Kinetics Of Processes In The Solid State

Book Description :

Chemical kinetics in solids are often dependent on numerous factors, and it's important for researchers to understand both the interactions relating to these factors, and how their own procedural choices may influence outcomes. Kinetics of Processes in the Solid State provides an authoritative overview of reactions in solids and helps readers quickly and easily identify the kinetic processes at play in their own work. Beginning with an introduction to the nature of solids and transformations, the book goes on to outline rate laws and experimental techniques, followed by such key areas as nucleation, phase transformations and crystallization. Chapters on the kinetics of dehydration, decomposition and polymers follow, before the book concludes by reviewing kinetics in relation to some important applications. Drawing on the experience of its expert author, Kinetics of Processes in the Solid State is a practical introduction to the field for chemists and researchers whose work is directly related to these interactions, and additionally for all those in related fields whose work would be enhanced by an understanding of these processes. Places the application of kinetic models in the context of reactions across numerous types of materials Illustrates the potentials and limitations of experimental techniques for studying reactions in solids Shows how experimental conditions can affect kinetic studies and how readers can address such issues

Book Description :

Kinetic studies have traditionally being extremely useful in characterizing several physical and chemical phenomena in organic, inorganic and metallic systems. It provides valuable qualitative, quantitative and kinetic information on phase transformations, solid state precipitation, crystallization, oxidation and decomposition. Unfortunately, no single reference comprehensively presents nonisothermal kinetic analysis method for the study of complex processes, determining the actual mechanism and kinetic parameters. This book provides a new method for nonisothermal kinetics and its application in heterogeneous solid state processes. In the backdrop of limitations in existing methods, the book presents a brief review of the widely used isothermal and nonisothermal kinetic analysis methods.

Book Description :

Many different chemical processes take place inside solids or at solid surfaces and interfaces. However, their quantitative description sometimes seems difficult to understand. This book by Professor Schmalzried, author of the eminently successful Solid State Reactions; bridges the gap between the 'physical' and 'chemical' approaches to this subject because it is written in a language which both sides understand. For the first time, a comprehensive coverage of the rapidly developing field of Solid State Kinetics is available. The topics covered in this book go far beyond diffusional transport. Homogeneous and heterogeneous solid-state reactions, phase transitions or the influence of external fields are also treated in detail. With this background, the author explains e.g. charge transport mechanisms in ionic conductors, principles of sensor technology, or oxidation processes clearly and comprehensibly. This book is a must for every solid-state chemist and an indispensable tool for academic and industrial readers alike. From reviews: 'a first-rate reference work that a must for any science library' (J. Am Chem. Soc.) 'can be recommended without restrictions ...' (Z. Phys. Chem.)

Book Description :

Much data has been collected from experiments on the kinetios of radical reactions in different solids, but to date, this has not been presented in book format in a thorough and comprehensive way. This book makes the experimental data accessible for all chemists involved in these reactions. Various models of the tunnel atom transfer are analyzed in order to explain the kinetic isotope effect in solid phase reactions and photoinitiated radical reactions are inspected for the kinetic non-equivalence of particles and factors affecting their reactivity. Topics covered include: kinetic description of reactions with dispersion particles in reactivity the influence of space-orientation factors on reactivity in cage reactions the influence of molecular dynamics on the kinetics of elementary reactions the effect of structural-physical modification on kinetics of cage radical reactions

Book Description :

The most current guide to solid state polymerization Solid State Polymerization (SSP)is an indispensable tool in the design, manufacture, and study of polymers, plastics, and fibers. SSP presents significant advantages over other polymerization techniques due to low operating temperatures, inexpensive equipment, and simple and environmentally sound procedures. Combining fundamentals of polymer science, chemistry, physical chemistry, and engineering, SSP also offers many research applications for a wide range of students and investigators. Gathering and filtering the latest literature on SSP, Solid Solid State Polymerization offers a unique, one-stop resource on this important process. With chapters contributed by leaders in the field, this text summarizes SSP, and provides essential coverage that includes: An introduction to SSP, with chemical and physical steps, apparatus, advantages, and parameters SSP physical chemistry and mechanisms Kinetic aspects of polyesters and polyamides SSP Catalysis in SSP processes Application of SSP under high pressure conditions in the laboratory Engineering aspects regarding process modeling and industrial application Recent developments and future possibilities Solid State Polymerization provides the most up-to-date coverage of this constantly developing field to academic and industry professionals, as well as graduate and postgraduate-level students in chemical engineering, materials science and engineering, polymer chemistry, polymer processing and polymer engineering.

