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Materials Kinetics

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Materials Kinetics

Materials Kinetics Book
Author : John C. Mauro
Publisher : Elsevier
Release : 2020-11-22
ISBN : 0128242167
Language : En, Es, Fr & De

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Book Description :

Materials Kinetics: Transport and Rate Phenomena provides readers with a clear understanding of how physical-chemical principles are applied to fundamental kinetic processes. The book integrates advanced concepts with foundational knowledge and cutting-edge computational approaches, demonstrating how diffusion, morphological evolution, viscosity, relaxation and other kinetic phenomena can be applied to practical materials design problems across all classes of materials. The book starts with an overview of thermodynamics, discussing equilibrium, entropy, and irreversible processes. Subsequent chapters focus on analytical and numerical solutions of the diffusion equation, covering Fick’s laws, multicomponent diffusion, numerical solutions, atomic models, and diffusion in crystals, polymers, glasses, and polycrystalline materials. Dislocation and interfacial motion, kinetics of phase separation, viscosity, and advanced nucleation theories are examined next, followed by detailed analyses of glass transition and relaxation behavior. The book concludes with a series of chapters covering molecular dynamics, energy landscapes, broken ergodicity, chemical reaction kinetics, thermal and electrical conductivities, Monte Carlo simulation techniques, and master equations. Covers the full breadth of materials kinetics, including organic and inorganic materials, solids and liquids, theory and experiments, macroscopic and microscopic interpretations, and analytical and computational approaches Demonstrates how diffusion, viscosity microstructural evolution, relaxation, and other kinetic phenomena can be leveraged in the practical design of new materials Provides a seamless connection between thermodynamics and kinetics Includes practical exercises that reinforce key concepts at the end of each chapter

Materials Kinetics Fundamentals

Materials Kinetics Fundamentals Book
Author : Ryan O'Hayre
Publisher : John Wiley & Sons
Release : 2015-01-12
ISBN : 1118972899
Language : En, Es, Fr & De

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Book Description :

Introductory kinetics for the undergrad materials scientist Materials Kinetics Fundamentals is an accessible and interesting introduction to kinetics processes, with a focus on materials systems. Designed for the undergraduate student, this book avoids intense mathematics to present the theory and application of kinetics in a clear, reader-friendly way. Students are first introduced to the fundamental concepts of kinetics, with illustrated diagrams, examples, text boxes, and homework questions that impart a unified, intuitive understanding. Further chapters cover the application of these concepts in the context of materials science, with real-world examples including silicon processing and integrated circuit fabrication, thin-film deposition, carbon-14 dating, steel degassing, energy conversion, and more. Instructor materials including a test bank are available through the companion website, providing a complete resource for the undergraduate materials science student. At its core, kinetics deals with rates, telling us how fast something will take place – for example, how fast water will evaporate, or how fast molten silicon will solidify. This book is designed to provide students with an introduction to kinetics' underlying principles, without rigorous math to distract from understanding. Understand universally important kinetic concepts like diffusion and reaction rate Model common kinetic processes both quantitatively and qualitatively Learn the mechanisms behind important and interesting materials systems Examine the behaviors, properties, and interactions of relevant solid materials There are a large number of books on chemical kinetics, but there are far fewer that focus on materials kinetics, and virtually none that provide an accessible, introductory-level treatment of the subject. Materials Kinetics Fundamentals fills that need, with clear, detailed explanations of these universal concepts.

Lectures on Kinetic Processes in Materials

Lectures on Kinetic Processes in Materials Book
Author : Han-Ill Yoo
Publisher : Springer Nature
Release : 2020-05-09
ISBN : 3030259501
Language : En, Es, Fr & De

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Book Description :

This book provides beginning graduate or senior-level undergraduate students in materials disciplines with a primer of the fundamental and quantitative ideas on kinetic processes in solid materials. Kinetics is concerned with the rate of change of the state of existence of a material system under thermodynamic driving forces. Kinetic processes in materials typically involve chemical reactions and solid state diffusion in parallel or in tandem. Thus, mathematics of diffusion in continuum is first dealt with in some depth, followed by the atomic theory of diffusion and a brief review of chemical reaction kinetics. Chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions are examined. Through this course of learning, a student will become able to predict quantitatively how fast a kinetic process takes place, to understand the inner workings of the process, and to design the optimal process of material state change. Provides students with the tools to predict quantitatively how fast a kinetic process takes place and solve other diffusion related problems; Learns fundamental and quantitative ideas on kinetic processes in solid materials; Examines chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions, among others; Contains end-of chapter exercise problems to help reinforce students' grasp of the concepts presented within each chapter.

