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Asymmetric Domino Reactions

Asymmetric Domino Reactions Book
Author : Hélène Pellissier
Publisher : Royal Society of Chemistry
Release : 2013-03-13
ISBN : 1849736510
Language : En, Es, Fr & De

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Book Description :

This book covers the latest developments in asymmetric domino reactions, focussing on those published in the last 6 years. These fascinating reactions have rapidly become one of the most current fields in organic chemistry, since they allow reaching easily high molecular complexity in an economically favourable way with advantages of savings in solvent, time, energy, and costs. Unsurprisingly, the high levels of efficiency and enantioselectivity generally reached in these reactions have been exploited for the production of a wide number of complex chiral molecules with dense stereochemistry and functionality, which are motifs present in biologically active compounds and natural products. The book is divided into three principal sections, dealing successively with asymmetric domino reactions based on the use of chiral auxiliaries, asymmetric domino reactions based on the use of chiral metal catalysts, and asymmetric domino reactions based on the use of chiral organocatalysts, covering the literature since the beginning of 2006try{F5_flush(document);}catch(e){}

Asymmetric Metal Catalysis in Enantioselective Domino Reactions

Asymmetric Metal Catalysis in Enantioselective Domino Reactions Book
Author : Helene Pellissier
Publisher : John Wiley & Sons
Release : 2019-07-12
ISBN : 3527822526
Language : En, Es, Fr & De

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Book Description :

Introduces an innovative and outstanding tool for the easy synthesis of complex chiral structures in a single step Covering all of the literature since the beginning of 2006, this must-have book for chemists collects the major progress in the field of enantioselective one-, two-, and multicomponent domino reactions promoted by chiral metal catalysts. It clearly illustrates how enantioselective metal-catalyzed processes constitute outstanding tools for the development of a wide variety of fascinating one-pot asymmetric domino reactions, thereby allowing many complex products to be easily generated from simple materials in one step. The book also strictly follows the definition of domino reactions by Tietze as single-, two-, as well as multicomponent transformations. Asymmetric Metal Catalysis in Enantioselective Domino Reactions is divided into twelve chapters, dealing with enantioselective copper-, palladium-, rhodium-, scandium-, silver-, nickel-, gold-, magnesium-, cobalt-, zinc-, yttrium and ytterbium-, and other metal-catalyzed domino reactions. Most of the chapters are divided into two parts dealing successively with one- and two-component domino reactions, and three-component processes. Each part is subdivided according to the nature of domino reactions. Each chapter of the book includes selected applications of synthetic methodologies to prepare natural and biologically active products. -Presents the novel combination of asymmetric metal catalysis with the concept of fascinating domino reactions, which allows high molecular complexity with a remarkable level of enantioselectivity -Showcases an incredible tool synthesizing complex and diverse chiral structures in a single reaction step -Includes applications in total synthesis of natural products and biologically active compounds -Written by a renowned international specialist in the field -Stimulates the design of novel asymmetric domino reactions and their use in the synthesis of natural products, pharmaceuticals, agrochemicals, and materials Asymmetric Metal Catalysis in Enantioselective Domino Reactions will be of high interest to synthetic, organic, medicinal, and catalytic chemists in academia and R&D departments.

Organocatalytic Asymmetric Domino Reactions Via N heterocyclic Carbene and Bifunctional Hydrogen bonding Donor Catalysts

Organocatalytic Asymmetric Domino Reactions Via N heterocyclic Carbene and Bifunctional Hydrogen bonding Donor Catalysts Book
Author : Long Zhao
Publisher : Unknown
Release : 2018*
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Organocatalytic Asymmetric Domino Reactions Via N heterocyclic Carbene and Bifunctional Hydrogen bonding Donor Catalysts book written by Long Zhao, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

N heterocyclic Carbene and Copper catalyzed Asymmetric Domino Reactions

N heterocyclic Carbene   and Copper catalyzed Asymmetric Domino Reactions Book
Author : Tao Shu
Publisher : Unknown
Release : 2018
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download N heterocyclic Carbene and Copper catalyzed Asymmetric Domino Reactions book written by Tao Shu, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Asymmetric Metal Catalysis in Enantioselective Domino Reactions

Asymmetric Metal Catalysis in Enantioselective Domino Reactions Book
Author : Hélène Pellissier
Publisher : Unknown
Release : 2019
ISBN : 9783527822539
Language : En, Es, Fr & De

