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High Pressure Fluid Phase Equilibria

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High pressure Fluid Phase Equilibria

High pressure Fluid Phase Equilibria Book
Author : Ulrich K. Deiters,Thomas Kraska
Publisher : Elsevier
Release : 2012
ISBN : 0444563474
Language : En, Es, Fr & De

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Book Description :

The book begins with an overview of the phase diagrams of fluid mixtures (fluid = liquid, gas, or supercritical state), which can show an astonishing variety when elevated pressures are taken into account; phenomena like retrograde condensation (single and double) and azeotropy (normal and double) are discussed. It then gives an introduction into the relevant thermodynamic equations for fluid mixtures, including some that are rarely found in modern textbooks, and shows how they can they be used to compute phase diagrams and related properties. This chapter gives a consistent and axiomatic approach to fluid thermodynamics; it avoids using activity coefficients. Further chapters are dedicated to solid-fluid phase equilibria and global phase diagrams (systematic search for phase diagram classes). The appendix contains numerical algorithms needed for the computations. The book thus enables the reader to create or improve computer programs for the calculation of fluid phase diagrams. introduces phase diagram classes, how to recognize them and identify their characteristic features presents rational nomenclature of binary fluid phase diagrams includes problems and solutions for self-testing, exercises or seminars

High Pressure Fluid Phase Equilibria

High Pressure Fluid Phase Equilibria Book
Author : Marlie Du Rand
Publisher : Unknown
Release : 2000
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download High Pressure Fluid Phase Equilibria book written by Marlie Du Rand, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Computer Calculations and Graphics Display of High Pressure Fluid Phase Equilibria in Binary Mixtures

Computer Calculations and Graphics Display of High Pressure Fluid Phase Equilibria in Binary Mixtures Book
Author : Catherine Ann Dauscher
Publisher : Unknown
Release : 1988
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Computer Calculations and Graphics Display of High Pressure Fluid Phase Equilibria in Binary Mixtures book written by Catherine Ann Dauscher, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Molecular Thermodynamics of Fluid Phase Equilibria

Molecular Thermodynamics of Fluid Phase Equilibria Book
Author : John M. Prausnitz,Rudiger N. Lichtenthaler,Edmundo Gomes de Azevedo
Publisher : Pearson Education
Release : 1998-10-22
ISBN : 0132440504
Language : En, Es, Fr & De

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Book Description :

The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.

An Experimental Investigation of the High Pressure Fluid Phase Equilibrium of Highly Asymmetric Binary Mixtures

An Experimental Investigation of the High Pressure Fluid Phase Equilibrium of Highly Asymmetric Binary Mixtures Book
Author : Mark Anthony McHugh
Publisher : Unknown
Release : 1981
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download An Experimental Investigation of the High Pressure Fluid Phase Equilibrium of Highly Asymmetric Binary Mixtures book written by Mark Anthony McHugh, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Ternary Fluid phase Equilibria at High Pressures with One Normally Gaseous Component

Ternary Fluid phase Equilibria at High Pressures with One Normally Gaseous Component Book
Author : Raymond Nickolas Fleck
Publisher : Unknown
Release : 1967
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Ternary Fluid phase Equilibria at High Pressures with One Normally Gaseous Component book written by Raymond Nickolas Fleck, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Molecular Thermodynamics of Fluid phase Equilibria

Molecular Thermodynamics of Fluid phase Equilibria Book
Author : J. M. Prausnitz,PrausnitzHJ. M.
Publisher : Prentice Hall
Release : 1969
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

97774-4 The classic guide to mixtures, completely updated with new models, theories, examples, and data. Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations. Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes: Techniques for improving separation processes and making them more environmentally friendly. Theoretical concepts enabling the description and interpretation of solution properties. New models, notably the lattice-fluid and statistical associated-fluid theories. Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels. Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes. Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more. Throughout, Molecular Thermodynamics ofFluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and oth

