Sciences Pharmaceuticals Medicinal Diagnostics and Agrochemicals

Fluorine in Life Sciences  Pharmaceuticals  Medicinal Diagnostics  and Agrochemicals Book
Author : Gunter Haufe,Frederic Leroux
Publisher : Academic Press
Release : 2018-09-19
ISBN : 0128127341
Language : En, Es, Fr & De

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Book Description :

Fluorine in Life Sciences: Pharmaceuticals, Medicinal Diagnostics and Agrochemicals, volume four in Alain Tressaud’s Progress in Fluorine Science series, presents a critical, multidisciplinary overview of the contributions of fluorinated products to solve important global issues in various life science fields, particularly in medicinal chemistry, molecular imaging techniques and agriculture. Edited by recognized experts, this book provides unique coverage of the wide-ranging uses and implications of fluorine and fluorinated compounds. Topics include medicinal monitoring and diagnosis, 19F MRI in medicine and in vivo cell tracking, 18F-labeled radiopharmaceuticals, brain imaging and neurology, risk assessment of reactive metabolites in drug discovery, and more. Edited by Alain Tressaud, past Chair and founder of the CNRS French Fluorine Network, each book in the collection also includes the work of highly-respected volume editors and contributors from both academia and industry who bring valuable and varied content to this active field. Covers a wide range of topics - from organic and physical chemistry, to pharmaceuticals, agrochemicals and medical diagnostics Describes major modern syntheses and unique reaction mechanisms yielding fluorine compounds in these diverse life science settings Features contributions from a wealth of global experts Acts as the fourth volume in Alain Tressaud’s Progress in Fluorine Science

Organic Reactions

Organic Reactions Book
Author : Anonim
Publisher : John Wiley & Sons
Release : 2019-11-19
ISBN : 1119456665
Language : En, Es, Fr & De

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Book Description :

Written by a "who is who" of leading organic chemists, this anniversary volume represent the Organic Reactions editors' choice of the most important, ground-breaking and versatile reactions in current organic synthesis. The 15 reaction types selected for this volume include reactions for carbon-carbon bond formation, cross-coupling reactions, hydro- and halofunctionalizations, among many others. In line with the successful recipe of the series, each chapter is focused on a single reaction, discussing its mechanism and stereochemistry, scope and limitations, applications to synthesis, comparison with other methods, and experimental procedures. Each chapter concludes with a tabular survey of selected key application examples, complete with reported reaction conditions and yields, to serve as a quick reference guide for synthesis planning.

Flow Chemistry Fundamentals

Flow Chemistry     Fundamentals Book
Author : Ferenc Darvas,György Dormán,Volker Hessel,Steven V. Ley
Publisher : Walter de Gruyter GmbH & Co KG
Release : 2021-10-25
ISBN : 3110693674
Language : En, Es, Fr & De

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Book Description :

The fully up-dated edition of the two-volume work covers both the theoretical foundation as well as the practical aspects. Presenting the complete insight into driving a chemical reaction provides a deep understanding for new potential technologies. Updated overview on devices and new key concepts of experimental procedures. Vol. 2: Applications.

Proceedings of 6th International Conference and Exhibition on Materials Science and Chemistry 2018

Proceedings of 6th International Conference and Exhibition on Materials Science and Chemistry 2018 Book
Author : ConferenceSeries
Publisher : ConferenceSeries
Release : 2021-12-08
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

May 17-18, 2018 Rome, Italy Key Topics : Materials Science and Chemistry, Materials Science and Engineering, Materials Chemistry in Developing Areas, Materials Synthesis and Characterization, Analytical Techniques and Instrumentation in Materials Chemistry, Polymeric Materials, Nanomaterials, Inorganic Materials Chemistry, Organic Materials Chemistry, Applied Materials Chemistry, Materials Chemistry and Physics, Science and Technology of Advanced Materials,

Organic and Inorganic Fluorine Chemistry

Organic and Inorganic Fluorine Chemistry Book
Author : Axel Haupt
Publisher : Walter de Gruyter GmbH & Co KG
Release : 2021-03-22
ISBN : 3110659336
Language : En, Es, Fr & De

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Book Description :

This textbook provides a comprehensive overview of synthesis protocols for organic and inorganic fluorinated compounds. Electrochemical fluorination, nucleophilic, radical and electrophilic addition is discussed. Applications of organofluorine compounds, main group fluorides and metal fluorides in pharmaceuticals, electronic devices and medical diagnostics is covered. Each chapter will be followed by exercises covering the topics.

