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The Lanthanides

The Lanthanides Book
Author : Richard Beatty
Publisher : Marshall Cavendish
Release : 2008
ISBN : 9780761426875
Language : En, Es, Fr & De

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Book Description :

Introduces the lanthanide elements, also known as the rare earth metals, discussing their physical and chemical properties, where they are found, and how they are used.

Systematics and the Properties of the Lanthanides

Systematics and the Properties of the Lanthanides Book
Author : Shyama P. Sinha
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 9400971753
Language : En, Es, Fr & De

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Book Description :

Science is not a mere collection of facts. It is the correlation of facts, the interpretative synthesis of the available knowledge and its application that excite the imagination of a scientist. Even in these days of modern technology, the need for quick and accurate dissemination of new information and current concepts still exists. Conferences and Symposia offer one direct method of communication. The Summer Schools are another approach. The success of a Summer School is mainly due to that human factor and under standing that goes with it and allows for extensive and often time-unrestricted discussions. During the course of the past 20 years, one of the most in tensively studied groups of elements in the Periodic Table is the Lanthanides. In this period, we have increased our knowledge on these once exotic elements, which were once considered to be a part of a lean and hungry industry, many-fold due to the involve ment of scientists from various disciplines. The purpose of our Summer School was to bring a group of ex perts and participants together for the exchange of ideas and in formation in an informal setting and to promote interdisciplinary interactions. Out of many conceivable topics, we selected the following five as the main basis to broaden our knowledge and understanding I) Systematics 2) Structure 3) Electronic and Magnetic Proper ties 4) Spectroscopic Properties and 5) Lanthanide Geochemistry.

Lanthanides Chemistry and Use in Organic Synthesis

Lanthanides  Chemistry and Use in Organic Synthesis Book
Author : Shu Kobayashi,G. Molander,Reiner Anwander,E. C. Dowdy,H. Groger,Z. Hou,H. Kagan
Publisher : Springer Science & Business Media
Release : 1999-03-08
ISBN : 3540645268
Language : En, Es, Fr & De

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Book Description :

The use of lanthanides in organic chemistry and in organic synthesis has attracted broad interest recently because of the unique reactivities and selectivities exhibited by compounds of these rare earth elements. In particular, several major advances have been made in the last five years. This volume of Topics in Organometallic Chemistry is designed to provide the specialist and non-specialist alike with a much needed overview of recent developments. Contributions by leaders in the field focus on stereoselective organic synthesis using lanthanides, the principles of lanthanide chemistry, lanthanide-based chiral catalysts, low-valent lanthanide compounds, polymer synthesis using lanthanide catalysts, and polymer-supported lanthanide catalysts used in organic synthesis.

Lanthanides

Lanthanides Book
Author : Nasser Awwad,Ahmed Mubarak
Publisher : BoD – Books on Demand
Release : 2019-01-23
ISBN : 1789850096
Language : En, Es, Fr & De

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Book Description :

This edited book Lanthanides is a collection of research chapters, offering an excellent review of recent applications in our lives. It consists of a number of interesting chapters by scientists and researchers from different parts of the world. The book is divided into six chapters. The first chapter is a short introduction that explains the nature and purpose of the book and the logic and significance of its contents. In the second chapter, Katarzyna Kiegiel et al. introduce novel apparatus solutions, for example membrane contactors in the extraction stage and different types of matrices (uranium ore, phosphorites, etc.). The third chapter by Dariusz Sala and Bogus?aw Bieda from AGH University of Science and Technology, Management Department, Poland, describes the development of the life cycle inventory to rare earth elements (REEs) based on secondary sources, conducted according to ISO 14040 (2006) guidelines. Chapter 4 concentrates on lanthanide soil chemistry and shows how the soil chemistry of REEs may support soil science investigations. Dmitry V. Ladonin in Chapter 5 studies the content of forms of lanthanides in soddy-calcareous soils at different distances from the Cherepovets steel mill (Vologda region, Russia). The author concludes that the individual properties of lanthanides are clearly manifested in their interaction with soil components. The largest part of the fraction, bound to organic matter, contains medium lanthanides, while the heavy lanthanides are bound to Fe and Mn (hydr)oxides. The last chapter discusses ecological and physiological impacts of lanthanides on algae as primary producers in aquatic environments. This book will definitely encourage readers, researchers, and scientists to look further into the frontier topics of lanthanides and opens new possible research paths for further novel development.