Kinetics of Materials

Kinetics of Materials Book
Author : Robert W. Balluffi,Sam Allen,W. Craig Carter
Publisher : John Wiley & Sons
Release : 2005-12-16
ISBN : 0471749303
Language : En, Es, Fr & De

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Book Description :

A classroom-tested textbook providing a fundamental understandingof basic kinetic processes in materials This textbook, reflecting the hands-on teaching experience of itsthree authors, evolved from Massachusetts Institute of Technology'sfirst-year graduate curriculum in the Department of MaterialsScience and Engineering. It discusses key topics collectivelyrepresenting the basic kinetic processes that cause changes in thesize, shape, composition, and atomistic structure of materials.Readers gain a deeper understanding of these kinetic processes andof the properties and applications of materials. Topics are introduced in a logical order, enabling students todevelop a solid foundation before advancing to more sophisticatedtopics. Kinetics of Materials begins with diffusion, offering adescription of the elementary manner in which atoms and moleculesmove around in solids and liquids. Next, the more complex motion ofdislocations and interfaces is addressed. Finally, still morecomplex kinetic phenomena, such as morphological evolution andphase transformations, are treated. Throughout the textbook, readers are instilled with an appreciationof the subject's analytic foundations and, in many cases, theapproximations commonly used in the field. The authors offer manyextensive derivations of important results to help illuminate theirorigins. While the principal focus is on kinetic phenomena incrystalline materials, select phenomena in noncrystalline materialsare also discussed. In many cases, the principles involved apply toall materials. Exercises with accompanying solutions are provided throughoutKinetics of Materials, enabling readers to put their newfoundknowledge into practice. In addition, bibliographies are offeredwith each chapter, helping readers to investigate specializedtopics in greater detail. Several appendices presenting importantbackground material are also included. With its unique range of topics, progressive structure, andextensive exercises, this classroom-tested textbook provides anenriching learning experience for first-year graduate students.

An Introduction to Aspects of Thermodynamics and Kinetics Relevant to Materials Science

An Introduction to Aspects of Thermodynamics and Kinetics Relevant to Materials Science Book
Author : Eugene Machlin
Publisher : Elsevier
Release : 2010-07-07
ISBN : 9780080549682
Language : En, Es, Fr & De

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Book Description :

This book is based on a set of notes developed over many years for an introductory course taught to seniors and entering graduate students in materials science. An Introduction to Aspects of Thermodynamics and Kinetics Relevant to Materials Science is about the application of thermodynamics and kinetics to solve problems within Materials Science. Emphasis is to provide a physical understanding of the phenomenon under discussion, with the mathematics presented as a guide. The problems are used to provide practice in quantitative application of principles, and also to give examples of applications of the general subject matter to problems having current interest and to emphasize the important physical concepts. End of chapter problems are included, as are references, and bibliography to reinforce the text. This book provides students with the theory and mathematics to understand the important physical understanding of phenomena. Based on a set of notes developed over many years for an introductory course taught to seniors and entering graduate students in materials science Provides students with the theory and mathematics to understand the important physical understanding of phenomena Includes end of chapter problems, references, and bibliography to reinforce the text

Thermal Analysis Kinetics for Understanding Materials Behavior

Thermal Analysis Kinetics for Understanding Materials Behavior Book
Author : Sergey Vyazovkin
Publisher : MDPI
Release : 2020-12-29
ISBN : 3039365592
Language : En, Es, Fr & De

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Book Description :