Phase Equilibrium Engineering

Phase Equilibrium Engineering Book
Author : Esteban Alberto Brignole,Selva Pereda
Publisher : Newnes
Release : 2013-04-02
ISBN : 044459471X
Language : En, Es, Fr & De

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Book Description :

Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs. Phase Equilibrium Engineering presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions. The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering. Methodologies are discussed using relevant industrial examples The molecular nature and composition of the process mixture is given a key role in process decisions Phase equilibrium diagrams are used as a drawing board for process implementation

CRC Handbook of Phase Equilibria and Thermodynamic Data of Polymer Solutions at Elevated Pressures

CRC Handbook of Phase Equilibria and Thermodynamic Data of Polymer Solutions at Elevated Pressures Book
Author : Christian Wohlfarth
Publisher : CRC Press
Release : 2015-02-10
ISBN : 9781498703208
Language : En, Es, Fr & De

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Book Description :

Thermodynamic data of polymer solutions are paramount for industrial and laboratory processes. These data also serve to understand the physical behavior of polymer solutions, study intermolecular interactions, and gain insights into the molecular nature of mixtures. Nearly a decade has passed since the release of a similar CRC Handbook and since then a large amount of new experimental data have been published, which is now compiled in this book. The CRC Handbook of Phase Equilibria and Thermodynamic Data of Polymer Solutions at Elevated Pressures features nearly 500 newly published references containing approximately 175 new vapor-liquid equilibrium data sets, 25 new liquid-liquid equilibrium data sets, 540 new high-pressure fluid phase equilibrium data sets, 60 new data sets describing PVT properties of polymers, and 20 new data sets with densities or excess volumes. The book is a valuable resource for researchers, specialists, and engineers working in the fields of polymer science, physical chemistry, chemical engineering, materials science, biological science and technology, and those developing computerized predictive packages.

High Pressure Phase Behaviour of Multicomponent Fluid Mixtures

High Pressure Phase Behaviour of Multicomponent Fluid Mixtures Book
Author : R.J. Sadus
Publisher : Elsevier
Release : 2012-12-02
ISBN : 0444596666
Language : En, Es, Fr & De

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Book Description :

The high pressure phase behaviour of binary fluid mixtures has been extensively studied during the last three decades. There is ample experimental data for a wide variety of binary mixtures and extensive methods for prediction have been developed. In contrast, the investigation of ternary and other multicomponent fluids is in its infancy. Experimental ternary mixture critical data are very rare and theoretical studies have been limited to data correlation rather than genuine prediction. The phase behaviour of ternary and other multicomponent fluid mixtures has many novel aspects which are not manifested in binary mixtures. The properties of ternary mixtures are also likely to be more difficult to characterize experimentally. It is in this context that calculated phase diagrams have an important role in leading the discovery of new phenomena and guiding experimental work. The criteria for phase equilibria of multicomponent fluids with particular emphasis on the critical state are examined in this book, and models for predicting fluid equilibria (e.g., different equations of state) are compared. Particular attention is paid to the critical state of ternary mixtures which has hitherto been largely neglected. The problems associated with predicting ternary equilibria are discussed, and some novel aspects of ternary critical phenomena are illustrated. The books also describes a novel type of critical transition which appears to be a common feature of the equilibria of ternary mixtures. Extensive phase diagrams of a wide range of ternary mixtures including systems containing carbon dioxide, water, nitrogen and tetrafluoromethane as one or more component are presented. The theoretical treatment is detailed in the appendix and a computation of known experimental critical points is also included.