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Book Description :

Introduces an innovative and outstanding tool for the easy synthesis of complex chiral structures in a single step Covering all of the literature since the beginning of 2006, this must-have book for chemists collects the major progress in the field of enantioselective one-, two-, and multicomponent domino reactions promoted by chiral metal catalysts. It clearly illustrates how enantioselective metal-catalyzed processes constitute outstanding tools for the development of a wide variety of fascinating one-pot asymmetric domino reactions, thereby allowing many complex products to be easily generated from simple materials in one step. The book also strictly follows the definition of domino reactions by Tietze as single-, two-, as well as multicomponent transformations. Asymmetric Metal Catalysis in Enantioselective Domino Reactions is divided into twelve chapters, dealing with enantioselective copper-, palladium-, rhodium-, scandium-, silver-, nickel-, gold-, magnesium-, cobalt-, zinc-, yttrium and ytterbium-, and other metal-catalyzed domino reactions. Most of the chapters are divided into two parts dealing successively with one- and two-component domino reactions, and three-component processes. Each part is subdivided according to the nature of domino reactions. Each chapter of the book includes selected applications of synthetic methodologies to prepare natural and biologically active products.-Presents the novel combination of asymmetric metal catalysis with the concept of fascinating domino reactions, which allows high molecular complexity with a remarkable level of enantioselectivity -Showcases an incredible tool synthesizing complex and diverse chiral structures in a single reaction step -Includes applications in total synthesis of natural products and biologically active compounds -Written by a renowned international specialist in the field -Stimulates the design of novel asymmetric domino reactions and their use in the synthesis of natural products, pharmaceuticals, agrochemicals, and materials Asymmetric Metal Catalysis in Enantioselective Domino Reactions will be of high interest to synthetic, organic, medicinal, and catalytic chemists in academia and R & D departments.

Asymmetric Domino Reactions

Asymmetric Domino Reactions Book
Author : Helene Pellissier
Publisher : Royal Society of Chemistry
Release : 2013-03-13
ISBN : 184973710X
Language : En, Es, Fr & De

GET BOOK

Book Description :

This book covers the latest developments in asymmetric domino reactions, focussing on those published in the last 6 years. These fascinating reactions have rapidly become one of the most current fields in organic chemistry, since they allow reaching easily high molecular complexity in an economically favourable way with advantages of savings in solvent, time, energy, and costs. Unsurprisingly, the high levels of efficiency and enantioselectivity generally reached in these reactions have been exploited for the production of a wide number of complex chiral molecules with dense stereochemistry and functionality, which are motifs present in biologically active compounds and natural products. The book is divided into three principal sections, dealing successively with asymmetric domino reactions based on the use of chiral auxiliaries, asymmetric domino reactions based on the use of chiral metal catalysts, and asymmetric domino reactions based on the use of chiral organocatalysts, covering the literature since the beginning of 2006.

Asymmetric Metal Catalysis in Enantioselective Domino Reactions

Asymmetric Metal Catalysis in Enantioselective Domino Reactions Book
Author : Helene Pellissier
Publisher : John Wiley & Sons
Release : 2019-08-02
ISBN : 3527822518
Language : En, Es, Fr & De

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Book Description :

Introduces an innovative and outstanding tool for the easy synthesis of complex chiral structures in a single step Covering all of the literature since the beginning of 2006, this must-have book for chemists collects the major progress in the field of enantioselective one-, two-, and multicomponent domino reactions promoted by chiral metal catalysts. It clearly illustrates how enantioselective metal-catalyzed processes constitute outstanding tools for the development of a wide variety of fascinating one-pot asymmetric domino reactions, thereby allowing many complex products to be easily generated from simple materials in one step. The book also strictly follows the definition of domino reactions by Tietze as single-, two-, as well as multicomponent transformations. Asymmetric Metal Catalysis in Enantioselective Domino Reactions is divided into twelve chapters, dealing with enantioselective copper-, palladium-, rhodium-, scandium-, silver-, nickel-, gold-, magnesium-, cobalt-, zinc-, yttrium and ytterbium-, and other metal-catalyzed domino reactions. Most of the chapters are divided into two parts dealing successively with one- and two-component domino reactions, and three-component processes. Each part is subdivided according to the nature of domino reactions. Each chapter of the book includes selected applications of synthetic methodologies to prepare natural and biologically active products. -Presents the novel combination of asymmetric metal catalysis with the concept of fascinating domino reactions, which allows high molecular complexity with a remarkable level of enantioselectivity -Showcases an incredible tool synthesizing complex and diverse chiral structures in a single reaction step -Includes applications in total synthesis of natural products and biologically active compounds -Written by a renowned international specialist in the field -Stimulates the design of novel asymmetric domino reactions and their use in the synthesis of natural products, pharmaceuticals, agrochemicals, and materials Asymmetric Metal Catalysis in Enantioselective Domino Reactions will be of high interest to synthetic, organic, medicinal, and catalytic chemists in academia and R&D departments.