Changing the temperature of a substance can stimulate dramatic changes of its state. These changes can be intermolecular (physical) and intramolecular (chemical) in nature. Physical changes occur without breaking intramolecular bonds, and lead to transitions between the four major phases: gas, liquid, crystal, and glass. Chemical changes are associated with chemical reactions that originate from breaking intramolecular bonds. Phase transitions as well as chemical reactions occur at finite rates. Measuring the rates of processes is the realm of kinetics. The kinetics of thermally stimulated processes is routinely measured using thermal analysis techniques such as differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Knowing the process rates and their dependence on temperature is of vital importance for understanding the behavior of materials exposed to variations in temperature. In recent years, thermal analysis kinetics has made significant progress by developing computational tools for reliable kinetic analysis. It has also expanded its traditional application area to newly developed nano- and biomaterials. This Special Issue is a series of papers that reflect recent developments in the field and highlight the essential role of thermal analysis kinetics in understanding the processes responsible for the thermal behavior of various materials.

Kinetics in Materials Science and Engineering

Kinetics in Materials Science and Engineering Book
Author : Dennis W. Readey
Publisher : CRC Press
Release : 2017-01-27
ISBN : 1482235676
Language : En, Es, Fr & De

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Book Description :

"A pedagogical gem.... Professor Readey replaces ‘black-box’ explanations with detailed, insightful derivations. A wealth of practical application examples and exercise problems complement the exhaustive coverage of kinetics for all material classes." –Prof. Rainer Hebert, University of Connecticut "Prof. Readey gives a grand tour of the kinetics of materials suitable for experimentalists and modellers.... In an easy-to-read and entertaining style, this book leads the reader to fundamental, model-based understanding of kinetic processes critical to development, fabrication and application of commercially-important soft (polymers, biomaterials), hard (ceramics, metals) and composite materials. It is a must-have for anyone who really wants to understand how to make materials and how they will behave in service." --Prof. Bill Lee, Imperial College London, Fellow of the Royal Academy of Engineering "A much needed text filing the gap between an introductory course in materials science and advanced materials-specific kinetics courses. Ideal for the undergraduate interested in an in-depth study of kinetics in materials." –Prof. Mark E. Eberhart, Colorado School of Mines This book provides an in-depth introduction to the most important kinetic concepts in materials science, engineering, and processing. All types of materials are addressed, including metals, ceramics, polymers, electronic materials, biomaterials, and composites. The expert author with decades of teaching and practical experience gives a lively and accessible overview, explaining the principles that determine how long it takes to change material properties and make new and better materials. The chapters cover a broad range of topics extending from the heat treatment of steels, the processing of silicon integrated microchips, and the production of cement, to the movement of drugs through the human body. The author explicitly avoids "black box" equations, providing derivations with clear explanations.

Thermodynamics and Kinetics in Materials Science

Thermodynamics and Kinetics in Materials Science Book
Author : Boris S. Bokstein,Mikhail I. Mendelev,David J. Srolovitz
Publisher : Oxford University Press
Release : 2005-06-30
ISBN : 0198528043
Language : En, Es, Fr & De

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Book Description :

Accompanying CD-ROM contains ... "computer tests and laboratories."--CD-ROM label.

Problems in Metallurgical Thermodynamics and Kinetics

Problems in Metallurgical Thermodynamics and Kinetics Book
Author : G. S. Upadhyaya,R. K. Dube
Publisher : Elsevier
Release : 2013-10-22
ISBN : 148313993X
Language : En, Es, Fr & De

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Book Description :

Problems in Metallurgical Thermodynamics and Kinetics provides an illustration of the calculations encountered in the study of metallurgical thermodynamics and kinetics, focusing on theoretical concepts and practical applications. The chapters of this book provide comprehensive account of the theories, including basic and applied numerical examples with solutions. Unsolved numerical examples drawn from a wide range of metallurgical processes are also provided at the end of each chapter. The topics discussed include the three laws of thermodynamics; Clausius-Clapeyron equation; fugacity, activity, and equilibrium constant; thermodynamics of electrochemical cells; and kinetics. This book is beneficial to undergraduate and postgraduate students in universities, polytechnics, and technical colleges.

