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Direct Synthesis Of Metal Complexes

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Direct Synthesis of Metal Complexes

Direct Synthesis of Metal Complexes Book
Author : B.I. Kharisov
Publisher : Elsevier
Release : 2018-04-19
ISBN : 0128110627
Language : En, Es, Fr & De

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Book Description :

Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter

Direct Synthesis of Coordination and Organometallic Compounds

Direct Synthesis of Coordination and Organometallic Compounds Book
Author : A.D. Garnovskii,B.I. Kharisov
Publisher : Elsevier
Release : 1999-08-13
ISBN : 9780080530444
Language : En, Es, Fr & De

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Book Description :

This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result of ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In these methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under the conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed. These methods have become the basis of a new field in synthetic chemistry - the direct synthesis of coordination and organometallic compounds from zero-valent metals. Particular aspects of the above problem have been described in a series of reviews and monographs. However, on the whole these main parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions. Some methods of direct synthesis have been developed in the former USSR (in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis) but, in spite of their novelty and/or wide applicability, they are practically unknown elsewhere due to the language barrier. Thus, another objective of this book is to acquaint the readers with the mentioned achievements. Every chapter contains the tables which describe all the reported data on direct reaction between metal atoms, metal particles or bulk metals with (in)organic ligans. There are some illustrations also (for example, the scheme of the reactor for gas-phase reaction between metal small particles and &bgr;-diketones).

Pincer Compounds

Pincer Compounds Book
Author : David Morales-Morales
Publisher : Elsevier
Release : 2018-04-11
ISBN : 0128129328
Language : En, Es, Fr & De

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Book Description :

Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

Molecular Electrochemistry of Inorganic Bioinorganic and Organometallic Compounds

Molecular Electrochemistry of Inorganic  Bioinorganic and Organometallic Compounds Book
Author : A.J.L. Pombeiro,J.A. McCleverty
Publisher : Springer Science & Business Media
Release : 2012-02-02
ISBN : 9401116288
Language : En, Es, Fr & De

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Book Description :

The use of electrochemical techniques by chemists, particularly those who regard themselves as "inorganic" coordination chemists, has undergone a very rapid growth in the last 15-20 years. The techniques, as dassically applied to inorganic species, had their origins in analytical chemistry, and the methodology had assumed, until the mid 60s, more importance than the chemiStry. However, the growth of interest in coordination compounds (including organometallic complexes) having unusually rich of electron-transfer in bio-inorganic redox properties, and in the understanding species, has propelfed electro-chemistry into the foreground of potentially readily available techniques for application to a very wide range of problems of interest to those chemists. This growth has been fuelled additionally by the availability of relatively cheap equipment of growing sophistication and by an increase in the "inorganic" chemists' general knowledge of physical electrochemistry. In particular, with increasing availability and sophistication of eqUipment, kinetic problems are now being addressed, and the range of electrode types and configuration and solvents has been greatly expanded. Furthermore, the rapid expansion of interest in biological problems has opened new avenues in functionalisation of electrodes, in the development of sensory devices and, in a sense, a return to the analytical base of the science, using novel and multi-disciplinary techniques drawing on synthesis chemistry of and electronic micro-engeneering. The drive towards increasing use microcomputer-controlled data analysis and the development of microeledrodes has opened exciting new avenues for the exploration of chemical reactions involving electron-transfer processes.

Transition Metal Organometallics in Organic Synthesis

Transition Metal Organometallics in Organic Synthesis Book
Author : Howard Alper
Publisher : Academic Press
Release : 2016-01-21
ISBN : 148321592X
Language : En, Es, Fr & De

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Book Description :

Transition Metal Organometallics in Organic Synthesis, Volume II covers chapters on the applications of arene and alkyne complexes, as well as cluster compounds, in organic synthesis. The book discusses the potential utility of transition metal-alkyne complexes and derived cluster compounds as reagents in organic synthesis, as well as the complexation reactions of arenes. The text also describes the oxidation, reduction, rearrangement, and other synthetically useful processes. Chemists will find the book invaluable.

Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity

Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity Book
Author : H. Geissbühler,G. T. Brooks,P. C. Kearney
Publisher : Elsevier
Release : 2013-10-22
ISBN : 1483278514
Language : En, Es, Fr & De

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Book Description :

Advances in Pesticide Science, Part 2: Synthesis of Pesticides, Chemical Structure and Biological Activity, Natural Products with Biological Activity is a collection of papers presented at the Fourth International Congress of Pesticide Chemistry, held in Zurich, Switzerland on July 24-28, 1978. This book is composed of forty eight chapters, and begins with the synthesis of pesticides. The succeeding chapters deal with heterocyclic synthesis by rearrangement, synthesis and transformations of nitrogen and sulphurcontaining bicyclic heterocyclic systems. These topics are followed by discussions on synthesis of bmc-analogous n-heterocycles from 1,2-, 1,3-, 1,4-, and 1,5- diamines. Other chapters describe the synthesis and herbicidal activity of 4-acylpyrazole derivatives, the synthesis and properties of plant growth regulators, the carboxyphenyl derivatives of five and six membered heterocycles and potential phosphorus-containing intermediates for the synthesis of pesticides. The final chapters consider the influence of antagonistic fungi on the spore-formation of rust fungi. This book will prove useful to agriculturists and organic chemists.

Carbonylation

Carbonylation Book
Author : H.M. Colquhoun,D.J. Thompson,M.V. Twigg
Publisher : Springer Science & Business Media
Release : 1991-05-31
ISBN : 9780306437472
Language : En, Es, Fr & De

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Book Description :

Describes and recommends catalytic carbonylation as a general tool in synthetic organic chemistry, dealing exclusively with laboratory scale reactions involving the interconversion of carbon monoxide and organic carbonyl compounds. Most of the reactions discussed involve catalytic formation of carbonyl compounds, but also considered are those requiring stoichiometric quantities of transition metal, and those that eliminate an organic carbonyl group as carbon monoxide. Annotation copyrighted by Book News, Inc., Portland, OR

The Chemistry of Pincer Compounds

The Chemistry of Pincer Compounds Book
Author : David Morales-Morales,Craig G.M. Jensen
Publisher : Elsevier
Release : 2011-08-11
ISBN : 9780080545158
Language : En, Es, Fr & De

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Book Description :

Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties. The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds * Covers the areas in which pincer complexes have had an impact * Includes information on more recent and interesting pincer compounds not just those that are well-known

Synthetic Coordination and Organometallic Chemistry

Synthetic Coordination and Organometallic Chemistry Book
Author : Alexander D. Garnovskii,Boris I. Kharissov
Publisher : CRC Press
Release : 2003-04-25
ISBN : 9780203911525
Language : En, Es, Fr & De

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Book Description :

This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.

Deuteride Materials

Deuteride Materials Book
Author : Jiping Liu,Xiaobo Liu
Publisher : Springer
Release : 2019-02-27
ISBN : 9811369623
Language : En, Es, Fr & De

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Book Description :

This is the very first book that offers an up-to-date and comprehensive overview on deuteride. It not only includes the concept, existing forms, key characteristics, but also reviews the preparation and characterization technologies and the latest research developments of deuteride. The special properties such as the nuclear properties, isotropic and neutron effect, poisonousness, radioactivity, volume expansion are systematically discussed to build up the sound understanding of the materials. In particular, this work reviews a number of commercial and scientific uses of the materials including nuclear reactors, NMR spectroscopy and medicines. Researchers and industrial professionals in medicine, chemistry, biochemistry, environmental sciences and defense sciences will benefit from this work.