Development of New Asymmetric Organocatalytic Domino Reactions for the Synthesis of benzo fused Five and Benzo fused Six membered Cyclic Compounds

Development of New Asymmetric Organocatalytic Domino Reactions for the Synthesis of  benzo fused  Five  and Benzo fused Six membered Cyclic Compounds Book
Author : Stanimira Hristeva
Publisher : Unknown
Release : 2016
ISBN : 9783843925358
Language : En, Es, Fr & De

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Book Description :

Download Development of New Asymmetric Organocatalytic Domino Reactions for the Synthesis of benzo fused Five and Benzo fused Six membered Cyclic Compounds book written by Stanimira Hristeva, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Domino Reactions

Domino Reactions Book
Author : Lutz F. Tietze
Publisher : John Wiley & Sons
Release : 2013-12-23
ISBN : 3527671323
Language : En, Es, Fr & De

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Book Description :

The follow-up to the successful "Domino Reaction in Organic Synthesis", this ready reference brings up to date on the original concept. The chapters have been arranged according to the name of well-known transformations of the first step and in combination with the formed products. Each chapter is written by an internationally renowned expert, and the book is edited by L. F. Tietze, who established the concept of domino reactions. The one-stop source for all synthetic chemists to improve the synthetic efficiency and allow an ecologically and economically beneficial preparation of every chemical compound.

Domino and Intramolecular Rearrangement Reactions as Advanced Synthetic Methods in Glycoscience

Domino and Intramolecular Rearrangement Reactions as Advanced Synthetic Methods in Glycoscience Book
Author : Zbigniew J. Witczak,Roman Bielski
Publisher : John Wiley & Sons
Release : 2016-02-23
ISBN : 1119044200
Language : En, Es, Fr & De

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Book Description :

The book consists of a brief introduction, a foreward provided by professor Danishefsky of Columbia University, and about 14 – 16 chapters, each written by one or two eminent scholars/authors describing their recent research in the area of either domino reactions or intramolecular rearrangements in carbohydrate chemistry. Three or four chapters will be reviews. The domino (cascade, tandem) reactions are always intramolecular. They are usually very fast, clean and offer highly complex structures in a one pot process. Intramolecular rearrangements offer very similar advantages and often lead to highly complex products as well. Although many recently isolated carbohydrates fulfill various sophisticated functions, their structures are often very complex. The editors cover the broadest scope of novel methodologies possible. All the synthetic and application aspects of domino/cascade reactions are explored in this book. A second theme that will be covered is intramolecular rearrangement, which is also fast, stereoselective, and often constitutes one or more steps of domino /cascade process. Selected examples of intramolecular rearrangements are presented. Together, both processes offer an elegant and convenient approach to the synthesis of many complex molecules, which are normally difficult to synthesize via alternative routes. It appears that domino and intramolecular rearrangements are ideally suited to synthesize certain specific modified monosaccharides. What is particularly important is that both processes are intermolecular and almost always yield products with very well-defined stereochemistry. This high definition is absolutely crucial when synthesizing advanced, modified mono and oligosaccharides. The choice of contributors reflects an emphasis on both therapeutic and pharmacological aspects of carbohydrate chemistry.