Emerging Fluorinated Motifs

Emerging Fluorinated Motifs Book
Author : Dominique Cahard,Jun-An Ma
Publisher : John Wiley & Sons
Release : 2020-04-03
ISBN : 3527824324
Language : En, Es, Fr & De

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Book Description :

A must-have resource for all the researchers working in the organofluorine and related fields This timely two-volume set uniquely focuses on emerging fluorinated motifs beyond R-CF3 and R-F, like R-CF2H, R-OCF3, R-SCF3 and R-SF5. It also offers descriptions of the properties, synthesis, and applications of these emerging fluorinated motifs in order to help readers design new chemical entities, while providing new interest for researchers in organofluorine chemistry and new tools for those in other areas. Emerging Fluorinated Motifs: Synthesis, Properties and Applications begins with a description of carbon-linked fluorine-containing groups that include monofluoromethyl and difluoromethyl groups. It then details combinations of heteroatoms, Oxygen, Sulfur, Selenium, Nitrogen, and Phosphorus with fluorine-containing groups, outlining subsections of the most popular current motifs. Fluoroalkyl ethers, thioethers, and the recent blossoming of the SF5 unit is covered. Other chapters look at: selenium-linked fluorine-containing motifs; construction of N?CF2H, N?CF3, N?CH2CF3 motifs; and the synthesis and applications of P¿Rf-containing molecules. -Focuses on the synthesis, properties, and applications of emerging fluorinated motifs -Covers carbon-linked fluorine-containing motifs, oxygen-linked fluorine-containing motifs, sulfur-linked fluorine-containing motifs, and more -Appeals to academic and industrial researchers working in organic chemistry, medicinal chemistry, food chemistry, and materials science -Edited by world-renowned experts in organofluorine chemistry Emerging Fluorinated Motifs is intended for academic research institutes, university libraries, researchers, graduate students, postdoctors, and researchers in the chemical industry.

The Curious World of Fluorinated Molecules

The Curious World of Fluorinated Molecules Book
Author : Konrad Seppelt
Publisher : Elsevier
Release : 2020-10-30
ISBN : 0128198753
Language : En, Es, Fr & De

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Book Description :

The Curious World of Fluorinated Molecules: Molecules Containing Fluorine is the sixth volume in the Progress in Fluorine Science series and is edited by the world-renowned scientist Konrad Seppelt. Dr. Seppelt brings together a team of global experts to uncover the multifaceted nature of the most electronegative element in the Periodic Table. The book explores the fascinating world of unpredictable, fluorine-containing molecules through their discoveries, path to recognition, current state of the art, and impact on the broader fields of fluorinated materials development. This volume will inspire and energize researchers, future scientists, and educators working in fluorine chemistry. Highlights the current state of fundamental research of fluorinated molecules that either helped to rewrite the fundamental rules of chemistry or impacted modern material technologies Features contributions from a global team of leading experts in the field Provides a unique combination of the historical and current examples that explain the unique role that fluorine can play in advancing our understanding of the scientific method at large

Organofluorine Chemistry

Organofluorine Chemistry Book
Author : Kalman J. Szabo,Nicklas Selander
Publisher : John Wiley & Sons
Release : 2021-01-05
ISBN : 3527825142
Language : En, Es, Fr & De

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Book Description :

By presenting novel methods for the efficient preparation of fluorinated compounds and their application in pharmaceutical and agrochemical chemistry as well as medicine, this is a valuable source of information for all researchers in academia and industry!

Chemistry of Organic Fluorine Compounds

Chemistry of Organic Fluorine Compounds Book
Author : Milos Hudlicky,Attila E. Pavlath
Publisher : Wiley-VCH
Release : 1995-08
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Provides complete coverage of the chemistry of organic fluorine compounds. Topics include fluorinating agents, fluorination processes, reactions of fluorinated compounds, modern analytical methods, and properties and applications of fluorinated compounds. Offers a critical review of the literature and provides over 4,500 references. Updates the 1976 volume Chemistry of Organic Fluorine Compounds.

