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Advances In Transition Metal Mediated Heterocyclic Synthesis

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Advances in Transition Metal Mediated Heterocyclic Synthesis

Advances in Transition Metal Mediated Heterocyclic Synthesis Book
Author : Daniel Sole,Israel Fernandez
Publisher : Academic Press
Release : 2018-05-19
ISBN : 9780128116517
Language : En, Es, Fr & De

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Book Description :

Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metals to produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (mainly aza- and oxa-heterocycles). As such, it covers recent applications on the synthesis of heterocycles, also describing the details of the novel transformations in a didactic manner to motivate readers in search of new catalytic processes. The editors have included state-of-the-art strategies, including transition-metal reactions involving unsaturated systems (reactions of allenes, new gold(I)-catalyzed reactions, and Prins reaction). Chapters highlight the versatility of organopalladium chemistry dealing with carbonylative transformations, C-H activation reactions, coupling processes, and the control of the ambiphilic character of organopalladium species. Finally, the book discusses new reactions leading to heterocycles based on C-H activation processes catalyzed by other metals (Rh, Ru, Co). Written by an outstanding team of authors who are leading experts in organometallic chemistry and organic synthesis, this book is a valuable resource not only for chemists mainly focused on synthesis, but also for those interested in reaction mechanisms involving transition metals. Helpfully organized by transformation type to stimulate the search for new synthetic processes Completely illustrated and written by global experts Includes thoughtfully selected strategies chosen by the editors to exemplify the state-of-the-art of the subject, including transition-metal reactions involving unsaturated systems, organopalladium chemistry, and metal-catalyzed C-H activation

Advances in Transition Metal Mediated Heterocyclic Synthesis

Advances in Transition Metal Mediated Heterocyclic Synthesis Book
Author : Daniel Sole,Israel Fernandez
Publisher : Academic Press
Release : 2018-05-17
ISBN : 0128116528
Language : En, Es, Fr & De

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Book Description :

Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metals to produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (mainly aza- and oxa-heterocycles). As such, it covers recent applications on the synthesis of heterocycles, also describing the details of the novel transformations in a didactic manner to motivate readers in search of new catalytic processes. The editors have included state-of-the-art strategies, including transition-metal reactions involving unsaturated systems (reactions of allenes, new gold(I)-catalyzed reactions, and Prins reaction). Chapters highlight the versatility of organopalladium chemistry dealing with carbonylative transformations, C-H activation reactions, coupling processes, and the control of the ambiphilic character of organopalladium species. Finally, the book discusses new reactions leading to heterocycles based on C-H activation processes catalyzed by other metals (Rh, Ru, Co). Written by an outstanding team of authors who are leading experts in organometallic chemistry and organic synthesis, this book is a valuable resource not only for chemists mainly focused on synthesis, but also for those interested in reaction mechanisms involving transition metals. Helpfully organized by transformation type to stimulate the search for new synthetic processes Completely illustrated and written by global experts Includes thoughtfully selected strategies chosen by the editors to exemplify the state-of-the-art of the subject, including transition-metal reactions involving unsaturated systems, organopalladium chemistry, and metal-catalyzed C-H activation

Transition Metal Mediated Aromatic Ring Construction

Transition Metal Mediated Aromatic Ring Construction Book
Author : Ken Tanaka
Publisher : John Wiley & Sons
Release : 2013-07-09
ISBN : 111862999X
Language : En, Es, Fr & De

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Book Description :

State-of-the-science methods, synthetic routes, andstrategies to construct aromatic rings The development of new reactions for the synthesis of aromaticcompounds is a highly active research area in organic synthesis,providing new functional organic materials, functional reagents,and biologically active compounds. Recently, significant advancesin transition-metal-mediated reactions have enabled the efficientand practical construction of new aromatic rings with usefulproperties and applications. This book draws together and reviewsall the latest discoveries and methods in transition-metal-mediatedreactions, offering readers promising new routes to design andconstruct complex aromatic compounds. Integrating metal catalysis with aromatic compound synthesis,Transition-Metal-Mediated Aromatic Ring Construction offersa practical guide to the methods, synthetic routes, and strategiesfor constructing aromatic compounds. The book's five partsexamine: [2+2+2], [2+2+1], and related cycloaddition reactions [4+2], [3+2], and related cycloaddition reactions Electrocyclization reactions Coupling and addition reactions Other important transformations, including methathesisreactions and skeletal rearrangement reactions Edited by Ken Tanaka, an internationally recognized expert inthe field of transition-metal catalysis, the book features authorswho are leading pioneers and researchers in synthetic reactions.Their contributions reflect a thorough review and analysis of theliterature as well as their own firsthand laboratory experiencedeveloping new aromatic compounds. All chapters end with a summary and outlook, setting forth newavenues of research and forecasting new discoveries. There are alsoreferences at the end of each chapter, guiding readers to importantoriginal research reports and reviews. In summary, Transition-Metal-Mediated Aromatic RingConstruction offers synthetic chemists a promising new avenuefor the development of important new aromatic compounds with abroad range of applications.

