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Carboranes

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Carboranes

Carboranes Book
Author : Russell N. Grimes
Publisher : Academic Press
Release : 2011-03-10
ISBN : 012374170X
Language : En, Es, Fr & De

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Book Description :

Carboranes, Second Edition is designed as a comprehensive source of information in a field that has experienced enormous growth in both its fundamental and applied aspects in the four decades since the publication of Carboranes (1970). During this long period thousands of original research papers have appeared, along with many review articles and book chapters dealing with aspects of carborane chemistry. As carborane science has grown in complexity, and applications have advanced steadily in areas such as medicine, nanostructured and electroactive materials, catalysis, polymers, and others, the need for a monograph covering the entire area in a unified treatment has become increasingly apparent. This volume has two principal objectives, the first of which is to provide a readable and concise introduction to the basic principles underlying the synthesis, structures, reactivity, and applications of carboranes and metallacarboranes at a level suitable for readers in industry and academe who are not trained in boron chemistry but find themselves working with, or lecturing about carboranes. Secondly, the book furnishes a trove of detailed information for workers active in carborane science and associated technologies. To that end, it incorporates tables listing thousands of specific compounds keyed to literature references, together with more than 2,000 molecular structure drawings that illuminate the accompanying discussion. Thorough treatment of the synthesis, structures, and reactions of carboranes, heterocarboranes, and metallacarboranes in the first 13 chapters is followed by four chapters detailing advances in practical applications in polymer science, catalysis, medicine, and other areas. Includes over 2,000 molecular structure drawings throughout the text Features tables listing thousands of compounds with key literature references

Carboranes

Carboranes Book
Author : Russell Grimes
Publisher : Elsevier
Release : 2012-12-02
ISBN : 0323157580
Language : En, Es, Fr & De

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Book Description :

Carboranes offers a comprehensive treatment of carborane chemistry and covers topics ranging from structures and chemical bonding to the degradation of the icosahedral cage. Carborane polymers as well as small nido- and closo-carboranes, intermediate closo-carboranes, and o-, m-, and p-carboranes are also discussed. This book is comprised of nine chapters and begins with an overview of the chemistry and properties of carboranes. The discussion then turns to the molecular structures of polyhedral carboranes and open-cage carboranes, along with the isomerism and rearrangement of carboranes; nomenclature and numbering systems used for carboranes; and chemical bonding in boranes and carboranes. The following chapters explore the synthesis, reactions, structures, and properties of small nido- and closo-carboranes, intermediate closo-carboranes, and o-, m-, and p-carboranes. The reactions of boranes and alkylboranes with alkynes as well as the degradation of icosahedral carboranes are also described. This monograph will be a useful resource for organic and inorganic chemists.

Carboranes

Carboranes Book
Author : Russell N. Grimes
Publisher : Academic Press
Release : 2016-12-20
ISBN : 0128019050
Language : En, Es, Fr & De

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Book Description :

Carboranes, Third Edition, by Russell Grimes, is the definitive resource on the subject. Completely updated with a wealth of research and review articles published in this active field since the previous volume was released in 2011, the book provides a readable and concise introduction to the basic principles underlying the synthesis, structures, and reactions of carboranes, heterocarboranes, and metallacarboranes. Following the valuable foundational information, the book explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science. These disciplines include polymer science, catalysis, biomedicine, nanomaterials, and others. Includes over 2,000 molecular structure drawings throughout the text Features expanded coverage on applications of carboranes, particularly in biomedicine and nanomaterials, given the growth of research in these areas Presents extended and updated tables, listing thousands of compounds with key literature references, provided online via the book’s website Explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science

Functionalization of Carborane via Carboryne Intermediates

Functionalization of Carborane via Carboryne Intermediates Book
Author : Da Zhao
Publisher : Springer
Release : 2016-06-04
ISBN : 9811015694
Language : En, Es, Fr & De

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Book Description :

This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and more. However, the limited number of efficient synthetic methods for obtaining functional carborane materials has restricted their applications. The methodologies established in this thesis represent simple, yet powerful strategies to assemble previously inaccessible, useful complex molecules, which will also have a significant impact on future synthetic, cluster and materials chemistry. Moreover, it discusses the first method for the in situ generation of electrophilic boron radical using photocatalysis.