Fluorine

Fluorine Book
Author : Alain Tressaud
Publisher : Academic Press
Release : 2018-10-06
ISBN : 0128129913
Language : En, Es, Fr & De

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Book Description :

Fluorine: A Paradoxical Element, Volume Five, deals with the link between fluorine, humanity and the environment. It is divided into three main sections, including i) The history and developmental stages of fluorinated products, ii) Awareness of its importance in our environment, and iii) Recent contributions of fluoride products in medicine, pharmacy and our daily lives. Made engaging through interesting figures and accessible language, and written by a leading expert, Professor Tressaud, the book supports the work of scientists working in materials, toxicology and environmental science. It complements the author’s edited series, Progress in Fluorine Science, covering recent advances. Describes background and contextual information regarding the history, development of understanding, and applications of this important element Explores the impacts of fluorine, both positive and negative, in the environment and biological systems Includes applied, real-world information from agencies, such as CNRS, NASA, HWS and DOH

Aromatic Fluorination

Aromatic Fluorination Book
Author : James H. Clark
Publisher : CRC Press
Release : 2018-01-10
ISBN : 1351086782
Language : En, Es, Fr & De

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Book Description :

Academia and industry join forces in Aromatic Fluorination, as an expert from each domain contributes to this new text on fluorination of carbocyclic and heterocyclic rings. The book begins with a discussion of fluorine's unique combination of properties, including size, electronic effects, and hydrophobicity, as well as the historical development of its product applications. It explains methods for introducing fluorine into an aromatic ring, focusing on nucleophilic fluorine transfer reactions. The role of catalysts, solvents, and other variables are examined, and the scope and limitations of the methods are discussed. Of particular interest to those working in non-specialist laboratories, Aromatic Fluorination includes detailed descriptions of the new electrophilic routes to fluoroaromatics, in addition to traditional routes and alternative methods involving radical chemistry. Because one of the most important fluorine-containing substituent is CF3, the book explains routes to benzotrifluorides (ArCF3), including traditional industrial methods and modern alternatives employing C-1 halofluorocarbons and other fluoroaliphatics. An alternative to CF3 is CF3S, and several methods of synthesizing aromatic CF3S-containing molecules are described. Since the successful development and diverse applications of aromatic fluorine compounds have led to the search for new compounds and novel substituents, the incorporation of other substituents is also explored. Aromatic Fluorination concludes with discussion of the factors responsible for the successful development of pharmaceutical, agrochemical and liquid crystal applications and the potential for applications in high-performance polymers and other areas. This section also describes in detail important industrial aromatic fluorination processes and the relative merits of different process technologies and their costs.

Modern Fluoroorganic Chemistry

Modern Fluoroorganic Chemistry Book
Author : Peer Kirsch
Publisher : John Wiley & Sons
Release : 2006-03-06
ISBN : 3527604197
Language : En, Es, Fr & De

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Book Description :

In this handbook, Peer Kirsch clearly shows that this exciting field is no longer an exotic area of research. Aimed primarily at synthetic chemists wanting to gain a deeper understanding of the fascinating implications of including the highly unusual element fluorine in organic compounds, the main part of the book presents a wide range of synthetic methodologies and the experimental procedures selected undeniably show that this can be done with standard laboratory equipment. To round off, the author looks at fluorous chemistry and the applications of organofluorine compounds in liquid crystals, polymers and more besides. This long-awaited book represents an indispensable source of high quality information for everyone working in the field.

Fluoropolymers 1

Fluoropolymers 1 Book
Author : Gareth G. Hougham,Patrick E. Cassidy,Ken Johns,Theodore Davidson
Publisher : Springer Science & Business Media
Release : 2006-04-11
ISBN : 0306469189
Language : En, Es, Fr & De

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Book Description :

The fluorine atom, by virtue of its electronegativity, size, and bond strength with carbon, can be used to create compounds with remarkable properties. Small molecules containing fluorine have many positive impacts on everyday life of which blood substitutes, pharmaceuticals, and surface modifiers are only a few examples. Fluoropolymers, too, while traditionally associated with extreme hi- performance applications have found their way into our homes, our clothing, and even our language. A recent American president was often likened to the tribology of PTFE. Since the serendipitous discovery of Teflon at the Dupont Jackson Laboratory in 1938, fluoropolymers have grown steadily in technological and marketplace importance. New synthetic fluorine chemistry, new processes, and new apprec- tion of the mechanisms by which fluorine imparts exceptional properties all contribute to accelerating growth in fluoropolymers. There are many stories of harrowing close calls in the fluorine chemistry lab, especially from the early years, and synthetic challenges at times remain daunting. But, fortunately, modern techniques and facilities have enabled significant strides toward taming both the hazards and synthetic uncertainties. In contrast to past environmental problems associated with fluorocarbon refrigerants, the exceptional properties of fluorine in polymers have great environmental value. Some fluoropolymers are enabling green technologies such as hydrogen fuel cells for automobiles and oxygen-selective membranes for cleaner diesel combustion.

