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Epitaxial Growth Of Complex Metal Oxides

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Epitaxial Growth of Complex Metal Oxides

Epitaxial Growth of Complex Metal Oxides Book
Author : Gertjan Koster,Mark Huijben,Guus Rijnders
Publisher : Woodhead Publishing
Release : 2022-04-29
ISBN : 0081029462
Language : En, Es, Fr & De

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Book Description :

Epitaxial Growth of Complex Metal Oxides, Second Edition reviews techniques and recent developments in the fabrication quality of complex metal oxides, which are facilitating advances in electronic, magnetic and optical applications. Sections review the key techniques involved in the epitaxial growth of complex metal oxides and explore the effects of strain and stoichiometry on crystal structure and related properties in thin film oxides. Finally, the book concludes by discussing selected examples of important applications of complex metal oxide thin films, including optoelectronics, batteries, spintronics and neuromorphic applications. This new edition has been fully updated, with brand new chapters on topics such as atomic layer deposition, interfaces, STEM-EELs, and the epitaxial growth of multiferroics, ferroelectrics and nanocomposites. Examines the techniques used in epitaxial thin film growth for complex oxides, including atomic layer deposition, sputtering techniques, molecular beam epitaxy, and chemical solution deposition techniques Reviews materials design strategies and materials property analysis methods, including the impacts of defects, strain, interfaces and stoichiometry Describes key applications of epitaxially grown metal oxides, including optoelectronics, batteries, spintronics and neuromorphic applications

Metal Oxide Based Thin Film Structures

Metal Oxide Based Thin Film Structures Book
Author : Nini Pryds,Vincenzo Esposito
Publisher : Elsevier
Release : 2017-09-07
ISBN : 0081017529
Language : En, Es, Fr & De

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Book Description :

Metal Oxide-Based Thin Film Structures: Formation, Characterization and Application of Interface-Based Phenomena bridges the gap between thin film deposition and device development by exploring the synthesis, properties and applications of thin film interfaces. Part I deals with theoretical and experimental aspects of epitaxial growth, the structure and morphology of oxide-metal interfaces deposited with different deposition techniques and new developments in growth methods. Part II concerns analysis techniques for the electrical, optical, magnetic and structural properties of thin film interfaces. In Part III, the emphasis is on ionic and electronic transport at the interfaces of Metal-oxide thin films. Part IV discusses methods for tailoring metal oxide thin film interfaces for specific applications, including microelectronics, communication, optical electronics, catalysis, and energy generation and conservation. This book is an essential resource for anyone seeking to further their knowledge of metal oxide thin films and interfaces, including scientists and engineers working on electronic devices and energy systems and those engaged in research into electronic materials. Introduces the theoretical and experimental aspects of epitaxial growth for the benefit of readers new to the field Explores state-of-the-art analysis techniques and their application to interface properties in order to give a fuller understanding of the relationship between macroscopic properties and atomic-scale manipulation Discusses techniques for tailoring thin film interfaces for specific applications, including information, electronics and energy technologies, making this book essential reading for materials scientists and engineers alike

Molecular Beam Epitaxial Growth of Complex Novel Oxides

Molecular Beam Epitaxial Growth of Complex Novel Oxides Book
Author : N. J. C. Ingle
Publisher : Unknown
Release : 2001
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Molecular Beam Epitaxial Growth of Complex Novel Oxides book written by N. J. C. Ingle, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Alkoxide Routes to Inorganic Materials

Alkoxide Routes to Inorganic Materials Book
Author : Anonim
Publisher : Unknown
Release : 2007
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