Comprehensive Supramolecular Chemistry II

Comprehensive Supramolecular Chemistry II Book
Author : George W. Gokel,Len Barbour
Publisher : Elsevier
Release : 2017-06-22
ISBN : 0128031999
Language : En, Es, Fr & De

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Book Description :

Comprehensive Supramolecular Chemistry II, Second Edition is a ‘one-stop shop’ that covers supramolecular chemistry, a field that originated from the work of researchers in organic, inorganic and physical chemistry, with some biological influence. The original edition was structured to reflect, in part, the origin of the field. However, in the past two decades, the field has changed a great deal as reflected in this new work that covers the general principles of supramolecular chemistry and molecular recognition, experimental and computational methods in supramolecular chemistry, supramolecular receptors, dynamic supramolecular chemistry, supramolecular engineering, crystallographic (engineered) assemblies, sensors, imaging agents, devices and the latest in nanotechnology. Each section begins with an introduction by an expert in the field, who offers an initial perspective on the development of the field. Each article begins with outlining basic concepts before moving on to more advanced material. Contains content that begins with the basics before moving on to more complex concepts, making it suitable for advanced undergraduates as well as academic researchers Focuses on application of the theory in practice, with particular focus on areas that have gained increasing importance in the 21st century, including nanomedicine, nanotechnology and medicinal chemistry Fully rewritten to make a completely up-to-date reference work that covers all the major advances that have taken place since the First Edition published in 1996

Advanced Inorganic Chemistry Vollume II

Advanced Inorganic Chemistry  Vollume II Book
Author : Anonim
Publisher : Krishna Prakashan Media
Release : 2022-12-07
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Advanced Inorganic Chemistry Vollume II book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Boron Carboranes 2 new suppl ser v 27

Boron  Carboranes 2  new suppl  ser  v  27  Book
Author : Anonim
Publisher : Unknown
Release : 1974
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Boron Carboranes 2 new suppl ser v 27 book written by , available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Boron Boron and Cl Br I S Se Te Carboranes

Boron  Boron and Cl  Br  I  S  Se  Te  Carboranes Book
Author : Thomas Onak
Publisher : Unknown
Release : 1988
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Boron Boron and Cl Br I S Se Te Carboranes book written by Thomas Onak, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Organometallic Chemistry

Organometallic Chemistry Book
Author : M. Green
Publisher : Royal Society of Chemistry
Release : 2005
ISBN : 0854043438
Language : En, Es, Fr & De

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Book Description :

Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis, synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests, reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Volume 31 covers literature published during 2002. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading authorities in the relevant subject areas, the series creates a unique service for the active research chemist, with regular, in-depth accounts of progress in particular fields of chemistry. Subject coverage within different volumes of a given title is similar and publication is on an annual or biennial basis.

50th Anniversary of Electron Counting Paradigms for Polyhedral Molecules

50th Anniversary of Electron Counting Paradigms for Polyhedral Molecules Book
Author : D. Michael P. Mingos
Publisher : Springer Nature
Release : 2022-01-01
ISBN : 3030848639
Language : En, Es, Fr & De

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Book Description :

The 50 Year Anniversary of the development of electron counting paradigms for polyhedral molecules is celebrated in two volumes of Structure and Bonding. Volume 1 covers the historical development, theoretical models and applications to boranes and metalloboranes.

Boron Hydride Chemistry

Boron Hydride Chemistry Book
Author : Earl Muetterties
Publisher : Elsevier
Release : 2012-12-02
ISBN : 032314649X
Language : En, Es, Fr & De

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Book Description :

Boron Hydride Chemistry covers the significant contributions of boron hydride research in the subjects of bonding, structure, and stereochemistry. This book contains 12 chapters that illustrate the merging of certain areas of boron hydride chemistry with other disciplines, such as organic, organometallic, and transition metal chemistry. After providing an overview of the general geometric, stereochemical, and dynamic stereochemical features of boron hydrides, this book goes on exploring the bonding theory and theoretical research on boron hydrides, with an emphasis on boron hydrides that have open polyhedral structures. These topics are followed by discussions on gas phase and solution reactions of borane and substituted boranes. A chapter focuses on the chemistry of cations containing boron atoms bonded to hydrogen. The remaining chapters examine the syntheses, structures, bonding, spectral properties, and chemistry of specific boron hydrides, including borazines, closo-boron hydrides, carboranes, icosahedral carboranes, and close- and nido-heteroboranes. Inorganic chemists and researchers, teachers, and undergraduate inorganic chemistry students will find this book invaluable.