Heterocycles

Heterocycles Book
Author : Teresa M. V. D. Pinho e Melo,Marta Pineiro
Publisher : John Wiley & Sons
Release : 2022-06-20
ISBN : 3527348867
Language : En, Es, Fr & De

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Book Description :

Heterocycles A must-read handbook on heterocycle chemistry with a focus on sustainability Heterocycles feature prominently in our daily life—they are essential for pharmaceuticals, agrochemicals, and fine chemicals. More, numerous natural, bioactive products contain heterocyclic compounds. As a result, heterocyclic chemistry continues to be one of the most important areas of study in organic chemistry. Heterocycles provides an important reference on a wide range of topics relating to heterocyclic chemistry, with a heavy emphasis on sustainable methods and greener syntheses. The book describes state-of-the-art synthetic methods, such as photochemical reactions, dearomatization reactions, organocatalysis, transition metal catalysis, and biocatalysis. It also covers: Sustainable methods, like flow chemistry, mechanochemistry, and multicomponent synthesis Strategies for the synthesis of heterocyclic macrocycles and medium-sized rings Characterization of heterocyclic compounds Heterocycles is a useful reference for organic chemists, natural products chemists, catalytic chemists, and medicinal chemists in academia and industry.

Advances in Heterocyclic Chemistry

Advances in Heterocyclic Chemistry Book
Author : Anonim
Publisher : Academic Press
Release : 2020-04-24
ISBN : 0128211725
Language : En, Es, Fr & De

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Book Description :

Advances in Heterocyclic Chemistry is the definitive series in the field - one of great importance to organic chemists, polymer chemists, and many biological scientists. Because biology and organic chemistry increasingly intersect, the associated nomenclature also is being used more frequently in explanations. Written by established authorities in the field from around the world, this comprehensive review combines descriptive synthetic chemistry and mechanistic insight to yield an understanding of how chemistry drives the preparation and useful properties of heterocyclic compounds. Considered the definitive serial in the field of heterocyclic chemistry Serves as the go-to reference for organic chemists, polymer chemists and many biological scientists Provides the latest comprehensive reviews written by established authorities in the field Combines descriptive synthetic chemistry and mechanistic insight to enhance understanding of how chemistry drives the preparation and useful properties of heterocyclic compounds

N Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis

N Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis Book
Author : Catherine S.J. Cazin
Publisher : Springer Science & Business Media
Release : 2010-10-04
ISBN : 9789048128662
Language : En, Es, Fr & De

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Book Description :

N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts. An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly apropos. The book begins with an introductory overview of NHCs which could have been subtitled all you need to know about NHCs. The main body of the book is dedicated to applications of NHCs in catalysis. In addition to the success stories of NHCs in metathesis, NHCs in cross coupling and more recently NHCs in organocatalysis, all other less publicized areas are also covered. As the success of NHCs is generally attributed to their potential to stabilize metal centres, the inclusion of a chapter on the decomposition of NHC catalysts is pertinent. The book closes with a chapter describing the applications of NHCs in industrial processes, which is the first coverage of its kind, and brings a unique industrial context to this book. Included in this book: Historical aspects of NHCs Synthetic pathways to NHC precursors, free NHCs and complexes Methods of characterisation of NHCs and related complexes Electronic properties of NHCs Steric properties of NHCs and models for their description NHCs for metathesis and cross-coupling reactions NHCs as organocatalysts NHC Transition-Metal mediated oxidations, additions to multiple bonds, polymerisation and oligomerisation, cyclisations, direct arylations, reactions involving CO, C-F and C-H bond activation, ... Decomposition of NHC-containing catalysts Industrial applications involving NHC-containing catalysts N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis provides a fresh view of NHCs since most contributors are young emerging researchers in the field of homogeneous catalysis using NHCs. This group of contributors is complemented by highly established academic researchers and an industrialist. This book is comprehensive, from the basic features of NHCs to the latest advances, hence it is suitable for both the novice and the expert.

