Skip to main content

Direct Synthesis Of Metal Complexes

In Order to Read Online or Download Direct Synthesis Of Metal Complexes Full eBooks in PDF, EPUB, Tuebl and Mobi you need to create a Free account. Get any books you like and read everywhere you want. Fast Download Speed ~ Commercial & Ad Free. We cannot guarantee that every book is in the library!

Direct Synthesis of Coordination and Organometallic Compounds

Direct Synthesis of Coordination and Organometallic Compounds Book
Author : A.D. Garnovskii,B.I. Kharisov
Publisher : Elsevier
Release : 1999-08-13
ISBN : 9780080530444
Language : En, Es, Fr & De

GET BOOK

Book Description :

This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result of ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In these methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under the conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed. These methods have become the basis of a new field in synthetic chemistry - the direct synthesis of coordination and organometallic compounds from zero-valent metals. Particular aspects of the above problem have been described in a series of reviews and monographs. However, on the whole these main parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions. Some methods of direct synthesis have been developed in the former USSR (in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis) but, in spite of their novelty and/or wide applicability, they are practically unknown elsewhere due to the language barrier. Thus, another objective of this book is to acquaint the readers with the mentioned achievements. Every chapter contains the tables which describe all the reported data on direct reaction between metal atoms, metal particles or bulk metals with (in)organic ligans. There are some illustrations also (for example, the scheme of the reactor for gas-phase reaction between metal small particles and &bgr;-diketones).

Direct Synthesis of Metal Complexes

Direct Synthesis of Metal Complexes Book
Author : B.I. Kharisov
Publisher : Elsevier
Release : 2018-04-19
ISBN : 0128110627
Language : En, Es, Fr & De

GET BOOK

Book Description :

Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and more Describes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and water Includes experimental procedures, with examples of direct synthesis, at the end of each chapter

Carbonylation

Carbonylation Book
Author : H.M. Colquhoun,D.J. Thompson,M.V. Twigg
Publisher : Springer Science & Business Media
Release : 2013-06-29
ISBN : 1475795769
Language : En, Es, Fr & De

GET BOOK

Book Description :

Since the publication of our earlier book on transition metal mediated organic synthesis, * there has been a widespread increase of interest in this topic, and transition metal based methodology has become firmly established in many areas of organic chemistry. The direct, catalytic formation of organic carbonyl compounds using carbon monoxide as the source of the carbonyl group has seen exceptional progress, and this carbonylation chemistry is being used increasingly in research and on a larger scale for fine chemicals production. In view of these developments, there is a need for a modem, practi cally oriented book dealing with transition metal based carbonylation chemistry. The present monograph should help fulfill this need, since it is intended specifically to foster the adoption of catalytic carbonylation as a general tool in synthetic organic chemistry. It deals exclusively with reactions involving the interconversion of carbon monoxide and organic carbonyl compounds, and although the majority of the reactions discussed involve catalytic formation of carbonyl compounds, potentially valuable syntheses requiring stoichiometric quantities of transition metal are also included. In addition, a chapter is devoted to the remarkably useful reverse transformation (decarbonylation), in which an organic carbonyl group is eliminated in the form of carbon monoxide.

Transition metal Organometallics In Organic Synthesis

Transition metal Organometallics In Organic Synthesis Book
Author : Howard Alper
Publisher : Academic Press
Release : 2012-12-02
ISBN : 9780323161930
Language : En, Es, Fr & De

GET BOOK

Book Description :

Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis. The book is recommended as a reference for chemists and inorganic chemists who would like to learn the applications of organometallic complexes as reagents and catalysts.

Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity

Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity Book
Author : H. Geissbühler,G. T. Brooks,P. C. Kearney
Publisher : Elsevier
Release : 2013-10-22
ISBN : 1483278514
Language : En, Es, Fr & De

GET BOOK

Book Description :

Advances in Pesticide Science, Part 2: Synthesis of Pesticides, Chemical Structure and Biological Activity, Natural Products with Biological Activity is a collection of papers presented at the Fourth International Congress of Pesticide Chemistry, held in Zurich, Switzerland on July 24-28, 1978. This book is composed of forty eight chapters, and begins with the synthesis of pesticides. The succeeding chapters deal with heterocyclic synthesis by rearrangement, synthesis and transformations of nitrogen and sulphurcontaining bicyclic heterocyclic systems. These topics are followed by discussions on synthesis of bmc-analogous n-heterocycles from 1,2-, 1,3-, 1,4-, and 1,5- diamines. Other chapters describe the synthesis and herbicidal activity of 4-acylpyrazole derivatives, the synthesis and properties of plant growth regulators, the carboxyphenyl derivatives of five and six membered heterocycles and potential phosphorus-containing intermediates for the synthesis of pesticides. The final chapters consider the influence of antagonistic fungi on the spore-formation of rust fungi. This book will prove useful to agriculturists and organic chemists.