An all alkoxide solution chemistry utilizing metal 2-methoxyethoxide complexes in 2-methoxyethanol was used to deposit thin-films of metal oxides on single-crystal metal oxide substrates and on biaxially textured metal substrates. This same chemistry was used to synthesize complex metal oxide nanoparticles. Nuclear Magnetic Resonance spectroscopy was used to study precursor solutions of the alkaline niobates and tantalates. Film crystallization temperatures were determined from X-ray diffraction patterns of powders derived from the metal oxide precursor solutions. Film structure was determined via X-ray diffraction. Film morphology was studied using scanning electron microscopy (SEM) and atomic force microscopy (AFM). Epitaxial thin-films of strontium bismuth tantalate (SrBi2Ta2O9, SBT) and strontium bismuth niobate (SrBi2Nb2O9, SBN) were deposited on single crystal [1 0 0] magnesium oxide (MgO) buffered with lanthanum manganate (LaMnO3, LMO). Epitaxial thin films of LMO were deposited on single crystal [100] MgO via Rf-magnetron sputtering and on single crystal [100] lanthanum aluminate (LaAlO3) via the chemical solution deposition technique. Epitaxial thin-films of sodium potassium tantalate (Na0.5K0.5TaO3, NKT), sodium potassium niobate (Na0.5K0.5NbO3, NKN) and sodium potassium tantalum niobate (Na0.5K0.5Ta0.5Nb0.5O3, NKTN) were deposited on single crystal [1 0 0] lanthanum aluminate and [1 0 0] MgO substrates (NKT and NKN) and biaxially textured metal substrates via the chemical solution deposition technique. Epitaxial growth of thin-films of NKT, NKN and NKTN was observed on LAO and Ni-5% W. Epitaxial growth of thin-films of NKN and the growth of c-axis aligned thin-films of NKT was observed on MgO. Nanoparticles of SBT, SBN, NKT and NKN were synthesized in reverse micelles from alkoxide precursor solutions. X-ray diffraction and transmission electron spectroscopy investigations reveal that amorphous nanoparticles (~5 nm) of SBT and SBN were synthesized. X-ray diffraction investigations reveal that nanoparticles (~3 nm) of NKT and NKN were also synthesized by this method.

Nanoinformatics

Nanoinformatics Book
Author : Isao Tanaka
Publisher : Springer
Release : 2018-01-15
ISBN : 9811076170
Language : En, Es, Fr & De

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Book Description :

This open access book brings out the state of the art on how informatics-based tools are used and expected to be used in nanomaterials research. There has been great progress in the area in which “big-data” generated by experiments or computations are fully utilized to accelerate discovery of new materials, key factors, and design rules. Data-intensive approaches play indispensable roles in advanced materials characterization. "Materials informatics" is the central paradigm in the new trend. "Nanoinformatics" is its essential subset, which focuses on nanostructures of materials such as surfaces, interfaces, dopants, and point defects, playing a critical role in determining materials properties. There have been significant advances in experimental and computational techniques to characterize individual atoms in nanostructures and to gain quantitative information. The collaboration of researchers in materials science and information science is growing actively and is creating a new trend in materials science and engineering.

Gallium Oxide

Gallium Oxide Book
Author : Stephen Pearton,Fan Ren,Michael Mastro
Publisher : Elsevier
Release : 2018-10-15
ISBN : 0128145226
Language : En, Es, Fr & De

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Book Description :

Gallium Oxide: Technology, Devices and Applications discusses the wide bandgap semiconductor and its promising applications in power electronics, solar blind UV detectors, and in extreme environment electronics. It also covers the fundamental science of gallium oxide, providing an in-depth look at the most relevant properties of this materials system. High quality bulk Ga2O3 is now commercially available from several sources and n-type epi structures are also coming onto the market. As researchers are focused on creating new complex structures, the book addresses the latest processing and synthesis methods. Chapters are designed to give readers a complete picture of the Ga2O3 field and the area of devices based on Ga2O3, from their theoretical simulation, to fabrication and application. Provides an overview of the advantages of the gallium oxide materials system, the advances in in bulk and epitaxial crystal growth, device design and processing Reviews the most relevant applications, including photodetectors, FETs, FINFETs, MOSFETs, sensors, catalytic applications, and more Addresses materials properties, including structural, mechanical, electrical, optical, surface and contact

Epitaxial and Lateral Solid phase Crystallization of Complex Oxides

Epitaxial and Lateral Solid phase Crystallization of Complex Oxides Book
Author : Yajin Chen
Publisher : Unknown
Release : 2019
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