Biochemistry of the Lanthanides

Biochemistry of the Lanthanides Book
Author : Christopher H. Evans
Publisher : Springer Science & Business Media
Release : 2013-11-11
ISBN : 1468487485
Language : En, Es, Fr & De

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Book Description :

By a happy coincidence, the completion of this text coincided with the 200th anniversary of the discovery of gadolinite, the mineral with which the lanthanide story begins. For a group of elements which occur in only trace amounts biologically, and which have no known metabolic role, the lanthanides have spawned a surprisingly large biochemicalliterature. Se rious interest in the biochemical properties ofthese elements can be traced to concerns about the safety of radioactive lanthanides toward the end of World War 11. As recent events at Chernobyl indicate, this concern re mains topical. However, the literature on lanthanide biochemistry pre dates the atomic era, beginning with sporadic, medically motivated studies in the latter part of the 19th century. Much of the present biochemical activity involving the lanthanides centers around their ability to provide 2 important information on the interactions of Ca + with macromolecules and with eukafyotic cells. With the increasing industrial use of the lan thanides, their toxicological properties will need to be examined more closely. Rare earth pneumonoconiosis has already been identified as a disease produced by industrial exposure to lanthanides. Several of the biochemical properties of the lanthanides are of relevance to modern medicine. Already cerium-based ointments are used to treat burn wounds, while paramagnetic lanthanides find application in nuclear magnetic res onance imaging. This book is an attempt to collate and to present in reasonable detail existing knowledge of lanthanide biochemistry before the literature be comes unmanageable.

The Chemistry of the Lanthanides

The Chemistry of the Lanthanides Book
Author : Therald Moeller
Publisher : Elsevier
Release : 2013-10-22
ISBN : 1483187632
Language : En, Es, Fr & De

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Book Description :

Inorganic Chemistry, Volume 26: The Chemistry of the Lanthanides provides information pertinent to the fundamental aspects of the chemistry of lanthanides. This book discusses the electronic configurations and the consequences thereof of lanthanides. Organized into four chapters, this volume begins with an overview of the characterized state of oxidation of all the lanthanides both in solid compounds and in solutions in water and other solvents. This text then presents the data indicating an overall decrease from lanthanum to lutetium even though there is the expected increase in the sizes of atoms and derived terpositive ions in Group IIIA elements. Other chapters consider the differences between the lanthanide elements and the d-transition. This book discusses as well the types of lanthanide complexes. The final chapter deals with the estimated absolute abundances of the lanthanides in the cosmos as well as in the crust. This book is a valuable resource for inorganic chemists.

Lanthanides And Actinides The Synthesis Reactivity Properties And Applications

Lanthanides And Actinides  The  Synthesis  Reactivity  Properties And Applications Book
Author : Stephen T Liddle,David P Mills,Louise Sarah Natrajan
Publisher : World Scientific
Release : 2021-12-30
ISBN : 1800610173
Language : En, Es, Fr & De

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Book Description :

The Lanthanides and Actinides: Synthesis, Reactivity, Properties and Applications constitutes an introduction to and comprehensive coverage of f-block chemistry encompassing the following areas: periodicity, natural occurrence and extraction, separations, electronic structure, coordination chemistry, organometallic chemistry, small molecule activation, catalysis, organic synthesis applications, magnetism, spectroscopy, computation, materials, photonics, solar cell technology, biological imaging, and technological applications. Under these subject areas the book provides a broad but deep coverage, providing basic overviews as well as detailed chapters on specific areas.This book, targeted at academics, postgraduates and advanced undergraduates, will serve as an ideal introductory text and key reference work to the Lanthanides and Actinides.

Extraction and Separation of Selected Lanthanides with a Tertiary Amine

Extraction and Separation of Selected Lanthanides with a Tertiary Amine Book
Author : Donald J. Bauer
Publisher : Unknown
Release : 1966
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Extraction and Separation of Selected Lanthanides with a Tertiary Amine book written by Donald J. Bauer, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Lanthanides and Actinides in Molecular Magnetism

Lanthanides and Actinides in Molecular Magnetism Book
Author : Richard A. Layfield,Muralee Murugesu
Publisher : John Wiley & Sons
Release : 2015-01-20
ISBN : 3527673504
Language : En, Es, Fr & De

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Book Description :

The first reference on this rapidly growing topic provides an essential up-to-date guide to current and emerging trends. A group of international experts has been carefully selected by the editors to cover all the central aspects, with a focus on molecular species while also including industrial applications. The resulting unique overview is a must-have for researchers, both in academia and industry, who are entering or already working in the field.