Book Description :

Volume is indexed by Thomson Reuters BCI (WoS). This monograph deals with a physico-chemical approach to the problem of the solid-state growth of chemical compound layers and reaction-diffusion in binary heterogeneous systems formed by two solids; as well as a solid with a liquid or a gas. It is explained why the number of compound layers growing at the interface between the original phases is usually much lower than the number of chemical compounds in the phase diagram of a given binary system. For example, of the eight intermetallic compounds which exist in the aluminium-zirconium binary system, only ZrAl3 was found to grow as a separate layer at the Al–Zr interface under isothermal conditions. The physico-chemical approach predicts that, in most cases, the number of compound layers should not exceed two; with the main factor, resulting in the appearance of additional layers, being crack formation due to thermal expansion and volume effects.

Book Description :

The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.

Book Description :

Download Detonation book written by David J. Edwards, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Book Description :

This book provides beginning graduate or senior-level undergraduate students in materials disciplines with a primer of the fundamental and quantitative ideas on kinetic processes in solid materials. Kinetics is concerned with the rate of change of the state of existence of a material system under thermodynamic driving forces. Kinetic processes in materials typically involve chemical reactions and solid state diffusion in parallel or in tandem. Thus, mathematics of diffusion in continuum is first dealt with in some depth, followed by the atomic theory of diffusion and a brief review of chemical reaction kinetics. Chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions are examined. Through this course of learning, a student will become able to predict quantitatively how fast a kinetic process takes place, to understand the inner workings of the process, and to design the optimal process of material state change. Provides students with the tools to predict quantitatively how fast a kinetic process takes place and solve other diffusion related problems; Learns fundamental and quantitative ideas on kinetic processes in solid materials; Examines chemical diffusion in metals and ionic solids, diffusion-controlled kinetics of phase transformations, and kinetics of gas-solid reactions, among others; Contains end-of chapter exercise problems to help reinforce students' grasp of the concepts presented within each chapter.

Book Description :

Reviews costs and benefits of nuclear programs involving Defense Dept and nuclear industries.

Book Description :

Download Solid state Ionic Devices III book written by E. D. Wachsman, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Book Description :

Download Hearings book written by United States. Congress. House, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Book Description :

This book complements others in biotechnology especially in industrialmicrobiology-biotechnology. It has been written with a research andacademic readership in mind but will prove equally beneficial to theprocess technologists and scientists working in biotechnology-basedbusiness and industries, large and small. The chapters include theinformation and facts based on the practically applicable knowledgegathered from up-to-date complete research published on the subjectand related topics. The contents of each chapter deal with How-to , asopposed to a Review of Literature with citation of a large number ofnon-applicable references .

Book Description :

Download Scientific and Technical Aerospace Reports book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Book Description :

Download Kinetics and Catalysis book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Book Description :

Download Comments on Solid State Physics book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Book Description :

Download Physics of the Solid State book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Book Description :

Download Physics Briefs book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Book Description :

The present theoretical and experimental knowledge of the time evolution of a system during solidification, not only in equilibrium, but also in nonequilibrium conditions, is summarized in this book. Such knowledge is of fundamental importance for the determination of the constitution of materials or of the technological conditions necessary to prepare materials with a desired structure. Emphasizing the importance of kinetic phase diagrams, the authors focus the attention of the reader on the problems connected with nonequilibrium conditions, that are encountered during real phase transformations. A critical review of phenomenological and statistical theories of phase transformations and of mass and heat transport enables the reader to determine the range of applicability of concrete models for the description of the evolution of a given system. The book is supplemented with several less-known methods and results of phase characterization, including a detailed account of the Soviet school of T.A. Cherepanova which is not well known in the West. The text also covers the modern research area of glasses and their preparation.

Book Description :

Download Thin Films and Nanostructures book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.