Synthetic Coordination and Organometallic Chemistry

Synthetic Coordination and Organometallic Chemistry Book
Author : Alexander D. Garnovskii,Boris I. Kharissov
Publisher : CRC Press
Release : 2003-04-25
ISBN : 9780203911525
Language : En, Es, Fr & De

GET BOOK

Book Description :

This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.

Copper II Complexes for Olefin Aziridination and Cyclopropanation

Copper II  Complexes for Olefin Aziridination and Cyclopropanation Book
Author : Henry U. Valle
Publisher : Unknown
Release : 2018
ISBN : 0987650XXX
Language : En, Es, Fr & De

GET BOOK

Book Description :

Aziridines and cyclopropanes are valued as important building blocks for the synthesis of a wide range of organic compounds, including biologically active compounds and pharmaceuticals. The development for more efficient and cost-effective catalysts for the atom transfer reaction with olefins is a continuing area of research in both organic and inorganic chemistry. Transition metal complexes, which catalyze reactions of olefins with nitrenes and carbenes, are well-developed efficient, approaches to the direct synthesis of aziridines and cyclopropanes, but traditionally rely on expensive synthetic methods. As part of our efforts in the catalytic formation of C—C and C—N bonds, herein we show the development of a new and efficient copper(II) catalyst that exhibits high reactivity forming cyclopropanes and aziridines from a range of olefins. These catalytic systems have also shown a propensity to conduct these atom-transfer reactions in aqueous solutions, affording the opportunity to use bio-macromolecules, like DNA, to induce enantioselectivity.

Transition metal Organometallics In Organic Synthesis

Transition metal Organometallics In Organic Synthesis Book
Author : Howard Alper
Publisher : Elsevier
Release : 2012-12-02
ISBN : 0323161936
Language : En, Es, Fr & De

GET BOOK

Book Description :

Transition Metal Organometallics in Organic Synthesis: Volume I reviews the literature in the field of organic synthesis with a focus on the most effective synthetic transformations. The text covers topics such as the general considerations in organic synthesis, C-C and C-X bond formations, and the isomerization and reorganization reactions of olefins. Also covered are topics such as displacement reactions with transition metal complexes, electrophilic reactions of organopalladium complexes, carbonylation reactions, and metal-carbene complexes — its structure, spectra, bonding, and direct synthesis. The book is recommended as a reference for chemists and inorganic chemists who would like to learn the applications of organometallic complexes as reagents and catalysts.

Deuteride Materials

Deuteride Materials Book
Author : Jiping Liu,Xiaobo Liu
Publisher : Springer
Release : 2019-02-27
ISBN : 9811369623
Language : En, Es, Fr & De

GET BOOK

Book Description :

This is the very first book that offers an up-to-date and comprehensive overview on deuteride. It not only includes the concept, existing forms, key characteristics, but also reviews the preparation and characterization technologies and the latest research developments of deuteride. The special properties such as the nuclear properties, isotropic and neutron effect, poisonousness, radioactivity, volume expansion are systematically discussed to build up the sound understanding of the materials. In particular, this work reviews a number of commercial and scientific uses of the materials including nuclear reactors, NMR spectroscopy and medicines. Researchers and industrial professionals in medicine, chemistry, biochemistry, environmental sciences and defense sciences will benefit from this work.

Science of Synthesis Houben Weyl Methods of Molecular Transformations Vol 2

Science of Synthesis  Houben Weyl Methods of Molecular Transformations Vol  2 Book
Author : Tsuneo Imamoto
Publisher : Georg Thieme Verlag
Release : 2014-05-14
ISBN : 3131717211
Language : En, Es, Fr & De

GET BOOK

Book Description :

Science of Synthesis provides a critical review of the synthetic methodology developed from the early 1800s to date for the entire field of organic and organometallic chemistry. As the only resource providing full-text descriptions of organic transformations and synthetic methods as well as experimental procedures, Science of Synthesis is therefore a unique chemical information tool. Over 1000 world-renowned experts have chosen the most important molecular transformations for a class of organic compounds and elaborated on their scope and limitations. The systematic, logical and consistent organization of the synthetic methods for each functional group enables users to quickly find out which methods are useful for a particular synthesis and which are not. Effective and practical experimental procedures can be implemented quickly and easily in the lab. // The content of this e-book was originally published in October 2002.