Molecular Magnetism of Lanthanides Complexes and Networks

Molecular Magnetism of Lanthanides Complexes and Networks Book
Author : Kevin Bernot
Publisher : MDPI
Release : 2018-08-20
ISBN : 3038429872
Language : En, Es, Fr & De

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Book Description :

This book is a printed edition of the Special Issue "Molecular Magnetism of Lanthanides Complexes" and Networks that was published in Magnetochemistry

Lanthanides and Actinides

Lanthanides and Actinides Book
Author : K. W. Bagnall
Publisher : Unknown
Release : 1972
ISBN : 9780839110071
Language : En, Es, Fr & De

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Book Description :

Download Lanthanides and Actinides book written by K. W. Bagnall, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Halides of the Transition Elements Halides of the lanthanides and actinides by D Brown

Halides of the Transition Elements  Halides of the lanthanides and actinides  by D  Brown Book
Author : David Brown,J. H. Canterford,Ray Colton
Publisher : Unknown
Release : 1968
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Halides of the Transition Elements Halides of the lanthanides and actinides by D Brown book written by David Brown,J. H. Canterford,Ray Colton, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Rare Earth Element Biochemistry Characterization and Applications of Lanthanide Binding Biomolecules

Rare Earth Element Biochemistry  Characterization and Applications of Lanthanide Binding Biomolecules Book
Author : Anonim
Publisher : Academic Press
Release : 2021-04-30
ISBN : 0323910866
Language : En, Es, Fr & De

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Book Description :

This new volume of Methods in Enzymology continues the legacy of this premier serial with quality chapters authored by leaders in the field. Provides the authority and expertise of leading contributors from an international board of authors Presents the latest release in the Methods in Enzymology series

Women in Lanthanide based Luminescence Research From Basic Research to Applications

Women in Lanthanide based Luminescence Research  From Basic Research to Applications Book
Author : Qianqian Su,Lining Sun,Eva Hemmer,Ho Seong Jang
Publisher : Frontiers Media SA
Release : 2021-05-18
ISBN : 2889667723
Language : En, Es, Fr & De

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Book Description :

Download Women in Lanthanide based Luminescence Research From Basic Research to Applications book written by Qianqian Su,Lining Sun,Eva Hemmer,Ho Seong Jang, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Synthesis of Lanthanide and Actinide Compounds

Synthesis of Lanthanide and Actinide Compounds Book
Author : G. Meyer,L.R. Morss
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 9401137587
Language : En, Es, Fr & De

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Book Description :

Download Synthesis of Lanthanide and Actinide Compounds book written by G. Meyer,L.R. Morss, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Energy Transfer Processes in Polynuclear Lanthanide Complexes

Energy Transfer Processes in Polynuclear Lanthanide Complexes Book
Author : Shun Omagari
Publisher : Springer
Release : 2019-01-17
ISBN : 9811360499
Language : En, Es, Fr & De

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Book Description :

This book describes the luminescence mechanism of polynuclear lanthanide complexes, focusing on energy transfer processes using a combination of experimental and theoretical approaches. Lanthanide complexes show intense luminescence from the lanthanide ion through sensitization by the organic ligands. The high chromaticity of the emission and the long lifetimes of the complexes are particularly attractive for applications such as organic light-emitting diodes and bioprobes. Polynuclear lanthanide complexes (coordination polymers and clusters) have attracted considerable interest for functionalization by energy transfer between lanthanide ions. At the same time, such extra processes complicate the luminescence mechanism, hindering the rational design of functional polynuclear lanthanide complexes. Firstly, the book explains the principle of the theoretical methods, and then describes the concentration-quenching mechanism in coordination polymers. It also examines the effect of intrinsic spin–orbit coupling arising from lanthanide ions on the ligand-to-lanthanide energy transfer efficiency and the mechanism of back energy transfer (the opposite of sensitizing energy transfer) in lanthanide clusters. This sets the stage for the final topic: the suppression of back energy transfer by energy transfer between lanthanide ions in lanthanide clusters, which is of critical importance, showing that the lanthanide clusters can be considered a new generation of functional and efficient luminescent material and could also provide a breakthrough in lanthanide photophysics.

Lanthanide Luminescence

Lanthanide Luminescence Book
Author : Pekka Hänninen,Harri Härmä
Publisher : Springer Science & Business Media
Release : 2011-06-21
ISBN : 3642210236
Language : En, Es, Fr & De

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Book Description :

Lanthanides have fascinated scientists for more than two centuries now, and since efficient separation techniques were established roughly 50 years ago, they have increasingly found their way into industrial exploitation and our everyday lives. Numerous applications are based on their unique luminescent properties, which are highlighted in this volume. It presents established knowledge about the photophysical basics, relevant lanthanide probes or materials, and describes instrumentation-related aspects including chemical and physical sensors. The uses of lanthanides in bioanalysis and medicine are outlined, such as assays for in vitro diagnostics and research. All chapters were compiled by renowned scientists with a broad audience in mind, providing both beginners in the field and advanced researchers with comprehensive information on on the given subject.

