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Advances In Transition Metal Mediated Heterocyclic Synthesis

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Advances in Transition Metal Mediated Heterocyclic Synthesis

Advances in Transition Metal Mediated Heterocyclic Synthesis Book
Author : Daniel Sole,Israel Fernandez
Publisher : Academic Press
Release : 2018-05-17
ISBN : 0128116528
Language : En, Es, Fr & De

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Book Description :

Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metals to produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (mainly aza- and oxa-heterocycles). As such, it covers recent applications on the synthesis of heterocycles, also describing the details of the novel transformations in a didactic manner to motivate readers in search of new catalytic processes. The editors have included state-of-the-art strategies, including transition-metal reactions involving unsaturated systems (reactions of allenes, new gold(I)-catalyzed reactions, and Prins reaction). Chapters highlight the versatility of organopalladium chemistry dealing with carbonylative transformations, C-H activation reactions, coupling processes, and the control of the ambiphilic character of organopalladium species. Finally, the book discusses new reactions leading to heterocycles based on C-H activation processes catalyzed by other metals (Rh, Ru, Co). Written by an outstanding team of authors who are leading experts in organometallic chemistry and organic synthesis, this book is a valuable resource not only for chemists mainly focused on synthesis, but also for those interested in reaction mechanisms involving transition metals. Helpfully organized by transformation type to stimulate the search for new synthetic processes Completely illustrated and written by global experts Includes thoughtfully selected strategies chosen by the editors to exemplify the state-of-the-art of the subject, including transition-metal reactions involving unsaturated systems, organopalladium chemistry, and metal-catalyzed C-H activation

Advances in Heterocyclic Chemistry

Advances in Heterocyclic Chemistry Book
Author : N.A
Publisher : Academic Press
Release : 2020-04-24
ISBN : 0128211725
Language : En, Es, Fr & De

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Book Description :

Advances in Heterocyclic Chemistry is the definitive series in the field - one of great importance to organic chemists, polymer chemists, and many biological scientists. Because biology and organic chemistry increasingly intersect, the associated nomenclature also is being used more frequently in explanations. Written by established authorities in the field from around the world, this comprehensive review combines descriptive synthetic chemistry and mechanistic insight to yield an understanding of how chemistry drives the preparation and useful properties of heterocyclic compounds. Considered the definitive serial in the field of heterocyclic chemistry Serves as the go-to reference for organic chemists, polymer chemists and many biological scientists Provides the latest comprehensive reviews written by established authorities in the field Combines descriptive synthetic chemistry and mechanistic insight to enhance understanding of how chemistry drives the preparation and useful properties of heterocyclic compounds

Transition Metal Mediated Aromatic Ring Construction

Transition Metal Mediated Aromatic Ring Construction Book
Author : Ken Tanaka
Publisher : John Wiley & Sons
Release : 2013-07-09
ISBN : 111862999X
Language : En, Es, Fr & De

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Book Description :

State-of-the-science methods, synthetic routes, andstrategies to construct aromatic rings The development of new reactions for the synthesis of aromaticcompounds is a highly active research area in organic synthesis,providing new functional organic materials, functional reagents,and biologically active compounds. Recently, significant advancesin transition-metal-mediated reactions have enabled the efficientand practical construction of new aromatic rings with usefulproperties and applications. This book draws together and reviewsall the latest discoveries and methods in transition-metal-mediatedreactions, offering readers promising new routes to design andconstruct complex aromatic compounds. Integrating metal catalysis with aromatic compound synthesis,Transition-Metal-Mediated Aromatic Ring Construction offersa practical guide to the methods, synthetic routes, and strategiesfor constructing aromatic compounds. The book's five partsexamine: [2+2+2], [2+2+1], and related cycloaddition reactions [4+2], [3+2], and related cycloaddition reactions Electrocyclization reactions Coupling and addition reactions Other important transformations, including methathesisreactions and skeletal rearrangement reactions Edited by Ken Tanaka, an internationally recognized expert inthe field of transition-metal catalysis, the book features authorswho are leading pioneers and researchers in synthetic reactions.Their contributions reflect a thorough review and analysis of theliterature as well as their own firsthand laboratory experiencedeveloping new aromatic compounds. All chapters end with a summary and outlook, setting forth newavenues of research and forecasting new discoveries. There are alsoreferences at the end of each chapter, guiding readers to importantoriginal research reports and reviews. In summary, Transition-Metal-Mediated Aromatic RingConstruction offers synthetic chemists a promising new avenuefor the development of important new aromatic compounds with abroad range of applications.