Pincer Compounds

Pincer Compounds Book
Author : David Morales-Morales
Publisher : Elsevier
Release : 2018-04-11
ISBN : 0128129328
Language : En, Es, Fr & De

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Book Description :

Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

Carbon Monoxide in Organic Synthesis

Carbon Monoxide in Organic Synthesis Book
Author : Bartolo Gabriele
Publisher : John Wiley & Sons
Release : 2022-01-10
ISBN : 352734795X
Language : En, Es, Fr & De

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Book Description :

Carbon Monoxide in Organic Synthesis A thoroughly up-to-date overview of carbonylation reactions in the presence of carbon monoxide In Carbon Monoxide in Organic Synthesis: Carbonylation Chemistry, expert researcher and chemist Bartolo Gabriele delivers a robust summary of the most central advances in the field of carbonylation reactions in the presence of carbon monoxide. Beginning with a brief introduction on the importance of carbon monoxide as a building block in modern organic synthesis, the author goes on to describe metal-catalyzed carbonylations utilizing iron, cobalt, nickel, copper, and manganese. Descriptions of palladium, ruthenium, and rhodium-catalyzed reactions follow, as do discussions of metal-free carbonylation processes. The book is organized by metal to make the book useful as a guide for researchers from both academia and industry whose work touches on the direct synthesis of carbonyl compounds, carboxylic acid derivatives, and heterocycles. It aims to stimulate further discoveries in this rapidly developing field. Readers will also enjoy: A thorough introduction to carbonylations promoted by first row transition metal catalysts, including cobalt-catalyzed and nickel-catalyzed carbonylations An exploration of carbonylations promoted by second row transition metal catalysts, including ruthenium-, rhodium-, palladium(0)-, and palladium (II)-catalyzed carbonylations Practical discussions of miscellaneous carbonylation reactions, including carbonylations promoted by third row transition metal catalysts and metal-free carbonylation processes Perfect for catalytic and organic chemists, Carbon Monoxide in Organic Synthesis: Carbonylation Chemistry is also an indispensable resource for chemists working with organometallics and industrial chemists seeking a summary of important processes used to synthesize value-added products.

Advances in Organometallic Chemistry

Advances in Organometallic Chemistry Book
Author : Pedro J. Perez
Publisher : Academic Press
Release : 2020-03-03
ISBN : 0128206918
Language : En, Es, Fr & De

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Book Description :

Advances in Organometallic Chemistry, Volume 73, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. Specific chapters in this new release include Metal carbonyl promoted multicomponent coupling of alkyne for synthesis of heterocyclic compounds, Group 10 metal(0) complexes stabilized by phosphorus and carbon donor ligands, Synthesis of Nitrogen-containing Molecules via Transition Metal-Catalyzed Reactions on Isoxazoles, Anthraniils and Benzoisoxazoles, and more. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

Transition Metal Catalyzed Heterocycle Synthesis via C H Activation

Transition Metal Catalyzed Heterocycle Synthesis via C H Activation Book
Author : Xiao-Feng Wu
Publisher : John Wiley & Sons
Release : 2016-03-07
ISBN : 3527338888
Language : En, Es, Fr & De

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Book Description :

Reflecting the tremendous growth of this hot topic in recent years, this book covers C-H activation with a focus on heterocycle synthesis. As such, the text provides general mechanistic aspects and gives a comprehensive overview of catalytic reactions in the presence of palladium, rhodium, ruthenium, copper, iron, cobalt, and iridium. The chapters are organized according to the transition metal used and sub-divided by type of heterocycle formed to enable quick access to the synthetic route needed. Chapters on carbonylative synthesis of heterocycles and the application of C-H activation methodology to the synthesis of natural products are also included. Written by an outstanding team of authors, this is a valuable reference for researchers in academia and industry working in the field of organic synthesis, catalysis, natural product synthesis, pharmaceutical chemistry, and crop protection.