Russian Chemical Reviews

Russian Chemical Reviews Book
Author : Anonim
Publisher : Unknown
Release : 2008
ISBN : 0987650XXX
Language : En, Es, Fr & De

GET BOOK

Book Description :

Download Russian Chemical Reviews book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Alkaline Earth Metal Compounds

Alkaline Earth Metal Compounds Book
Author : Sjoerd Harder
Publisher : Springer
Release : 2013-07-20
ISBN : 3642362702
Language : En, Es, Fr & De

GET BOOK

Book Description :

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

New Applications of Organometallic Reagents in Organic Synthesis

New Applications of Organometallic Reagents in Organic Synthesis Book
Author : Dietmar Seyferth,American Chemical Society
Publisher : Unknown
Release : 1976
ISBN : 0987650XXX
Language : En, Es, Fr & De

GET BOOK

Book Description :

Download New Applications of Organometallic Reagents in Organic Synthesis book written by Dietmar Seyferth,American Chemical Society, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Handbook on Applications of Ultrasound

Handbook on Applications of Ultrasound Book
Author : Dong Chen,Sanjay K. Sharma,Ackmez Mudhoo
Publisher : CRC Press
Release : 2011-07-26
ISBN : 143984206X
Language : En, Es, Fr & De

GET BOOK

Book Description :

Ultrasonic irradiation and the associated sonochemical and sonophysical effects are complementary techniques for driving more efficient chemical reactions and yields. Sonochemistry—the chemical effects and applications of ultrasonic waves—and sustainable (green) chemistry both aim to use less hazardous chemicals and solvents, reduce energy consumption, and increase product selectivity. A comprehensive collection of knowledge, Handbook on Applications of Ultrasound covers the most relevant aspects linked to and linking green chemistry practices to environmental sustainability through the uses and applications of ultrasound-mediated and ultrasound-assisted biological, biochemical, chemical, and physical processes. Chapters are presented in the areas of: Medical applications Drug and gene delivery Nanotechnology Food technology Synthetic applications and organic chemistry Anaerobic digestion Environmental contaminants degradation Polymer chemistry Industrial syntheses and processes Reactor design Electrochemical systems Combined ultrasound−microwave technologies While the concepts of sonochemistry have been known for more than 80 years, in-depth understanding of this phenomenon continues to evolve. Through a review of the current status of chemical and physical science and engineering in developing more environmentally friendly and less toxic synthetic processes, this book highlights many existing applications and the enormous potential of ultrasound technology to upgrade present industrial, agricultural, and environmental processes.

New Polymer Nanocomposites for Environmental Remediation

New Polymer Nanocomposites for Environmental Remediation Book
Author : Chaudhery Mustansar Hussain,Ajay Kumar Mishra
Publisher : Elsevier
Release : 2018-02-19
ISBN : 0128110341
Language : En, Es, Fr & De

GET BOOK

Book Description :

New Polymer Nanocomposites for Environmental Remediation summarizes recent progress in the development of materials’ properties, fabrication methods and their applications for treatment of contaminants, pollutant sensing and detection. This book presents current research into how polymer nanocomposites can be used in environmental remediation, detailing major environmental issues, and key materials properties and existing polymers or nanomaterials that can solve these issues. The book covers the fundamental molecular structure of polymers used in environmental applications, the toxicology, economy and life-cycle analysis of polymer nanocomposites, and an analysis of potential future applications of these materials. Recent research and development in polymer nanocomposites has inspired the progress and use of novel and cost-effective environmental applications. Presents critical, actionable guidelines to the structure and property design of nanocomposites in environmental remediation Focuses on taking technology out of the lab and into the real world Summarizes the latest developments in polymer nanocomposites and their applications in catalytic degradation, adsorptive removal and detection of contaminants in the environment Enables researchers to stay ahead of the curve, with a full discussion of regulatory issues and potential new applications and materials in this area

Chemistry of Zeolites and Related Porous Materials

Chemistry of Zeolites and Related Porous Materials Book
Author : Ruren Xu,Wenqin Pang,Jihong Yu,Qisheng Huo,Jiesheng Chen
Publisher : John Wiley & Sons
Release : 2009-05-29
ISBN : 0470822368
Language : En, Es, Fr & De