Russian Chemical Reviews

Russian Chemical Reviews Book
Author : Anonim
Publisher : Unknown
Release : 2005
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Russian Chemical Reviews book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Alkaline Earth Metal Compounds

Alkaline Earth Metal Compounds Book
Author : Sjoerd Harder
Publisher : Springer
Release : 2013-07-20
ISBN : 3642362702
Language : En, Es, Fr & De

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Book Description :

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Handbook on Applications of Ultrasound

Handbook on Applications of Ultrasound Book
Author : Dong Chen,Sanjay K. Sharma,Ackmez Mudhoo
Publisher : CRC Press
Release : 2011-07-26
ISBN : 143984206X
Language : En, Es, Fr & De

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Book Description :

Ultrasonic irradiation and the associated sonochemical and sonophysical effects are complementary techniques for driving more efficient chemical reactions and yields. Sonochemistry—the chemical effects and applications of ultrasonic waves—and sustainable (green) chemistry both aim to use less hazardous chemicals and solvents, reduce energy consumption, and increase product selectivity. A comprehensive collection of knowledge, Handbook on Applications of Ultrasound covers the most relevant aspects linked to and linking green chemistry practices to environmental sustainability through the uses and applications of ultrasound-mediated and ultrasound-assisted biological, biochemical, chemical, and physical processes. Chapters are presented in the areas of: Medical applications Drug and gene delivery Nanotechnology Food technology Synthetic applications and organic chemistry Anaerobic digestion Environmental contaminants degradation Polymer chemistry Industrial syntheses and processes Reactor design Electrochemical systems Combined ultrasound−microwave technologies While the concepts of sonochemistry have been known for more than 80 years, in-depth understanding of this phenomenon continues to evolve. Through a review of the current status of chemical and physical science and engineering in developing more environmentally friendly and less toxic synthetic processes, this book highlights many existing applications and the enormous potential of ultrasound technology to upgrade present industrial, agricultural, and environmental processes.

Reaction Mechanisms of Metal Complexes

Reaction Mechanisms of Metal Complexes Book
Author : R W Hay
Publisher : Elsevier
Release : 2000-03-01
ISBN : 1782420630
Language : En, Es, Fr & De

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Book Description :

This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. Provides a general background as a course module in the area of inorganic reaction mechanisms, which has important research applications in the metallurgical industry Contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands

Official Gazette of the United States Patent and Trademark Office

Official Gazette of the United States Patent and Trademark Office Book
Author : United States. Patent and Trademark Office
Publisher : Unknown
Release : 1996
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Official Gazette of the United States Patent and Trademark Office book written by United States. Patent and Trademark Office, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Chemistry Under Extreme and Non Classical Conditions

Chemistry Under Extreme and Non Classical Conditions Book
Author : Rudi van Eldik,Colin D. Hubbard
Publisher : John Wiley & Sons
Release : 1996-12-06
ISBN : 9780471165613
Language : En, Es, Fr & De

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Book Description :

The very best and latest advances compiled in a single volume-an ideal resource for graduate students and researchers . . . Here is the perfect introduction to chemistry under extreme or non-classical conditions, including use of high temperature species, high pressure, supercritical media, sonochemistry, and microwave chemistry. Written by leading experts in their respective fields, this unique text applies a unified approach to each method, including background, instrumentation, examples, information on industrial applications (where relevant), and sources for further reading. Featured topics: * Chemical Synthesis Using High Temperature Species * Effect of Pressure on Inorganic Reactions * Effect of Pressure on Organic Reactions * Organic Synthesis at High Pressure * Inorganic and Related Chemical Reactions in Supercritical Fluids * Organic Chemistry in Supercritical Fluids * Industrial and Environmental Applications of Supercritical Fluids * Ultrasound as a New Tool for Synthetic Chemists * Applications of High Intensity Ultrasound in Polymer Chemistry * Chemistry Under Extreme Conditions in Water Induced Electrohydraulic Cavitation and Pulsed-Plasma Discharges * Microwave Dielectric Heating Effects in Chemical Synthesis * Biomolecules Under Extreme Conditions