Advances in Organometallic Chemistry

Advances in Organometallic Chemistry Book
Author : Pedro J. Perez
Publisher : Academic Press
Release : 2020-03-03
ISBN : 0128206918
Language : En, Es, Fr & De

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Book Description :

Advances in Organometallic Chemistry, Volume 73, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. Specific chapters in this new release include Metal carbonyl promoted multicomponent coupling of alkyne for synthesis of heterocyclic compounds, Group 10 metal(0) complexes stabilized by phosphorus and carbon donor ligands, Synthesis of Nitrogen-containing Molecules via Transition Metal-Catalyzed Reactions on Isoxazoles, Anthraniils and Benzoisoxazoles, and more. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

N Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis

N Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis Book
Author : Catherine S.J. Cazin
Publisher : Springer Science & Business Media
Release : 2010-10-04
ISBN : 9789048128662
Language : En, Es, Fr & De

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Book Description :

N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts. An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly apropos. The book begins with an introductory overview of NHCs which could have been subtitled all you need to know about NHCs. The main body of the book is dedicated to applications of NHCs in catalysis. In addition to the success stories of NHCs in metathesis, NHCs in cross coupling and more recently NHCs in organocatalysis, all other less publicized areas are also covered. As the success of NHCs is generally attributed to their potential to stabilize metal centres, the inclusion of a chapter on the decomposition of NHC catalysts is pertinent. The book closes with a chapter describing the applications of NHCs in industrial processes, which is the first coverage of its kind, and brings a unique industrial context to this book. Included in this book: Historical aspects of NHCs Synthetic pathways to NHC precursors, free NHCs and complexes Methods of characterisation of NHCs and related complexes Electronic properties of NHCs Steric properties of NHCs and models for their description NHCs for metathesis and cross-coupling reactions NHCs as organocatalysts NHC Transition-Metal mediated oxidations, additions to multiple bonds, polymerisation and oligomerisation, cyclisations, direct arylations, reactions involving CO, C-F and C-H bond activation, ... Decomposition of NHC-containing catalysts Industrial applications involving NHC-containing catalysts N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis provides a fresh view of NHCs since most contributors are young emerging researchers in the field of homogeneous catalysis using NHCs. This group of contributors is complemented by highly established academic researchers and an industrialist. This book is comprehensive, from the basic features of NHCs to the latest advances, hence it is suitable for both the novice and the expert.

General and Synthetic Methods

General and Synthetic Methods Book
Author : G. Pattenden
Publisher : Royal Society of Chemistry
Release : 1994-01
ISBN : 0851868347
Language : En, Es, Fr & De

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Book Description :

Reflecting the growing volume of published work in this field, researchers will find this book an invaluable source of information on current methods and applications.

Progress in Heterocyclic Chemistry

Progress in Heterocyclic Chemistry Book
Author : Gordon W. Gribble,John Arthur Joule
Publisher : Elsevier
Release : 2011
ISBN : 0080968058
Language : En, Es, Fr & De

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Book Description :

Progress in Heterocyclic Chemistry (PHC) is an annual review series commissioned by the International Society of Heterocyclic Chemistry (ISHC). Volumes in the series contain both highlights of the previous year's literature on heterocyclic chemistry and articles on emerging topics of particular interest to heterocyclic chemists. The chapters in Volume 23 constitute a systematic survey of the important original material reported in the literature of heterocyclic chemistry in 2010. As with previous volumes in the series, Volume 23 apprises academic/industrial chemists and advanced students of developments in heterocyclic chemistry in a convenient format. Covers the heterocyclic literature published in 2010 Includes specialized reviews Features contributions from leading researchers in their fields

