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Alkene Polymerization Reactions With Transition Metal Catalysts

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Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts Book
Author : Yury Kissin
Publisher : Elsevier
Release : 2008-03-10
ISBN : 9780080557991
Language : En, Es, Fr & De

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Book Description :

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

Alkene Polymerization Reactions with Transition Metal Catalysts

Alkene Polymerization Reactions with Transition Metal Catalysts Book
Author : Y. V. Kissin
Publisher : Elsevier Science & Technology
Release : 2008
ISBN : 9781435628755
Language : En, Es, Fr & De

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Book Description :

During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes: 1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure. 2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands. 3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts. 4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms. The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymers The book contains over 2000 references, the most recent up to end of 2006.

Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts Book
Author : Ray Hoff
Publisher : John Wiley & Sons
Release : 2018-04-20
ISBN : 1119242150
Language : En, Es, Fr & De

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Book Description :

Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization

Transition Metal Catalyzed Polymerizations

Transition Metal Catalyzed Polymerizations Book
Author : Roderic P. Quirk
Publisher : Taylor & Francis
Release : 1983
ISBN : 9783718601431
Language : En, Es, Fr & De

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Book Description :

Download Transition Metal Catalyzed Polymerizations book written by Roderic P. Quirk, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Transition Metal Catalysis in Macromolecular Design

Transition Metal Catalysis in Macromolecular Design Book
Author : Lisa Saunders Boffa,Bruce M. Novak
Publisher : Amer Chemical Society
Release : 2000
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Metal-mediated polymerization is fast becoming an essential tool for the fine control of macromolecular architecture. Advanced Catalysis demonstrates how the field of transition metal-catalyzed polymer syntheses has moved beyond the simple use of single-site catalysts to new applications and "advanced" techniques of architectural control. This book defines and presents "next generation" techniques and trends for polymer architecture control for an immediate grasp on the future of this exciting field.

Direct Observation of Zirconocene catalyzed Alkene Polymerization Via NMR and the Role of an Aluminum Alkyl During Ploymerization

Direct Observation of Zirconocene catalyzed Alkene Polymerization Via NMR and the Role of an Aluminum Alkyl During Ploymerization Book
Author : Janice Hall Tomasik
Publisher : Unknown
Release : 2007
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Direct Observation of Zirconocene catalyzed Alkene Polymerization Via NMR and the Role of an Aluminum Alkyl During Ploymerization book written by Janice Hall Tomasik, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Comprehensive Organometallic Chemistry III

Comprehensive Organometallic Chemistry III Book
Author : Robert Crabtree
Publisher : Unknown
Release : 2007
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Comprehensive Organometallic Chemistry, (COMC-III), Third Edition, 13 Volume Set is aimed at the specialist and non-specialist alike. It covers the major developments in the field in a carefully presented way with extensive cross-references. COMC-III provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field over the next ten years. Applications of organometallic chemistry continue to expand and this has been reflected by the significant increase in the number of volumes devoted to applications in COMC-III. Organic chemists have edited the volumes on organometallic chemistry towards organic synthesis - this is now organized by reaction type so as to be readily accessible to the organic community. Like its predecessors, COMC (1982) and COMC-II (1995), this new work is the essential reference text for any chemist or technologist who needs to use or apply organometallic compounds. Also available online via ScienceDirect (2006) - featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. Presents a comprehensive overview of the major developments in the field since 1993 providing general and significant insights Highlights the expansion of applications in organometallic chemistry with a strong organic synthesis focus Provides a structured first point of entry to the key literature and background material for those planning research, teaching and writing about the area

Proceedings of the National Academy of Sciences of the United States of America

Proceedings of the National Academy of Sciences of the United States of America Book
Author : National Academy of Sciences (U.S.)
Publisher : Unknown
Release : 2006
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Proceedings of the National Academy of Sciences of the United States of America book written by National Academy of Sciences (U.S.), available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Transition Metal Catalyzed Polymerizations