The Synthesis and Characterization of Some Monocarbon Carboranes and Derivatives Characterization of the Polynuclear Aromatic Hydrocarbon and Aliphatic Fractions of Solvent Refined Coal by Capillary column Gas Chromatography mass Spectroscopy

The Synthesis and Characterization of Some Monocarbon Carboranes and Derivatives   Characterization of the Polynuclear Aromatic Hydrocarbon and Aliphatic Fractions of Solvent Refined Coal by Capillary column Gas Chromatography mass Spectroscopy Book
Author : Rosemary V. Schultz
Publisher : Unknown
Release : 1979
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download The Synthesis and Characterization of Some Monocarbon Carboranes and Derivatives Characterization of the Polynuclear Aromatic Hydrocarbon and Aliphatic Fractions of Solvent Refined Coal by Capillary column Gas Chromatography mass Spectroscopy book written by Rosemary V. Schultz, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Metal Interactions with Boron Clusters

Metal Interactions with Boron Clusters Book
Author : Russell N. Grimes
Publisher : Springer Science & Business Media
Release : 2013-11-11
ISBN : 1489921540
Language : En, Es, Fr & De

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Book Description :

Molecular clusters, in the broad sense that the term is commonly understood, today comprise an enormous class of species extending into virtually every important area of chemistry: "naked" metal clusters, transition metal carbonyl clusters, hydrocarbon cages such as cubane (C H ) and dodecahedrane (C H ), 8 8 20 20 organometallic cluster complexes, enzymes containing Fe S or MoFe S 4 4 3 4 cores, high polymers based on carborane units, and, of course, the many kinds of polyhedral borane species. So large is the area spanned by these diverse classes that any attempt to deal with them comprehensively in one volume would, to say the least, be ambitious-and also premature. We are presently at a stage where intriguing relationships between the various cluster families are becoming apparent (particularly in terms of bonding descriptions), and despite large dif ferences in their chemistry an underlying unity is gradually developing in the field. For example, structural changes occurring in Fe S cores as electrons are 4 4 pumped in and out, in some measure resemble those observed in boranes and carboranes. The cleavage of alkynes via incorporation into carborane cages and subsequent cage rearrangement, a sequence familiar to boron chemists, is a thermodynamically favored process which may be related to the behavior of unsaturated hydrocarbons on metal surfaces; analogies of this sort have drawn attention from theorists and experimentalists.

Basic Organometallic Chemistry

Basic Organometallic Chemistry Book
Author : Ionel Haiduc,Jerry J. Zuckerman
Publisher : Walter de Gruyter
Release : 1985-01-01
ISBN : 3110847884
Language : En, Es, Fr & De

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Book Description :

Download Basic Organometallic Chemistry book written by Ionel Haiduc,Jerry J. Zuckerman, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Boron Science

Boron Science Book
Author : Narayan S. Hosmane
Publisher : CRC Press
Release : 2016-04-19
ISBN : 1439826633
Language : En, Es, Fr & De

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Book Description :

Boron has made a significant impact in our lives through its quiet use in fertilizers, fungicides, soaps, detergents, and heat-resistant glassware. Boron Science: New Technologies and Applications addresses the applications of boron in chemistry, industry, medicine, and pharmacology by explaining its role in problems such as catalysis and hydroboration as well as its use in superconductors, materials, magnetic/nonmagnetic nanoparticles, and medical applications including cancer therapy. Illustrating the practical versatility of boron, the 29 chapters are divided into seven major sections: Boron for Living: Medicine Boron for Living: Health and Nutrition Boron for Living: Radioisotope Boron for Living: Boron Neutron Capture Therapy Boron for Electronics: Optoelectronics Boron for Energy: Energy Storage, Space, and Other Applications Boron for Chemistry and Catalysis: Catalysis and Organic Transformations More than just an updated compilation of progress in the applied science of boron, this book is a tribute to the legions of workers who have spent years conducting groundbreaking studies. The book celebrates these scientists and their protégés, who together transformed boron science into the exciting and growing area it is today.

Boron Based Compounds

Boron Based Compounds Book
Author : Evamarie Hey-Hawkins,Clara Viñas Teixidor
Publisher : John Wiley & Sons
Release : 2018-07-23
ISBN : 1119275555
Language : En, Es, Fr & De

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Book Description :

Noted experts review the current status of boron-containing drugs and materials for molecular medical diagnostics Boron-Based Compounds offers a summary of the present status and promotes the further development of new boron-containing drugs and advanced materials, mostly boron clusters, for molecular medical diagnostics. The knowledge accumulated during the past decades on the chemistry and biology of bioorganic and organometallic boron compounds laid the foundation for the emergence of a new area of study and application of boron compounds as lipophilic pharmacophores and modulators of biologically active molecules.This important text brings together in one comprehensive volume contributions from renowned experts in the field of medicinal chemistry of boron compounds. The authors cover a range of the most relevant topics including boron compounds as modulators of the bioactivity of biomolecules, boron clusters as pharmacophores or for drug delivery, boron compounds for boron neutron capture therapy (BNCT) and for diagnostics, as well as in silico molecular modeling of boron- and carborane-containing compounds in drug design. Authoritative and accessible, Boron-Based Compounds: Contains contributions from a panel of internationally renowned experts in the field Offers a concise summary of the current status of boron-containing drugs and materials used for molecular diagnostics Highlights the range and capacity of boron-based compounds in medical applications Includes information on boron neutron capture therapy and diagnostics Designed for academic and industrial scientists, this important resource offers the cutting-edge information needed to understand the current state of boron-containing drugs and materials for molecular medical diagnostics.