GET BOOK

Book Description :

Widely used in adsorption, catalysis and ion exchange, the family of molecular sieves such as zeolites has been greatly extended and many advances have recently been achieved in the field of molecular sieves synthesis and related porous materials. Chemistry of Zeolites and Related Porous Materials focuses on the synthetic and structural chemistry of the major types of molecular sieves. It offers a systematic introduction to and an in-depth discussion of microporous, mesoporous, and macroporous materials and also includes metal-organic frameworks. Provides focused coverage of the key aspects of molecular sieves Features two frontier subjects: molecular engineering and host-guest advanced materials Comprehensively covers both theory and application with particular emphasis on industrial uses This book is essential reading for researches in the chemical and materials industries and research institutions. The book is also indispensable for researches and engineers in R&D (for catalysis) divisions of companies in petroleum refining and the petrochemical and fine chemical industries.

Green Synthesis of Silver Nanomaterials

Green Synthesis of Silver Nanomaterials Book
Author : Kamel A. Abd-Elsalam
Publisher : Elsevier
Release : 2021-11-01
ISBN : 0128245093
Language : En, Es, Fr & De

GET BOOK

Book Description :

Green Synthesis of Silver Nanomaterials illustrates how to biologically scale up silver nanoparticle synthesis. This book covers green synthesis of silver nanomaterials, via plants, agricultural waste, fungi, and microorganisms. Sections cover the synthesis and characterization of chemical and green synthesis, various types of silver nanomaterialism, the ability of different fungal species, such as filamentous fungi, to produce silver nanoparticles, the microbial synthesis of silver NMs, biosynthesis mechanisms, toxicity, fate and commercialization. As examples, greener pathways and mechanisms, toxicity of silver nanoparticles in aquatic life and in natural eco-systems, and strategies for the scaling up of green-synthesized nanomaterials are discussed. With the extended work in enhancing nanomaterials synthesis performance, and discovering their biomedical, environmental, and agricultural applications, it is hoped that the execution of these methods on a large scale and their industrial applications in different fields will take place in the near future. Assesses the impact of a large variety of silver-based nanostructures in the biomedical, environmental and agri-food sectors Discusses the major synthesis methods used for effectively processing plant-based silver nanoparticles Outlines the potential and major challenges for adopting green synthesis methods on a mass scale

Chemistry Under Extreme and Non Classical Conditions

Chemistry Under Extreme and Non Classical Conditions Book
Author : Rudi van Eldik,Colin D. Hubbard
Publisher : John Wiley & Sons
Release : 1996-12-06
ISBN : 9780471165613
Language : En, Es, Fr & De

GET BOOK

Book Description :

The very best and latest advances compiled in a single volume-an ideal resource for graduate students and researchers . . . Here is the perfect introduction to chemistry under extreme or non-classical conditions, including use of high temperature species, high pressure, supercritical media, sonochemistry, and microwave chemistry. Written by leading experts in their respective fields, this unique text applies a unified approach to each method, including background, instrumentation, examples, information on industrial applications (where relevant), and sources for further reading. Featured topics: * Chemical Synthesis Using High Temperature Species * Effect of Pressure on Inorganic Reactions * Effect of Pressure on Organic Reactions * Organic Synthesis at High Pressure * Inorganic and Related Chemical Reactions in Supercritical Fluids * Organic Chemistry in Supercritical Fluids * Industrial and Environmental Applications of Supercritical Fluids * Ultrasound as a New Tool for Synthetic Chemists * Applications of High Intensity Ultrasound in Polymer Chemistry * Chemistry Under Extreme Conditions in Water Induced Electrohydraulic Cavitation and Pulsed-Plasma Discharges * Microwave Dielectric Heating Effects in Chemical Synthesis * Biomolecules Under Extreme Conditions

Transition Metal Complexes of Phosphorus Arsenic Antimony Ligands

Transition Metal Complexes of Phosphorus  Arsenic   Antimony Ligands Book
Author : Anonim
Publisher : Macmillan International Higher Education
Release : 2015-12-26
ISBN : 1349815586
Language : En, Es, Fr & De

GET BOOK

Book Description :

Download Transition Metal Complexes of Phosphorus Arsenic Antimony Ligands book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Metal Complexes Containing Boron Based Ligands

Metal Complexes Containing Boron Based Ligands Book
Author : Gareth Owen
Publisher : MDPI
Release : 2019-10-30
ISBN : 3039215841
Language : En, Es, Fr & De

GET BOOK

Book Description :

Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.