Fluid Phase Equilibria for the Binary System Dimethyl Ether water

Fluid Phase Equilibria for the Binary System Dimethyl Ether water Book
Author : Maria Elena Pozo
Publisher : Unknown
Release : 1983
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Fluid Phase Equilibria for the Binary System Dimethyl Ether water book written by Maria Elena Pozo, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Crc Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures

Crc Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures Book
Author : Christian Wohlfarth
Publisher : CRC Press
Release : 2019-08-30
ISBN : 9780367393304
Language : En, Es, Fr & De

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Book Description :

This handbook provides the only complete collection of high-pressure thermodynamic data pertaining to polymer solutions at elevated pressures to date of all critical data for understanding the physical nature of these mixtures and applicable to a number of industrial and laboratory processes in polymer science, physical chemistry, chemical engineering, and biotechnology. In response to the increasing commercial interest due to the physico-chemical properties of these solutions, the CRC Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures compiles information on experimental data from hundreds of primary journal articles, dissertations, and other papers into a single source entirely devoted to polymer solutions. The book contains data on vapor-liquid equilibria and gas solubilities, liquidâ "liquid equilibria, high-pressure fluid phase equilibria for polymer systems in supercritical fluids, enthalpic and volumetric data, and second virial coefficients, all at elevated pressures. An excellent companion to the author's previous publications, the CRC Handbook of Thermodynamic Data of Copolymer Solutions and the CRC Handbook of Thermodynamic Data of Aqueous Polymer Solutions, this handbook contains reliable, easy-to-use entries, references, tables, examples, and appendices that provide students, professors, and researchers with a well-organized, quick route to the data they need. The CRC Handbook of Thermodynamic Data of Polymer Solutions at Elevated Pressures is a staple resource for all university libraries as well as private laboratories, particularly for researchers, academics, and engineers who handle polymer systems in supercritical fluids, material science applications such as computerized predictive packages, and chemical and biochemical processes, such as synthesis and character

High Pressure Phase Equilibria Applications Involving Supercritical Fluids

High Pressure Phase Equilibria Applications Involving Supercritical Fluids Book
Author : Norhidayah Suleiman
Publisher : Unknown
Release : 2016
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download High Pressure Phase Equilibria Applications Involving Supercritical Fluids book written by Norhidayah Suleiman, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Thermodynamic Properties of Complex Fluid Mixtures

Thermodynamic Properties of Complex Fluid Mixtures Book
Author : Gerd Maurer
Publisher : Wiley-VCH
Release : 2004-06-25
ISBN : 9783527277704
Language : En, Es, Fr & De

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Book Description :

A priority programme of the Deutsche Forschungsgemeinschaft (DFG) was conducted to investigate the thermophysical and thermochemical fundamentals relevant for process design in the chemical and petrochemical industry as well as for biotechnological and environmental process sciences. The priority programme comprised 27 projects in which researchers form various disciplines like applied thermodynamics, industrial chemistry, physical chemistry, process sciences, or biotechnology collaborated to solve some of the major problems of modern thermodynamics. The research results are exclusively documented in this book and cover topics like phase equilibrium in chemical reactive mixtures, in aqueous solutions of electrolytes, aqueous two-phase systems and polymer solutions, high pressure fluid phase equilibria, and microemulsion systems. The results contribute to a better understanding of important phase equilibrium phenomena and help to improve process models.

Phase Equilibrium Engineering

Phase Equilibrium Engineering Book
Author : Esteban Brignole,Selva Pereda
Publisher : Elsevier Inc. Chapters
Release : 2013-04-02
ISBN : 0128082631
Language : En, Es, Fr & De

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Book Description :

In this chapter, the problem of sustainability of the chemical and pharmaceutical industries and the principles of green chemistry are outlined. In particular, the need for secure and environmentally safe solvents (ESSs) is pointed out. There are several ESS alternatives under study nowadays, like ionic liquids, polymeric solvents, and simple liquids like fatty esters; however, an increasing attention is being paid to supercritical fluids (SCFs) for a wide variety of applications in the chemical and pharmaceutical as well as in the materials and electronic industry. In the present chapter after an introduction to the fundamentals of SCF extraction, PEE principles are applied to several case studies of SCF—substrate mixtures of natural products with different types of phase behavior. Finally the application of SCF for supercritical micronization is reviewed and a case study is presented.