Transition Metal Catalyzed Polymerizations Book
Author : Roderic P. Quirk,Raymond E. Hoff,University of Akron. Institute of Polymer Science,Edison Polymer Innovation Corporation
Publisher : CUP Archive
Release : 1988
ISBN : 9780521332897
Language : En, Es, Fr & De

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Book Description :

This volume contains the proceedings of the Second International Symposium on Transition Metal Catalyzed Polymerizations held in 1986. The papers provide a broad-based perspective covering recent scientific and technological advances in Ziegler-Natta and metathesis polymerization, including olefin, diene, and acetylene polymerization, and copolymerization. The emphasis on reaction kinetics of polymerizations in different reagent and catalyst environments makes this volume of interest to both academic and industrial researchers.

Homogeneous Catalysis by Metal Complexes Activation of alkenes and alkynes

Homogeneous Catalysis by Metal Complexes  Activation of alkenes and alkynes Book
Author : M. M. Taqui Khan,Arthur Earl Martell
Publisher : Unknown
Release : 1974
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Homogeneous Catalysis by Metal Complexes Activation of alkenes and alkynes book written by M. M. Taqui Khan,Arthur Earl Martell, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Early Main Group Metal Catalysis

Early Main Group Metal Catalysis Book
Author : Sjoerd Harder
Publisher : John Wiley & Sons
Release : 2020-02-03
ISBN : 3527344489
Language : En, Es, Fr & De

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Book Description :

Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.

Step growth Polymers for High performance Materials

Step growth Polymers for High performance Materials Book
Author : James L. Hedrick,American Chemical Society,Jeff W. Labadie,American Chemical Society. Division of Polymer Chemistry,American Chemical Society. Meeting,Calif.) American Chemical Society Meeting 1995 (Anaheim
Publisher : Amer Chemical Society
Release : 1996
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Presents the latest work in transition metal catalyzed polymerization, dendritic and hyperbranched systems, poly(aryl ether) synthesis, polyimides, and high-temperature polymers. Describes recent research on commercially important polymers based on step-growth polymerization. Includes well-referenced overview articles that review step-growth polymerization and indicate how individual research papers have impacted the field.

Kinetics and Thermodynamics of D0 yttrocene alkyl alkene Complexes I Reaction Rates of Alkenes with Cp 2YH THF II

Kinetics and Thermodynamics of D0 yttrocene alkyl alkene Complexes   I    Reaction Rates of Alkenes with Cp 2YH THF    II  Book
Author : Jennifer Fisher Klein
Publisher : Unknown
Release : 1999
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Kinetics and Thermodynamics of D0 yttrocene alkyl alkene Complexes I Reaction Rates of Alkenes with Cp 2YH THF II book written by Jennifer Fisher Klein, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Introduction to Polymer Chemistry Second Edition

Introduction to Polymer Chemistry  Second Edition Book
Author : Charles E. Carraher Jr.
Publisher : CRC Press
Release : 2010-01-12
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

With an emphasis on the environment and green chemistry and materials, this second edition offers detailed coverage of natural and synthetic giant molecules, inorganic and organic polymers, elastomers, adhesives, coatings, fibers, plastics, ceramics, and more.

Mechanistic Investigation of Zironocene Alkene Polymerization Catalysts

Mechanistic Investigation of Zironocene Alkene Polymerization Catalysts Book
Author : Jeanine M. Batterton
Publisher : Unknown
Release : 2007
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Mechanistic Investigation of Zironocene Alkene Polymerization Catalysts book written by Jeanine M. Batterton, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Transition Metals in Homogeneous Catalysis

Transition Metals in Homogeneous Catalysis Book
Author : Gerhard N. Schrauzer
Publisher : Unknown
Release : 1971
ISBN : 0987650XXX
Language : En, Es, Fr & De

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Book Description :

Download Transition Metals in Homogeneous Catalysis book written by Gerhard N. Schrauzer, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.