Advances in Cross Coupling Reactions

Advances in Cross Coupling Reactions Book
Author : José Pérez Sestelo,Luis A. Sarandeses
Publisher : MDPI
Release : 2020-12-03
ISBN : 3039435671
Language : En, Es, Fr & De

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Book Description :

In this Special Issue, recent advances in cross-coupling reactions are presented in the form of original research articles, reviews, and short communications. These contributions cover different topics in this area, including novel coupling reactions, reaction conditions, synthetic alternatives, metal ligands, and applications for new pharmaceutical compounds and organic materials. In particular, the reviews deal with methodologies such as the synthesis of diarylketones through palladium catalysis and the most relevant examples of Suzuki–Miyaura and Buchwald–Hartwig coupling reactions in the synthesis of bioactive compounds. The synthetic utility of cross-coupling reactions for the synthesis of medium-size rings and the utility of Stille and Suzuki coupling reactions for the synthesis of new molecular machines based on sterically hindered anthracenyl trypticenyl units are also summarized. The original research articles present the synthesis of 2-alkynylpyrrols by inverse Sonogashira coupling and the synthesis of indoles under oxidative dearomative cross-dehydrogenative conditions. The efficient combination of iridium-catalyzed C–H borylation of aryl halides with the Sonogashira coupling and a sequential iridium-catalyzed borylation of NH-free pyrroles followed by a Suzuki–Miyaura reaction are included. The synthesis of aryl propionic acids, a common structural motif in medicinal chemistry, and the synthesis of new organic dyes are also covered.

Synthetic Inorganic Chemistry

Synthetic Inorganic Chemistry Book
Author : Ewan J. M. Hamilton
Publisher : Elsevier
Release : 2021-04-17
ISBN : 0128189339
Language : En, Es, Fr & De

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Book Description :

Synthetic Inorganic Chemistry: New Perspectives presents summaries of the work of some of the most creative researchers in the field. The book highlights the most novel approaches and burgeoning applications of synthetic inorganic chemistry in development. Topics include non-precious metals in catalysis, smart inorganic polymers, new inorganic therapeutics, new photocatalysts for hydrogen production, and more. As the first volume in the Developments in Inorganic Chemistry series, this work is a valuable resource for students and researchers working in inorganic chemistry and material science. Illustrates the scope and vitality of modern synthetic inorganic chemistry Shows the centrality of inorganic chemistry, addressing a variety of global challenges Serves to define the current, important and expanding roles of synthetic inorganic chemistry in interdisciplinary areas such as materials science, synthetic organic chemistry, homogeneous and heterogeneous catalysis

Comprehensive Organic Synthesis

Comprehensive Organic Synthesis Book
Author : Anonim
Publisher : Newnes
Release : 2014-02-14
ISBN : 008097743X
Language : En, Es, Fr & De

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Book Description :

The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively

Advances in Heterocyclic Chemistry

Advances in Heterocyclic Chemistry Book
Author : Alan R. Katritzky
Publisher : Academic Press
Release : 2011-02-17
ISBN : 0123854652
Language : En, Es, Fr & De

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Book Description :

Established in 1960, Advances in Heterocyclic Chemistry is the definitive serial in the area—one of great importance to organic chemists, polymer chemists, and many biological scientists. Written by established authorities in the field, the comprehensive reviews combine descriptive chemistry and mechanistic insight and yield an understanding of how the chemistry drives the properties. Provides up-to-date material on a fast-growing and highly topical subject area Contains the latest research covering a wide variety of heterocyclic topics Written by leading authorities and designed as a handbook for students and industry and academic researchers

Advances in Nitrogen Heterocycles

Advances in Nitrogen Heterocycles Book
Author : C.J. Moody
Publisher : Elsevier
Release : 1999-01-19
ISBN : 9780080560762
Language : En, Es, Fr & De

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Book Description :

This volume contains a range of topics such as the activation and manipulation of pyrroles, the synthesis of annelated pyrroles using acylation reactions and the synthesis of kainoids, a family of highly biologically active nitrogen heterocycles.

Three Membered Rings

Three Membered Rings Book
Author : A. Davison,M.J.S. Dewar
Publisher : Springer
Release : 1973-08-24
ISBN : 9783540062653
Language : En, Es, Fr & De

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Book Description :

Download Three Membered Rings book written by A. Davison,M.J.S. Dewar, available in PDF, EPUB, and Kindle, or read full book online anywhere and anytime. Compatible with any devices.