Science of Synthesis Metal Catalyzed Cyclization Reactions Vol 2

Science of Synthesis  Metal Catalyzed Cyclization Reactions Vol  2 Book
Author : Shengming Ma,Shuanhu Gao
Publisher : Georg Thieme Verlag
Release : 2016-12-14
ISBN : 3131998512
Language : En, Es, Fr & De

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Book Description :

Significant advances in metal-catalyzed reactions, especially cyclizations, have dramatically improved the efficiency of organic synthesis over the last three decades. To date these transformations are widely used in the area of synthesis of both natural products and therapeutic agents. "Science of Synthesis: Metal-Catalyzed Cyclization Reactions" presents the most commonly used and significant metal-catalyzed reactions for modern organic synthesis. The basic principles, the current state of the art, scope, limitations, and mechanism of these reactions are also discussed. Typical examples of target synthesis are provided to help inspire further applications. Volume 2 covers epoxidations, aziridinations, cyclopropanations, and Pauson-Khand reactions, as well as a wide range of cycloaddition processes, radical cyclizations, and ring-closing metathesis.

Catalyst Components for Coupling Reactions

Catalyst Components for Coupling Reactions Book
Author : Gary A. Molander
Publisher : John Wiley & Sons Incorporated
Release : 1999
ISBN :
Language : En, Es, Fr & De

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Book Description :

Among the myriad new methodological strategies developed over the past 50 years, none have impacted the construction of organic molecules as much as those transformations categorized as cross-coupling reactions. Most of these reactions rapidly assumed their current status as "name reactions", including the Suzuki-Miyaura, Negishi, Kumada-Tamao/Corriu, Stille/Migita-Kosugi, Tamao-Kumada/Hiyama-Hatanaka and Sonogashira cross-couplings, as well as the Mizoroki-Heck, Tsuji-Trost and Buchwald-Hartwig reactions. All cross-couplings are inextricably linked by one common theme: they employ catalyst systems comprised of various metal complexes and ligands that promote the reactions through catalytic cycles in which many of the individual steps are analogous. For this reason this Handbook focuses on the individual components of catalyst systems. Many of these may be organized into "super-families" of compounds that are constituted from similar molecular platforms. An attempt has been made to group these under a single parent compound. All the information compiled in this volume is also available in electronic format on Wiley InterScience. The electronic Encyclopedia of Reagents for Organic Synthesis (e-EROS) includes all the reagents described in this volume plus many more reagents of other types and for other uses. e-EROS allows for both text and structure searches and has many new and updated entries added every year. For more information visit: http://www.mrw.interscience.wiley.com/eros/

Reagents for Radical and Radical Ion Chemistry

Reagents for Radical and Radical Ion Chemistry Book
Author : David Crich
Publisher : Wiley
Release : 2009-01-07
ISBN : 9780470065365
Language : En, Es, Fr & De

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Book Description :

Radicals and radical ions are important intermediates with wide use in organic synthesis. The first book to concentrate on reagents for the creation and use of radicals and radical ions, this new volume in the Handbooks of Reagents for Organic Synthesis series compiles articles taken from the e-eros database, on reagents for use in radical and radical chemistry, to help the chemist in the lab choose the right reagents. Reflecting the enormous growth of radical chemistry over the past ten years, this is an essential guide for all synthetic chemists.

Metathesis Chemistry

Metathesis Chemistry Book
Author : Yavuz Imamoglu,Valerian Dragutan
Publisher : Springer Science & Business Media
Release : 2007-07-24
ISBN : 1402060912
Language : En, Es, Fr & De

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Book Description :

Discover why olefin metathesis has asserted itself as a powerful strategy for obtaining fine chemicals, biologically active compounds, architecturally complex assemblies, new materials, and functionalized polymers. This volume compiles all the latest trends in olefin metathesis. In particular, you’ll learn how olefin metathesis has growing potential for the development of sustainable technologies with many possible industrial applications.