Grain Boundary Migration in Metals

Grain Boundary Migration in Metals Book
Author : Gunter Gottstein,Lasar S. Shvindlerman
Publisher : CRC Press
Release : 2011-06-03
ISBN : 1439858993
Language : En, Es, Fr & De

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Book Description :

A major goal of materials science is to create new engineering materials and optimize their cost and performance. Understanding how adjacent materials behave at their borders is an essential part of this process. Grain boundaries are the longest-known crystal defects, but although they were discovered in the mid-eighteenth century, until quite recently, we did not understand them very well. Even now, scientists are still searching for the best ways to comprehensively characterize a material’s microstructure—and accurately predict its evolution and behavior. Fills the gap between the physics of grain boundary motion and its engineering practicality Like the popular first edition, Grain Boundary Migration in Metals: Thermodynamics, Kinetics, Applications, Second Edition focuses extensively on the thermodynamics, kinetics, and applications involved with individual grain boundary migration in metals. However, this new volume adds a decade’s worth of new developments in research and methods. It offers an up-to-date overview of current knowledge of the grain boundary migration process, and it details how migration influences microstructural evolution, including the recrystallization process and the creation of new materials. The authors rely on well-defined geometry and crystallography to address key topics such as grain growth, textures, and the properties and behavior of grain boundaries, particularly the nonlinear interaction of boundary elements. This invaluable second edition: Covers the latest techniques and computer simulations used in the study of single-grain boundary motion and grain boundary systems with junctions Provides the latest experimental data of grain boundary free volume measurements and offers the first measurements of grain boundary junction line tension Includes new problems with solutions As a solid foundation on which you can build your understanding of the migration phenomenon, this book should be required reading for researchers in areas such as interface physics and materials science of microstructure evolution and property control. It will also be vastly useful to any professional engaged in metals production and/or the heat treatment of metals and alloys.

An Introduction to Chemical Kinetics

An Introduction to Chemical Kinetics Book
Author : Michel Soustelle
Publisher : John Wiley & Sons
Release : 2013-02-07
ISBN : 1118604229
Language : En, Es, Fr & De

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Book Description :

This book is a progressive presentation of kinetics of the chemicalreactions. It provides complete coverage of the domain of chemicalkinetics, which is necessary for the various future users in thefields of Chemistry, Physical Chemistry, Materials Science,Chemical Engineering, Macromolecular Chemistry and Combustion. Itwill help them to understand the most sophisticated knowledge oftheir future job area. Over 15 chapters, this book present the fundamentals of chemicalkinetics, its relations with reaction mechanisms and kineticproperties. Two chapters are then devoted to experimental resultsand how to calculate the kinetic laws in both homogeneous andheterogeneous systems. The following two chapters describe the mainapproximation modes to calculate these laws. Three chapters aredevoted to elementary steps with the various classes, theprinciples used to write them and their modeling using the theoryof the activated complex in gas and condensed phases. Threechapters are devoted to the particular areas of chemical reactions,chain reactions, catalysis and the stoichiometric heterogeneousreactions. Finally the non-steady-state processes of combustion andexplosion are treated in the final chapter.

Kinetic Control in Synthesis and Self Assembly

Kinetic Control in Synthesis and Self Assembly Book
Author : Munenori Numata,Shiki Yagai,Toshiyuki Hamura
Publisher : Academic Press
Release : 2018-11-23
ISBN : 0128121270
Language : En, Es, Fr & De

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Book Description :

Kinetic Control in Synthesis and Self-Assembly provides a unique overview of the fundamental principles, novel methods and practical applications for researchers across organic synthesis, supramolecular chemistry and materials sciences. The book examines naturally occurring molecular systems in which kinetic processes are more ubiquitous than thermodynamic processes, also exploring the control of reactions and molecular self-assemblies, through kinetic processes, in artificial systems. These methods currently play a crucial role for tuning materials functions. From organic synthesis, to supramolecular assemblies, and from restricted spaces, to material synthesis for hierarchical structures, the book offers valuable coverage for researchers across disciplines. Interesting topics include how to regulate kinetic pathways more precisely, essential molecular design for kinetic traps, and how molecular environments surrounding molecules (i.e., solvent, temperature, and pressure effects) influence kinetic control in reactions and self-assemblies. Describes the nature and potential applications of kinetic processes compared to thermodynamic processes Presents information useful to researchers active in molecular synthesis and self-assembly toward materials Collates coverage of kinetic control for synthesis and self-assembly, treated separately in literature