Nitrogenation Strategy for the Synthesis of N containing Compounds

Nitrogenation Strategy for the Synthesis of N containing Compounds Book
Author : Ning Jiao
Publisher : Springer
Release : 2016-11-15
ISBN : 9811028133
Language : En, Es, Fr & De

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Book Description :

This book focuses on direct nitrogenation strategies to incorporate one or more N-atoms into simple substrates especially hydrocarbons via C–H and/or C–C bond cleavage, which is a green and sustainable way to synthesize nitrogen-containing compounds. The book consists of seven chapters demonstrating interesting advances in the preparation of amines, amides, nitriles, carbamides, azides, and N-heterocyclic compounds and illustrating the mechanisms of these novel transformations. It offers an accessible introduction to nitrogenation reactions for chemists involved in N-compound synthesis and those interested in discovering new reagents and reactions. Ning Jiao is a Professor of Chemistry at Peking University, China.

Advances in Microwave Chemistry

Advances in Microwave Chemistry Book
Author : Bimal K Banik,Debasish Bandyopadhyay
Publisher : CRC Press
Release : 2018-12-07
ISBN : 1351240471
Language : En, Es, Fr & De

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Book Description :

Advances in Microwave Chemistry discusses the novel bond formation methodologies, synergistic effects of microwaves with other entities, sample preparation including digestion, combustion, and extraction techniques, as well as selectivity in chemical processes. Recent updates are provided on microwave-assisted syntheses of pharmacologically significant aza-, oxo- and other heterocycles, including lactams, nucleosides, bile acids and sterols, the preparation of nanomaterials, composites, and absorber layer materials for thin film. This book also incorporates comparative discussions involving microwave irradiation with conventional methods in different aspects of organic, inorganic, medicinal, and green chemistry. Key Features: Provides a comparative discussion on microwave irradiation with conventional methods in different aspects of organic, inorganic, medicinal, and green chemistry Presents recent applications of microwave radiation in biocatalysis Offers a complete package correlating various aspects of microwaves in organic syntheses, the biological impact of products formed in reactions, pharmacological features, and environmental sustainability of the procedures Explains microwave-induced reactions on structurally complex bile acids and sterols Stands as a valuable and unique addition to the well-established book series, New Directions in Organic and Biological Chemistry

Catalyst Components for Coupling Reactions

Catalyst Components for Coupling Reactions Book
Author : Gary A. Molander
Publisher : John Wiley & Sons
Release : 2013-05-30
ISBN : 1118643437
Language : En, Es, Fr & De

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Book Description :

The long awaited Handbook for all synthetic chemists working on coupling reactions, compiling all major catalyst components in use in the area. Consists of a compilation of articles taken from the EROS database, with the inclusion of about 20 newly commissioned catalysts/pre-catalysts/ligands that have made an impact in this area of synthetic organic chemistry. Includes catalyst systems used in Heck, Kumada-Tamao-Corriu, Suzuki-Miyaura, Hiyama-Hatanaka, Negishi, Migita-Kosugi-Stille, Buchwald-Hartwig, and Tsuji-Trost coupling reactions.

Isocoumarin Thiaisocoumarin and Phosphaisocoumarin

Isocoumarin  Thiaisocoumarin and Phosphaisocoumarin Book
Author : Sarbani Pal,Manojit Pal
Publisher : Elsevier
Release : 2018-10-16
ISBN : 0128154462
Language : En, Es, Fr & De

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Book Description :

Isocoumarin, Thiaisocoumarin and Phosphaisocoumarin: Natural Occurrences, Synthetic Approaches and Pharmaceutical Applications gives an overview of the various aspects of this class of heterocycle, with a major focus on synthesis and biological activity. Aromatic δ lactones or isocoumarins with thiaisocoumarins, phosphaisocoumarins and a-pyranone fused with a heteroaryl ring constitute an important class of heterocyclic compounds. This book provides the methods applied for the synthesis of thiaisocoumarins, phosphaisocoumarins, and a-pyranone fused with a heteroaryl ring. It is useful to medicinal and natural product chemists who want to synthesize target molecules and develop cutting-edge technologies to provide better solutions to researchers. Features an overview of isocoumarins and their role in pharmaceutical research Presents a template for the design, discovery and development of new and potential drugs in various therapeutic areas Includes comprehensive coverage of the synthesis of isocoumarins, from traditional methods, to transition metal catalyzed methods Looks at future applications for these important compounds in the areas of drug discovery and pharmaceutical research