The crystallization of complex-oxide materials through a transformation from the amorphous to crystalline forms presents a range of new opportunities to synthesize new materials, and simultaneously poses important scientific challenges. New crystallization method complements more conventional vapor-phase epitaxy techniques for epitaxial complex-oxide thin film growth that involve long-range surface diffusion on 2D planar crystal surfaces. The vapor-phase techniques are not readily adaptable to creating nanoscale epitaxial complex-oxide crystals. The alternative synthesis method described in this thesis is solid-phase crystallization, which is the crystallization of amorphous oxides, often in the form of thin films, by post-deposition heating. The creation of epitaxial complex-oxide nanostructures can facilitate their integration in 3D electronic, optoelectronic and ionic devices. Epitaxial complex-oxide crystals in intricate geometries can be created by solid-phase crystallization employing patterned substrates with a distribution of isolated crystalline seeds. This method requires the study of distinct crystal growth and nucleation kinetics on epitaxial and non-epitaxial surfaces. Nanoscale seeded crystallization can be achieved by understanding the relative rates of nucleation and lateral crystal growth processes, and the role of seeds in determining the overall orientation of the resulting crystals. Epitaxial complex-oxide thin films in intricate geometries with an expanded range of compositions can be created by combining the use of atomic layer deposition (ALD) and solid-phase crystallization, with the development of new ALD procedures to deposit amorphous oxide films and the study of the subsequent crystallization processes to select the crystalline structures of the crystallized film. ALD itself allows for the conformal deposition of thin films over non-planar surfaces. Solid-phase crystallization can also be used to deposit epitaxial complex-oxide thin films with a wider range of compositions, including those that cannot be deposited from the vapor phase at high temperatures. Such oxides include the oxides that have complex compositions and volatile components. The different kinetic constraints of solid-phase crystallization allow the epitaxial growth of those oxide thin films because of the slow diffusion in the solid state at relatively low crystallization temperatures. This thesis describes the discovery that, at low crystallization temperatures, epitaxial crystal growth of the model perovskite SrTiO3 on single-crystal SrTiO3 propagates over long distances without nucleation of SrTiO3 on Si with a native oxide. Two kinds of isolated nanoscale seed crystals are employed to study the seeded lateral crystallization of SrTiO3, yielding highly similar results. Micron-scale crystalline regions form surrounding the seeds before encountering separately nucleated crystals away from the seeds. Seed crystals play an important role in determining the orientations of the resulting crystals. New chemical precursors and ALD procedures were developed to grow amorphous PrAlO3 films. An epitaxial [lowercase gamma]-Al2O3 layer formed at the interface between the PrAlO3 film and (001) SrTiO3 substrate during the deposition. Epitaxial PrAlO3 films were achieved on (001) [lowercase gamma]-Al2O3/SrTiO3 by solid-phase epitaxy. The study of SrTiO3 and PrAlO[3] is also applicable to a series of chemically and structurally similar functional ABO3 compounds. The concepts of solid-phase crystallization also apply to oxides with multiple metal ions and more complex crystal structure. The kinetic processes occurring during the crystallization of ScAlMgO4, on (0001) sapphire substrates are quite different at two different temperatures. Epitaxial ScAlMgO4 crystals grow through the film thickness at a crystallization temperature of 950 °C. Solid-state reaction and evaporation of the component Sc prohibits the formation of large ScAlMgO4 crystals at a crystallization temperature of 1400 °C. Low-temperature crystallization can be used to create epitaxial oxide thin films with complex compositions and volatile components.

Japanese Journal of Applied Physics

Japanese Journal of Applied Physics Book
Author : Anonim
Publisher : Unknown
Release : 1999
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Japanese Journal of Applied Physics book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Quantum Dots Nanoparticles and Nanowires Volume 789

Quantum Dots  Nanoparticles and Nanowires  Volume 789 Book
Author : P. Guyot-Sionnest,N. J. Halas,H. Mattoussi,U. Woggon,Z. L. Wang
Publisher : Cambridge University Press
Release : 2004-05-04
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Nanostructures of semiconductors and metals show novel optical and transport properties, and offer the perspective of designing materials properties with unprecedented flexibility and control. This has motivated research in the synthesis and characterization of new materials. This 2004 book brings together scientists with various levels of expertise in the growth, characterization and applications of inorganic nanostructures, such as quantum dots, nanowires and nanorods, to discuss and share developments in the field. Reports focus on techniques to prepare and characterize novel materials, investigations of novel optical and electronic properties, and novel applications, such as those that are biologically inspired. Topics include: synthesis and characterization of semiconductor quantum dots, nanoparticles and nanowires using wet chemistry and molecular beam approaches; synthesis, characterization and novel properties of metallic nanostructures; optical properties of neutral and charged excitons and exciton complexes in self-assembled quantum dots; nanoscale devices and sensors based on nanostructures and their properties; and design and characterization of quantum dot-bioconjugates and their use in assay developments.