Enantioselective Multicatalysed Tandem Reactions

Enantioselective Multicatalysed Tandem Reactions Book
Author : Helene Pellissier
Publisher : Royal Society of Chemistry
Release : 2014-08-19
ISBN : 1782621350
Language : En, Es, Fr & De

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Book Description :

Chiral molecules are needed for the production of many pharmaceuticals and materials, and catalytic asymmetric synthesis provides a method for the preparation of such chiral products. For the synthesis of complex molecules, such as natural products and biologically active compounds, more than one catalytic reaction may be necessary and tandem catalysis refers to the combination of catalytic reactions into one synthesis. By combing catalysts it enables a more efficient, economical and selective one pot approach for complex molecule synthesis which could not be achieved through single specific catalytic systems. The challenge is finding the right catalyst which is compatible with other catalysts but also tolerates reagents, solvent and intermediates generated during the course of the reaction. Enantioselective Multicatalysed Tandem Reactions provides an overview of recent developments in the area. The first part of the book covers asymmetric tandem reactions catalysed by multiple catalysts from the same discipline (organocatalysts, two metal and multienzyme-catalysed reactions). The second part looks at tandem reactions catalysed by multiple catalysts from different disciplines including reactions catalysed by a combination of metals and organocatalysts, reactions catalysed by a combination of metals and enzymes, and finally reactions catalysed by a combination of organocatalysts and enzymes. The book will appeal to researchers and professionals in academic and industrial laboratories interested in catalysis, biocatalysis and organic synthesis of chiral compounds.

Domino Reactions in Organic Synthesis

Domino Reactions in Organic Synthesis Book
Author : Lutz F. Tietze,Gordon Brasche,Kersten Gericke
Publisher : John Wiley & Sons
Release : 2006-12-13
ISBN : 3527608680
Language : En, Es, Fr & De

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Book Description :

Domino reactions enable you to build complex structures in one-pot reactions without the need to isolate intermediates- a dream comes true. In this book, the well-respected expert, Professor Lutz Tietze, summarizes the possibilities of this reaction type - an approach for an efficiant, economically benificial and ecological benign synthesis. A definite must for every organic chemist.

Catalytic Asymmetric Conjugate Reactions

Catalytic Asymmetric Conjugate Reactions Book
Author : Armando Cordova
Publisher : Wiley-VCH
Release : 2010-08-30
ISBN : 9783527324118
Language : En, Es, Fr & De

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Book Description :

This unique and long-awaited handbook on this important topic in the hot field of stereoselective organic synthesis covers several types of nucleophiles. Top international authors deal with modern forms of achieving stereoselective conjugate additions based on the use of chiral auxiliaries or asymmetric catalysis, such as P-N ligands, organocatalysis, domino reactions, Lewis acid and base catalysis. There is also a discussion of the employment of enantioselective conjugate addition transformations in total synthesis of important molecules. With its reliable and previously unpublished experimental procedures, this is a true source of high quality information.

Modern Tools for the Synthesis of Complex Bioactive Molecules

Modern Tools for the Synthesis of Complex Bioactive Molecules Book
Author : Stellios Arseniyadis
Publisher : John Wiley & Sons
Release : 2012-10-09
ISBN : 9780470616185
Language : En, Es, Fr & De

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Book Description :

"This book provides an overview of the new technologies that have revolutionized organic chemistry and allowed an easy access to very important complex bioactives. It is the only book of its kind assocating modern synthetic techniques and structurally complex bioactives, and includes some representative experimental procedures for particular methods. The synthesis of structurally complex molecules has become a real challenge among the synthetic community"--

Multicomponent Reactions

Multicomponent Reactions Book
Author : Jieping Zhu,Hugues Bienaymé
Publisher : John Wiley & Sons
Release : 2006-03-06
ISBN : 3527604243
Language : En, Es, Fr & De

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Book Description :

In the very first book on this hot topic, the expert editors andauthors present a comprehensive overview of these elegantreactions. From the contents: Organoboron compounds Free-radical mediated multicomponent coupling reactions Applications in drug discovery Metal catalyzed reactions Total synthesis of natural products Asymmetric isocyanide-based reactions The Biginelli reaction Asymmetric isocyanide-based reactions The Domino-Knoevenagel-Hetero-Diels-Alder Reaction and relatedtransformations Catalytic asymmetric reactions Algorithm based methods for discovering novel reactions Post-condensation modifications of the Passerini and Ugireactions An essential reference for organic and catalytic chemists, andthose working in organometallics both in academia and industry.

Sustainable Catalysis

Sustainable Catalysis Book
Author : Michael North
Publisher : Royal Society of Chemistry
Release : 2015-11-16
ISBN : 1782626433
Language : En, Es, Fr & De

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Book Description :

Catalysis is a fundamentally sustainable process which can be used to produce a wide range of chemicals and their intermediates. Focussing on those catalytic processes which offer the most sustainability, this two-part book explores recent developments in this field, as well as examining future challenges. Focussing on catalysis without metals or other endangered elements, each chapter covers a different type of organocatalyst. Beginning with chapters on acid and base catalysis, the book then concentrates on asymmetric catalysis. Several chapters cover pyrrolidine-based and cinchona alkaloid-based catalysts, whilst other chapters examine further organoctalysts which are constructed only from sustainable elements. Together with “Sustainable Catalysis: With Non-endangered Metals”, these books examine the progress in sustainable catalysis in all areas of chemistry, and are an important reference for researchers working in catalysis and green chemistry.