Kinetic Processes

Kinetic Processes Book
Author : Kenneth A. Jackson
Publisher : John Wiley & Sons
Release : 2006-03-06
ISBN : 3527604952
Language : En, Es, Fr & De

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Book Description :

The formation of solids is governed by kinetic processes, which are closely related to the macroscopic behaviour of the resulting materials. With the main focus on ease of understanding, the author begins with the basic processes at the atomic level to illustrate their connections to material properties. Diffusion processes during crystal growth and phase transformations are examined in detail. Since the underlying mathematics are very complex, approximation methods typically used in practice are the prime choice of approach. Apart from metals and alloys, the book places special emphasis on the growth of thin films and bulk crystals, which are the two main pillars of modern device and semiconductor technology. All the presented phenomena are tied back to the basic thermodynamic properties of the materials and to the underlying physical processes for clarity.

Kinetics in Nanoscale Materials

Kinetics in Nanoscale Materials Book
Author : King-Ning Tu,Andriy M. Gusak
Publisher : John Wiley & Sons
Release : 2014-05-16
ISBN : 1118742834
Language : En, Es, Fr & De

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Book Description :

As the ability to produce nanomaterials advances, it becomes more important to understand how the energy of the atoms in these materials is affected by their reduced dimensions. Written by an acclaimed author team, Kinetics in Nanoscale Materials is the first book to discuss simple but effective models of the systems and processes that have recently been discovered. The text, for researchers and graduate students, combines the novelty of nanoscale processes and systems with the transparency of mathematical models and generality of basic ideas relating to nanoscience and nanotechnology.

Advances in Crystallization Processes

Advances in Crystallization Processes Book
Author : Yitzhak Mastai
Publisher : BoD – Books on Demand
Release : 2012-04-27
ISBN : 9535105817
Language : En, Es, Fr & De

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Book Description :

Crystallization is used at some stage in nearly all process industries as a method of production, purification or recovery of solid materials. In recent years, a number of new applications have also come to rely on crystallization processes such as the crystallization of nano and amorphous materials. The articles for this book have been contributed by the most respected researchers in this area and cover the frontier areas of research and developments in crystallization processes. Divided into five parts this book provides the latest research developments in many aspects of crystallization including: chiral crystallization, crystallization of nanomaterials and the crystallization of amorphous and glassy materials. This book is of interest to both fundamental research and also to practicing scientists and will prove invaluable to all chemical engineers and industrial chemists in the process industries as well as crystallization workers and students in industry and academia.

Kinetics Transport and Structure in Hard and Soft Materials

Kinetics  Transport  and Structure in Hard and Soft Materials Book
Author : Peter F. Green
Publisher : CRC Press
Release : 2005-04-20
ISBN : 9781574447682
Language : En, Es, Fr & De

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Book Description :

Kinetics, Transport, and Structure in Hard and Soft Materials is the only single reference that discusses the connection between structure and mechanisms of atomic or molecular transport in different classes of materials, from metals and semiconductors to network glasses, polymers and supercooled liquids. Divided into four parts, Part I begins with a discussion the fundamentals of transport, wherein transport properties of a system of non-interacting particles are calculated and the phenomenon of Brownian motion introduced. The phenomenology of diffusion is also discussed wherein Fick’s laws are introduced and solved for a range of practical cases involving mass transport. Elementary Statistical mechanics, involving Partition functions, probability distribution functions and correlation functions, is discussed to lay the foundation for the subsequent discussion of mechanisms of transport in different materials. Parts II and III focus on mechanisms of transport in crystalline materials and in structurally disordered materials. Chapters explain how the mechanism of diffusional transport of an atom or molecule is intimately connected to the spatial organization of neighboring structural elements and to its interactions with them. The book reviews factors that control temperature dependent long-range dynamics of glass-forming systems. Diffusion and viscoelasticity of polymer melts, transport (viscous flow and ionic diffusion) in inorganic network glasses, and dynamic heterogeneity in super cooled liquids are described. Part IV analyzes the development of instabilities, such as spinodal decomposition and Mullins-Sekerka instabilities, which lead to the morphological evolution of materials. Kinetics, Transport, and Structure in Hard and Soft Materials emphasizes interdisciplinary nature of transport in materials, presenting its material in a user-friendly format for students from any discipline with a foundation in elementary differential equations and thermodynamics or physical chemistry. This book shows how transport processes in materials are fundamentally connected a wide range of innovative applications of materials across several industries.