Fundamentals of Novel Oxide semiconductor Interfaces

Fundamentals of Novel Oxide semiconductor Interfaces Book
Author : C. R. Abernathy
Publisher : Unknown
Release : 2004
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Fundamentals of Novel Oxide semiconductor Interfaces book written by C. R. Abernathy, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Recent Developments in Oxide and Metal Epitaxy Theory and Experiment

Recent Developments in Oxide and Metal Epitaxy   Theory and Experiment  Book
Author : Mark Yeadon,Shirley Chiang,Robin f. C. Farrow,James W. Evans,Orlando Auciello
Publisher : Cambridge University Press
Release : 2014-06-05
ISBN : 9781107413085
Language : En, Es, Fr & De

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Book Description :

Thin-film epitaxy is integral to many current and emerging technologies, and continued progress in solving critical issues is essential to the realization of new devices. This book, first published in 2000, focuses on progress in solving fundamental issues in the epitaxial growth of metals and oxides. Insights from both experiment, and modeling are combined to facilitate cross fertilization of ideas and understanding. Highlighted is the use of in situ characterization techniques for enhancing the efficiency of materials development. Thin-film research is often empirical in nature. Techniques for minimizing the time spent exploring the complex parameter space in order to optimize growth and processing conditions are of particular value. Among the techniques discussed are spectroscopic ellipsometry and ion scattering and recoil spectrometry, LEEM (low-energy electron microscopy), STM (scanning tunneling microscopy), TEM (transmission electron microscopy) and RHEED (reflection high-energy electron diffraction). Topics include: growth and dynamics of metal films; structure and oxidation of metal films and surfaces; in situ studies of oxide growth and epitaxial growth of oxides.

Extended Abstracts

Extended Abstracts Book
Author : Electrochemical Society
Publisher : Unknown
Release : 1970
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Extended Abstracts book written by Electrochemical Society, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

1969 Abstracts of the Intermag Conference

1969 Abstracts of the Intermag Conference Book
Author : Anonim
Publisher : Unknown
Release : 1969
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download 1969 Abstracts of the Intermag Conference book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Abstracts

Abstracts Book
Author : Anonim
Publisher : Unknown
Release : 1969
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Abstracts book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Digests of the Intermag Conference

Digests of the Intermag Conference Book
Author : Anonim
Publisher : Unknown
Release : 1969
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Digests of the Intermag Conference book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Materials Science and Technology Structure of solids

Materials Science and Technology  Structure of solids Book
Author : Robert W. Cahn,Peter Haasen,Edward J. Kramer
Publisher : Unknown
Release : 1991
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Materials Science and Technology Structure of solids book written by Robert W. Cahn,Peter Haasen,Edward J. Kramer, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Alkoxide Routes to Inorganic Materials

Alkoxide Routes to Inorganic Materials Book
Author : Anonim
Publisher : Unknown
Release : 2007
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

An all alkoxide solution chemistry utilizing metal 2-methoxyethoxide complexes in 2-methoxyethanol was used to deposit thin-films of metal oxides on single-crystal metal oxide substrates and on biaxially textured metal substrates. This same chemistry was used to synthesize complex metal oxide nanoparticles. Nuclear Magnetic Resonance spectroscopy was used to study precursor solutions of the alkaline niobates and tantalates. Film crystallization temperatures were determined from x-ray diffraction patterns of powders derived from the metal oxide precursor solutions. Film structure was determined via x-ray diffraction. Film morphology was studied using scanning electron microscopy (SEM) and atomic force microscopy (AFM). Epitaxial thin-films of strontium bismuth tantalate (SrBi2Ta2O9, SBT) and strontium bismuth niobate (SrBi2Nb2O9, SBN) were deposited on single crystal [1 0 0] magnesium oxide (MgO) buffered with lanthanum manganate (LaMnO3, LMO). Epitaxial thin films of LMO were deposited on single crystal [100] MgO via Rf-magnetron sputtering and on single crysal [100] lanthanum aluminate (LaAlO3) via the chemical solution deposition technique. Epitaxial thin-films of sodium potassium tantalate (na{sub 0.5}K{sub 0.5}TaO3, NKT), sodium potassium niobate (Na{sub 0.5}K{sub 0.5}NbO3, NKN) and sodium potassium tantalum niobate (Na{sub 0.5}K{sub 0.5}Ta{sub 0.5}O3, NKTN) were deposited on single crystal [1 0 0] lanthanum aluminate and [1 0 0] MgO substrates (NKT and NKN) and biaxially textured metal substrates via the chemical solution deposition technique. Epitaxial growth of thin-films of NKT, NKN and NKTN was observed on LAO and Ni-5% W. Epitaxial growth of thin-films of NKN and the growth of c-axis aligned thin-films of NKT was observed on MgO. Nanoparticles of SBT, SBN, NKT and NKN were synthesized in reverse micelles from alkoxide precursor solutions. X-ray diffraction and transmission electron spectroscopy investigations reveal that amorphous nanoparticles ((almost equal to) 5 nm) of SBT and SBN were synthesized. X-ray diffraction investigations reveal that nanoparticles ((almost equal to) nm) of NKT and NKN were also synthesized by this method.