New Polymer Nanocomposites for Environmental Remediation

New Polymer Nanocomposites for Environmental Remediation Book
Author : Chaudhery Mustansar Hussain,Ajay Kumar Mishra
Publisher : Elsevier
Release : 2018-02-19
ISBN : 0128110341
Language : En, Es, Fr & De

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Book Description :

New Polymer Nanocomposites for Environmental Remediation summarizes recent progress in the development of materials’ properties, fabrication methods and their applications for treatment of contaminants, pollutant sensing and detection. This book presents current research into how polymer nanocomposites can be used in environmental remediation, detailing major environmental issues, and key materials properties and existing polymers or nanomaterials that can solve these issues. The book covers the fundamental molecular structure of polymers used in environmental applications, the toxicology, economy and life-cycle analysis of polymer nanocomposites, and an analysis of potential future applications of these materials. Recent research and development in polymer nanocomposites has inspired the progress and use of novel and cost-effective environmental applications. Presents critical, actionable guidelines to the structure and property design of nanocomposites in environmental remediation Focuses on taking technology out of the lab and into the real world Summarizes the latest developments in polymer nanocomposites and their applications in catalytic degradation, adsorptive removal and detection of contaminants in the environment Enables researchers to stay ahead of the curve, with a full discussion of regulatory issues and potential new applications and materials in this area

Synthesis of Organometallic Compounds

Synthesis of Organometallic Compounds Book
Author : Sanshiro Komiya
Publisher : Wiley-Blackwell
Release : 1997-05-28
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Inorganic Chemistry This series reflects the breadth of modern research in inorganic chemistry and fulfils the need for advanced texts. The series covers the whole range of inorganic and physical chemistry, solid state chemistry, coordination chemistry, main group chemistry and bioinorganic chemistry. Synthesis of Organometallic Compounds A Practical Guide Edited by Sanshiro Komiya Tokyo University of Agriculture and Technology, Japan. This book describes the concepts of organometallic chemistry and provides an overview of the chemistry of each metal including the synthesis and handling of its important organometallic compounds. Synthesis of Organometallic Compounds: A Practical Guide provides: * an excellent introduction to organometallic synthesis * detailed synthetic protocols for the most important organometallic syntheses * an overview of the reactivity, applications and versatility of organometallic compounds * a survey of metals and their organometallic derivatives The purpose of this book is to serve as a practical guide to understanding the general concepts of organometallics for graduate students and scientists who are not necessarily specialists in organometallic chemistry.

Advances in Organometallic Chemistry

Advances in Organometallic Chemistry Book
Author : Anthony F. Hill,Mark J. Fink
Publisher : Academic Press
Release : 2013-09-11
ISBN : 0124078419
Language : En, Es, Fr & De

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Book Description :

Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field that has expanded enormously since the publication of Volume 1 in 1964. Informs and updates on all the latest developments in the field Contributions from leading authorities and industry experts

New Polymers for Special Applications

New Polymers for Special Applications Book
Author : Ailton De Souza Gomes
Publisher : BoD – Books on Demand
Release : 2012-09-12
ISBN : 9535107445
Language : En, Es, Fr & De

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Book Description :

This book comprises the contributions of several authors in the area of polymer physics by application of conducting polymers; hydrogel films on optical fiber core; thin film polymers; PDLC films application; photopolymers for holographic media; microwave absorption and EMI shielding behavior of nanocomposites based on intrinsically conducting polymers and graphene and carbon nanotubes; in the area of polymer synthesis of conducting polymers; oxidative polymerization of aniline; electro reductive polymerization; polysilanes with ordered sequences; radiation cross-linking poly(urethane-imide) and nitrogen-rich polymers as candidates for energetic applications; development of ruthenium complexes to novel functional nanocomposites. We hope that this book will help inspire readers to pursue study and research in this field.