Hypercarbon Chemistry

Hypercarbon Chemistry Book
Author : George A. Olah,G. K. Surya Prakash,Robert E. Williams,Kenneth Wade,Árpád Molnár
Publisher : John Wiley & Sons
Release : 2011-08-04
ISBN : 9781118016459
Language : En, Es, Fr & De

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Book Description :

The essential new edition of the book that put hypercarbon chemistry on the map A comprehensive and contemporary treatment of the chemistry of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) towards electrophiles, Hypercarbon Chemistry, Second Edition deals with all major aspects of such chemistry involved in hydrocarbon transformations, and of the structural and reaction chemistry of carboranes, mixed hydrides in which both carbon and boron atoms participate in the polyhedral molecular frameworks. Despite the firmly established tetravalency, carbon can bond simultaneously to five or more other atoms. "Hypercarbon" bonding permeates much organic, inorganic and organometallic chemistry, and the book serves as the compendium for this phenomenon. Copious diagrams illustrate the rich variety of hypercarbon structures now known, and patterns therein. Individual chapters deal with specific categories of compound (e.g. organometallics, carboranes, carbocations) or transformations that proceed through transient hypercarbon species, detailing fundamental chemistry, including reactivity, selectivity, stereochemistry, mechanistic factors and more.

Future Directions in Biocatalysis

Future Directions in Biocatalysis Book
Author : Tomoko Matsuda
Publisher : Elsevier
Release : 2017-08-11
ISBN : 0444637508
Language : En, Es, Fr & De

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Book Description :

Future Directions in Biocatalysis, Second Edition, presents the future direction and latest research on how to utilize enzymes, i.e., natural catalysts, to make medicines and other necessities for humans. It emphasizes the most important and unique research on biocatalysis instead of simply detailing the ABC’s on the topic. This book is an indispensable tool for new researchers in the field to help identify specific needs, start new projects that address current environmental concerns, and develop techniques based on green technology. It provides invaluable hints and clues for conducting new research on enzymes, with final sections outlining future directions in biocatalysis further expanding the science into new applications. Gives future directions in the area of biocatalysis research Presents research topics based on their uniqueness, originality, and novelty Includes many explanatory figures to demonstrate concepts to both organic chemists and biochemists Shows that there is no boundary between organic chemistry and biochemistry

Chemistry of the Elements

Chemistry of the Elements Book
Author : N. N. Greenwood,A. Earnshaw
Publisher : Elsevier
Release : 2012-12-02
ISBN : 0080501095
Language : En, Es, Fr & De

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Book Description :

When this innovative textbook first appeared in 1984 it rapidly became a great success throughout the world and has already been translated into several European and Asian languages. Now the authors have completely revised and updated the text, including more than 2000 new literature references to work published since the first edition. No page has been left unaltered but the novel features which proved so attractive have been retained. The book presents a balanced, coherent and comprehensive account of the chemistry of the elements for both undergraduate and postgraduate students. This crucial central area of chemistry is full of ingenious experiments, intriguing compounds and exciting new discoveries. The authors specifically avoid the term `inorganic chemistry' since this evokes an outmoded view of chemistry which is no longer appropriate in the final decade of the 20th century. Accordingly, the book covers not only the 'inorganic' chemistry of the elements, but also analytical, theoretical, industrial, organometallic, bio-inorganic and other cognate areas of chemistry. The authors have broken with recent tradition in the teaching of their subject and adopted a new and highly successful approach based on descriptive chemistry. The chemistry of the elements is still discussed within the context of an underlying theoretical framework, giving cohesion and structure to the text, but at all times the chemical facts are emphasized. Students are invited to enter the exciting world of chemical phenomena with a sound knowledge and understanding of the subject, to approach experimentation with an open mind, and to assess observations reliably. This is a book that students will not only value during their formal education, but will keep and refer to throughout their careers as chemists. Completely revised and updated Unique approach to the subject More comprehensive than competing titles