Fluorine containing Amino Acids

Fluorine containing Amino Acids Book
Author : Valery P. Kukhar,Valeriĭ Pavlovich Kukharʹ,Vadim A. Soloshonok
Publisher : Wiley-Blackwell
Release : 1995-04-06
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

In recent years, organo-fluorine chemistry has made a marked impact on the design and synthesis of a large variety of biologically active molecules, such as steroids, carbohydrates, amines, amino acids, peptides and other natural products. Naturally occurring amino acids play a pivotal role in living systems, and therefore synthetic fluorine-containing amino acids have been of significant interest to researchers working towards the understanding and modification of physiological processes. Fluorine-containing Amino Acids: is the first volume devoted to the synthesis and properties of fluorine-containing amino acids pays special attention to the preparation of enantiomerically pure acids (which are essential to the modern pharmaceutical industry) deals with a rapidly expanding field of research has been written by experienced researchers who are responsible for many developments in the field highlights the interdisciplinary nature of this topic Fluorine-containing Amino Acids is the only dedicated reference in this subject and will be essential for researchers in synthetic organic, peptide, natural product, and medicinal chemistry and biochemistry.

Catalog Handbook of Fine Chemicals

Catalog Handbook of Fine Chemicals Book
Author : Aldrich Chemical Company
Publisher : Unknown
Release : 2003
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Catalog Handbook of Fine Chemicals book written by Aldrich Chemical Company, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Late Stage Fluorination of Bioactive Molecules and Biologically Relevant Substrates

Late Stage Fluorination of Bioactive Molecules and Biologically Relevant Substrates Book
Author : Al Postigo
Publisher : Elsevier
Release : 2018-09-05
ISBN : 0128130393
Language : En, Es, Fr & De

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Book Description :

Late-Stage Fluorination of Bioactive Molecules and Biologically-Relevant Substrates reviews how the use of these techniques on compounds with already known and relevant biological activity can provide new pharmaceutical leads with improved medicinal properties. The fluorination strategies discussed take into account both conventional and novel reagents, including nucleophilic, electrophilic, those of a radical nature, and diverse families of organic compounds, such as (hetero) aromatic rings and aliphatic substrates. Drawing on the authors' expert knowledge, this book provides researchers with a broad set of applicable methods to use in their work. Highlights the latest developments in the field in a concise volume Provides details of key fluorinating reagents across diverse families of organic compounds Explores the current applications and future potential of fluorine in drug development

Modern Phosphonate Chemistry

Modern Phosphonate Chemistry Book
Author : Philippe Savignac,Bogdan Iorga
Publisher : CRC Press
Release : 2003-04-28
ISBN : 0203503678
Language : En, Es, Fr & De

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Book Description :

A century after their discovery, phosphonates have become important compounds recognized both for their use as efficient reagents in organic synthesis and for their biological and industrial importance. This unique, up-to-date reference presents a concise summary of the state of the art in phosphonate chemistry, covering the role of phosphonates in

Well Architectured Fluoropolymers Synthesis Properties and Applications

Well Architectured Fluoropolymers  Synthesis  Properties and Applications Book
Author : Bruno Ameduri,Bernard Boutevin
Publisher : Elsevier
Release : 2004-07-07
ISBN : 0080474829
Language : En, Es, Fr & De

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Book Description :

Because of the increasing need for ever better performing materials endowed with specific properties, macromolecular engineering has become a useful tool for designing well-architectured polymers (telomers, telechelics, stars, dendrimers, alternating, block- and graftcopolymers). These polymers are nowadays seeing an enormous growth. Among them, fluoropolymers are seen as high value added materials in many applications ranging from surfactants, optical fibers, biomaterials, coatings, to membranes for fuel cells. Indeed, the relationship between structure of the monomer to the properties of the polymers is of increasing interest so that these properties are tuned for the most appropriate applications. As most fluoropolymers are prepared from radical synthesis, this book devotes various parts on the use of the controlled radical (or pseudo-living) polymerisation of fluoromonomers leading to discoveries of thermoplastic elastomers or original surfactants for polymerisation in supercritical CO2. Well-Architectured Fluoropolymers: Synthesis, Properties and Applications is composed of five chapters starting with a general introduction outlining basic concepts. Emphasis is placed on recent developments, and each chapter describes comprehensive techniques of synthesis of well-defined fluorotelomers or polymers, their properties, characterisations, and their applications, for immediate use by today’s engineers, industrial and academic scientists, and researchers. The book has been arranged to enable self-managed reading and learning. It is both a source of data and a reference. On the synthesis, properties and applications of fluoropolymers: remarkable, high value added materials applied in surfactants, optical fibres, biomaterials, coatings and membranes for fuel cells For immediate use by today's engineers, industrial and academic scientists, and researchers Written to enable self-managed reading and learning, being both a source of data and a reference