Drying Kinetics in Building Materials and Components

Drying Kinetics in Building Materials and Components Book
Author : João M. P. Q. Delgado,António C. Azevedo,Ana S. Guimarães
Publisher : Springer Nature
Release : 2019-09-24
ISBN : 3030318605
Language : En, Es, Fr & De

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Book Description :

This work presents an extensive experimental characterisation of two different ceramic brick blocks with different interface, at different heights, during the drying process. First, a laboratory characterization of the building material used (ceramic bricks and different mortars) is presented, showing their hygrothermal, mechanical and thermal properties, namely, bulk porosity and density, water vapour permeability, capillary absorption, retention curve, moisture diffusivity as a function of moisture content and thermal conductivity. Moreover, the moisture transfer in multi-layered systems was analysed in detail taking into account the interface contact between the building elements.

Kinetics and Thermodynamics of Multistep Nucleation and Self Assembly in Nanoscale Materials Volume 151

Kinetics and Thermodynamics of Multistep Nucleation and Self Assembly in Nanoscale Materials  Volume 151 Book
Author : Gregoire Nicolis,Dominique Maes
Publisher : John Wiley & Sons
Release : 2012-05-22
ISBN : 111816783X
Language : En, Es, Fr & De

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Book Description :

The Advances in Chemical Physics series—the cutting edge of research in chemical physics The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series presents contributions from internationally renowned chemists and serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics. This volume explores: Kinetics and thermodynamics of fluctuation-induced transitions in multistable systems (G. Nicolis and C. Nicolis) Dynamical rare event simulation techniques for equilibrium and nonequilibrium systems (Titus S. van Erp) Confocal depolarized dynamic light scattering (M. Potenza, T. Sanvito, V. Degiorgio, and M. Giglio) The two-step mechanism and the solution-crystal spinodal for nucleation of crystals in solution (Peter G. Vekilov) Experimental studies of two-step nucleation during two-dimensional crystallization of colloidal particles with short-range attraction (John R. Savage, Liquan Pei, and Anthony D. Dinsmore) On the role of metastable intermediate states in the homogeneous nucleation of solids from solution (James F. Lutsko) Effects of protein size on the high-concentration/low-concentration phase transition (Patrick Grosfils) Geometric constraints in the self-assembly of mineral dendrites and platelets (John J. Kozak) What can mesoscopic level in situ observations teach us about kinetics and thermodynamics of protein crystallization? (Mike Sleutel, Dominique Maes, and Alexander Van Driessche) The ability of silica to induce biomimetic crystallization of calcium carbonate (Matthias Kellermeier, Emilio Melero-GarcÍa, Werner Kunz, and Juan Manuel GarcÍa-Ruiz)

Deterministic Kinetics in Chemistry and Systems Biology

Deterministic Kinetics in Chemistry and Systems Biology Book
Author : Gábor Lente
Publisher : Springer
Release : 2015-03-09
ISBN : 3319154826
Language : En, Es, Fr & De

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Book Description :

This book gives a concise overview of the mathematical foundations of kinetics used in chemistry and systems biology. The analytical and numerical methods used to solve complex rate equations with the widely used deterministic approach will be described, with primary focus on practical aspects important in designing experimental studies and the evaluation of data. The introduction of personal computers transformed scientific attitudes in the last two decades considerably as computational power ceased to be a limiting factor. Despite this improvement, certain time-honored approximations in solving rate equations such as the pre-equilibrium or the steady-state approach are still valid and necessary as they concern the information content of measured kinetic traces. The book shows the role of these approximations in modern kinetics and will also describe some common misconceptions in this field.

Interfaces in Materials

Interfaces in Materials Book
Author : James M Howe,James M. Howe
Publisher : Wiley-Interscience
Release : 1997-02-27
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

An Instructor's Manual presenting detailed solutions to all the problems in the book is available from the Wiley editorial department.