High Pressure Fluid Technology for Green Food Processing

High Pressure Fluid Technology for Green Food Processing Book
Author : Tiziana Fornari,Roumiana P. Stateva
Publisher : Springer
Release : 2014-10-31
ISBN : 3319106112
Language : En, Es, Fr & De

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Book Description :

The aim of this book is to present the fundamentals of high pressure technologies from the perspective of mass transfer phenomena and thermodynamic considerations. Novel food applications are exposed and their relation to chemical analysis, extraction, reaction and particle formation processes are outlined. The chapters are written by a diverse group of scientists with expertise in chemistry, food processes, analytical chemistry, chemical engineering and chemical engineering thermodynamics, and biotechnology. The mission of green food engineering is to promote innovative technologies that reduce or eliminate the use or generation of hazardous materials (solvents, reagents) in the design and operation of food related processes, with the view to improve food safety and quality. Several efficient, environmentally friendly and benign technologies based on the use of high pressure and green solvents have demonstrated to be sustainable alternatives to traditional processes in the food industry. Although hundreds of new ideas are being published in the open literature, reliable engineering tools to simulate and design those processes are still under development. High Pressure Fluid Technology for Green Food Processing presents in-depth analyses and outlines the ways towards their maturity. Tiziana Fornari, Research Institute of Food Science (CIAL) Universidad Autonoma de Madrid, Madrid, Spain Roumiana P. Stateva, Institute of Chemical Engineering, Bulgarian Academy of Sciences, Sofia, Bulgaria

Calculation of Phase Equilibria of Quantum Fluids at High Pressure

Calculation of Phase Equilibria of Quantum Fluids at High Pressure Book
Author : Rozita Laghaei
Publisher : Unknown
Release : 2003
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Calculation of Phase Equilibria of Quantum Fluids at High Pressure book written by Rozita Laghaei, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

CRC Handbook of Phase Equilibria and Thermodynamic Data of Copolymer Solutions

CRC Handbook of Phase Equilibria and Thermodynamic Data of Copolymer Solutions Book
Author : Christian Wohlfarth
Publisher : CRC Press
Release : 2019-09-23
ISBN : 9780367383312
Language : En, Es, Fr & De

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Book Description :

Ten years after the debut of the expansive CRC Handbook of Thermodynamic Data of Copolymer Solutions, The CRC Handbook of Phase Equilibria and Thermodynamic Data of Copolymer Solutionsupdates and expands the world's first comprehensive source of this vital data. Author Christian Wohlfarth, a chemical thermodynamicist specializing in phase equilibria of polymer and copolymer solutions and a respected contributor to the CRC Handbook of Chemistry and Physics, has gathered up-to-the-minute data from more than 500 newly published references. Fully committed to ensuring the reliability of the data, the author included only results with published or personally communicated numerical values. With volumetric, calormetric, and various phase equilibrium data on more than 450 copolymers and 130 solvents, this handbook furnishes: 150 new vapor-liquid equilibrium datasets 50 new tables containing classical Henry's coefficients 250 new liquid-liquid equilibrium datasets 350 new high-pressure fluid phase equilibrium 70 new PVT-properties datasets 40 new enthalpic datasets Expanded second osmotic virial coefficients data table Carefully organized, clearly presented, and fully referenced, The Handbook of Phase Equilibria and Thermodynamic Data of Copolymer Solutionswill prove a cardinal contribution to the open literature and invaluable to anyone working with copolymers.

Phase Equilibria and Other Physicochemical Aspects of Interest for Enzymatic Reactions in Near critical Carbon Dioxide

Phase Equilibria and Other Physicochemical Aspects of Interest for Enzymatic Reactions in Near critical Carbon Dioxide Book
Author : Rob Matheus Maria Stevens
Publisher : Unknown
Release : 1997
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Phase Equilibria and Other Physicochemical Aspects of Interest for Enzymatic Reactions in Near critical Carbon Dioxide book written by Rob Matheus Maria Stevens, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.