Lanthanide and Actinide Chemistry

Lanthanide and Actinide Chemistry Book
Author : Simon Cotton
Publisher : John Wiley & Sons
Release : 2013-03-15
ISBN : 1118681363
Language : En, Es, Fr & De

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Book Description :

The only introduction into the exciting chemistry of Lanthanidesand Actinides. The book is based on a number of courses on "f elements" The author has a long experience in teaching this field ofchemistry Lanthanides have become very common elements in research andtechnology applications; this book offers the basic knowledge The book offers insights into a vast range of applications,from lasers to synthesis The Inorganic Chemistry: A Textbook series reflects thepivotal role of modern inorganic and physical chemistry in a wholerange of emerging areas, such as materials chemistry, greenchemistry and bioinorganic chemistry, as well as providing a solidgrounding in established areas such as solid state chemistry,coordination chemistry, main group chemistry and physical inorganicchemistry. Lanthanide and Actinide Chemistry is a one-volume accountof the Lanthanides (including scandium and yttrium), the Actinidesand the Transactinide elements, intended as an introductorytreatment for undergraduate and postgraduate students. Theprincipal features of these elements are set out in detail,enabling clear comparison and contrast with the Transition Elementsand Main Group metals. The book covers the extraction of the elements from their oresand their purification, as well as the synthesis of the man-madeelements; the properties of the elements and principal binarycompounds; detailed accounts of their coordination chemistry andorganometallic chemistry, from both preparative and structuralviewpoints, with a clear explanation of the factors responsible forthe adoption of particular coordination numbers; spectroscopy andmagnetism, especially for the lanthanides, with case studies andaccounts of applications in areas like magnetic resonance imaging,lasers and luminescence; nuclear separations and problems in wastedisposal for the radioactive elements, particularly in the contextof plutonium. Latest developments are covered in areas like the synthesis ofthe latest man-made elements, whilst there is a whole chapter onthe application of lanthanide compounds in synthetic organicchemistry. End-of-chapter questions suitable for tutorial discussions areprovided, whilst there is a very comprehensive bibliographyproviding ready access to further reading on all topics.

Computational Methods in Lanthanide and Actinide Chemistry

Computational Methods in Lanthanide and Actinide Chemistry Book
Author : Michael Dolg
Publisher : John Wiley & Sons
Release : 2015-02-17
ISBN : 1118688295
Language : En, Es, Fr & De

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Book Description :

The f-elements and their compounds often possess an unusually complex electronic structure, governed by the high number of electronic states arising from open f-shells as well as large relativistic and electron correlation effects. A correct theoretical description of these elements poses the highest challenges to theory. Computational Methods in Lanthanide and Actinide Chemistry summarizes state-of-the-art electronic structure methods applicable for quantum chemical calculations of lanthanide and actinide systems and presents a broad overview of their most recent applications to atoms, molecules and solids. The book contains sixteen chapters, written by leading experts in method development as well as in theoretical investigations of f-element systems. Topics covered include: Relativistic configuration interaction calculations for lanthanide and actinide anions Study of actinides by relativistic coupled cluster methods Relativistic all-electron approaches to the study of f- element chemistry Relativistic pseudopotentials and their applications Gaussian basis sets for lanthanide and actinide elements Applied computational actinide chemistry This book will serve as a comprehensive reference work for quantum chemists and computational chemists, both those already working in, and those planning to enter the field of quantum chemistry for f-elements. Experimentalists will also find important information concerning the capabilities of modern quantum chemical methods to assist in the interpretation or even to predict the outcome of their experiments.

Lanthanide Based Multifunctional Materials

Lanthanide Based Multifunctional Materials Book
Author : Anonim
Publisher : Elsevier
Release : 2018-06-26
ISBN : 0128138416
Language : En, Es, Fr & De

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Book Description :

Lanthanide-Based Multifunctional Materials: From OLEDs to SIMs serves as a comprehensive and state-of the art review on these promising compounds, delivering a panorama of their extensive and rapidly growing applications. After an introductory chapter on the theoretical description of the optical and magnetic behaviour of lanthanides and on the prediction of their properties by ab-initio methods, four chapters are devoted to lanthanide-based OLEDs, including the latest trends in visible emitters, the emerging field of near infrared emitters and the first achievements attained in the field of chiral OLEDs. The use of lanthanide complexes as molecular magnets spreads over another two chapters, which explain the evolution of 4f-elements-based SIMs and the most recent advances in heterometallic 3d–4f SMMs. Other very active research areas are covered in the remaining five chapters, dedicated to lanthanide-doped germanate and tellurite glasses, luminescent materials for up-conversion, luminescent thermosensors, multimodal imaging and therapeutic agents, and chemosensors. The book is aimed at academic and industrial researchers, undergraduates and postgraduates alike, and is of particular interest for the Materials Science, Applied Physics and Applied Chemistry communities. Includes the latest progress on lanthanide-based materials and their applications (in OLEDs, SIMs, doped matrices, up-conversion, thermosensors, theragnostics and chemosensors) Presents basic and applied aspects of the Physics and Chemistry of lanthanide compounds, as well as future lines of action Covers successful examples of devices and proofs-of-concept and provides guidelines for the rational design of new materials