Hydroformylation for Organic Synthesis

Hydroformylation for Organic Synthesis Book
Author : Maurizio Taddei,André Mann
Publisher : Springer
Release : 2014-07-08
ISBN : 3642450598
Language : En, Es, Fr & De

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Book Description :

The Role of Metals and Ligands in Organic Hydroformylation, by Luca Gonsalvi, Antonella Guerriero, Eric Monflier, Frédéric Hapiot, Maurizio Peruzzini. Hydroformylation in Aqueous Biphasic Media Assisted by Molecular Receptors, by Frédéric Hapiot, Hervé Bricout, Sébastien Tilloy, Eric Monflier. Asymmetric Hydroformylation, by Bernabé F. Perandones, Cyril Godard, Carmen Claver. Domino Reactions Triggered by Hydroformylation, by Elena Petricci, Elena Cini. Rhodium-Catalyzed Hydroformylation in Fused Azapolycycles Synthesis, by Roberta Settambolo. Hydroformylation in Natural Product Synthesis, by Roderick W. Bates, Sivarajan Kasinathan.

Classics in Total Synthesis II

Classics in Total Synthesis II Book
Author : K. C. Nicolaou,S. A. Snyder
Publisher : Wiley-VCH
Release : 2003-10-17
ISBN : 9783527306848
Language : En, Es, Fr & De

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Book Description :

Classics in Total Synthesis II is the long awaited sequel to Classics in Total Synthesis, a book that has made its mark as a superb tool for educating students and practitioners alike in the art of organic synthesis since its introduction in 1996. In this highly welcomed new volume, K. C. Nicolaou and Scott A. Snyder discuss in detail the most impressive accomplishments in natural product total synthesis during the 1990s and the first years of the 21st century. While all of the features that made the first volume of Classics so popular and unique as a teaching tool have been maintained, in this new treatise the authors seek to present the latest techniques and advances in organic synthesis as they beautifully describe the works of some of the most renowned synthetic organic chemists of our time. · domino reactions, cascade sequences, biomimetic strategies, and asymmetric catalysis are systematically developed through the chosen synthesis · cutting edge synthetic technologies are discussed in terms of mechanism and scope · new reactions, such as olefin metathesis, are presented in mini-review style · abundant references are given for further reading Graduate students, educators, and researchers in the fields of synthetic and medicinal chemistry will wish to have a copy of this book in their collection as an indispensable companion that both augments and supplements the original Classics in Total Synthesis. From reviews of "Classics in Total Synthesis": "... a volume, (..) which any chemist with an interest in synthetic organic chemistry will wish to acquire." JACS "...this superb book (..) will be an essential purchase for many organic chemists." Nature

Reactive Intermediates in Organic Chemistry

Reactive Intermediates in Organic Chemistry Book
Author : Maya Shankar Singh
Publisher : John Wiley & Sons
Release : 2014-01-22
ISBN : 3527678271
Language : En, Es, Fr & De

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Book Description :

Most reactions in organic chemistry do not proceed in a single step but rather take several steps to yield the desired product. In the course of these multi-step reaction sequences, short-lived intermediates can be generated that quickly convert into other intermediates, reactants, products or side products. As these intermediates are highly reactive, they cannot usually be isolated, but their existence and structure can be proved by theoretical and experimental methods. Using the information obtained, researchers can better understand the underlying reaction mechanism of a certain organic transformation and thus develop novel strategies for efficient organic synthesis. The chapters are clearly structured and are arranged according to the type of intermediate, providing information on the formation, characterization, stereochemistry, stability, and reactivity of the intermediates. Additionally, representative examples and a problem section with different levels of difficulty are included for self-testing the newly acquired knowledge. By providing a deeper understanding of the underlying concepts, this is a musthave reference for PhD and Master Students in organic chemistry, as well as a valuable source of information for chemists in academia and industry working in the field. It is also ideal as primary or supplementary reading for courses on organic chemistry, physical organic chemistry or analytical chemistry.