Current Trends in Organic Synthesis

Current Trends in Organic Synthesis Book
Author : Carlo Scolastico,Francesco Nicotra
Publisher : Springer Science & Business Media
Release : 2012-12-06
ISBN : 1461548012
Language : En, Es, Fr & De

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Book Description :

The last two decades have seen a rapid growth in the synthetic processing of both simple and complex molecules, aimed at meeting the needs of society in all aspects of life. Many efforts have been devoted to the development of new biologically active compounds, new materials with innovative properties such as bio-compatibility, new catalysts that allow highly selective transformations, and technologies that facilitate the synthetic pro cesses. This book is a compendium of recent progress in all these aspects of synthetic chemistry. It collects the lectures of the XII International Conference on Organic Synthesis, held in Venice from June 28 to July 2, 1998, in which the present state of art of this discipline has been reported. The topics covered include: combinatorial chemistry, new synthetic methods, stereo selective synthesis, metal-mediated synthesis, and target oriented synthesis. The book collects the contributions, in the mentioned topics, of 43 scientists from 19 different countries. The contributions presented in the Conference as plenary lectures are reported in the first section of the book. Particular attention has been dedicated to combinatorial chemistry, a new and promising methodology for the synthesis of libraries of pharmaco logically interesting compounds in order to allow the automatic pharmacological screening of thousands of compounds. The Conference has dedicated to combinatorial chemistry a mini-symposium in which scientists from academy and companies have described the current trends of this very new technology.

Cross coupling Reactions

Cross coupling Reactions Book
Author : Joffrey Vrijdag
Publisher :
Release : 2020
ISBN : 9781536176957
Language : En, Es, Fr & De

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Book Description :

"Cross-Coupling Reactions: An Overview opens with an overview of the fundamentals and applications of the young and fast developing area of transition metal catalyzed/mediated oxidative (dehydrogenative) C-H/C-H coupling reactions between two (hetero)arenes. Continuing, the authors highlight the recent advances regarding the ligand supported transition metal-catalyzed domino (cascade) or one-pot syntheses of various heterocycles involving cross-coupling reactions. The recent advances in Cu catalyzed tandem reactions for heterocycle synthesis are also addressed. Cu metal chemistry has garnered attention as a potential alternative to precious transition metals, being cheaper, more sustainable and more easily available. A comprehensive account of research on green chemical routes is provided, involving various palladium metal-based catalysts utilized in facilitating cross-coupling reaction in aqueous media. Reported decarboxylative cross-coupling reactions are discussed along with suitable examples, focusing on their mechanism of action"--

Organometallic Chemistry

Organometallic Chemistry Book
Author : Royal Society of Chemistry,Edward W. Abel
Publisher : Royal Society of Chemistry
Release : 1994-01-01
ISBN : 0851867111
Language : En, Es, Fr & De

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Book Description :

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry.

Advances in Metal Carbene Chemistry

Advances in Metal Carbene Chemistry Book
Author : U. Schubert
Publisher : Springer Science & Business Media
Release : 1989-04-30
ISBN : 9780792301561
Language : En, Es, Fr & De

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Book Description :

There are only few topics in organometallic chemistry, which have stimulated research activities in as many areas, as transition-metal carbene (alkylidene) complexes. About 25 years after the first planned synthesis of a carbene complex in E.O. Fischer's laboratory in Munich the NATO Advanced Research Workshop on Transition-Metal Carbene Complexes was the first meeting which,brought together scientists from different disciplines to discuss inorganic, organic, theoretical structural catalysis-related aspects of metal carbene chemistry. The 70th birthday of Professor E.O. Fischer was a good occasion for this enterprise. The organizers of the meeting (K.D. Dotz, Marburg; F.R. KreiBl, Munchen; U. Schubert, Wurzburg) were encouraged by the fact that most of the leading scientists in this area were able to participate in the workshop. The very high standard of the contributions is reflected in this book, which contains papers from the majority of the participants. The Proceedings show the state of the art in metal carbene chemistry and will hopefully be a landmark in the development of this area of chemistry. Generous financial support for the workshop and for the preparation of this book was provided by the Scientific Affairs Division of NATO and some companies. The organizers also acknowledge the efforts of the staff of the Bildungs zentrum der Hans-Seidel-Stiftung in Wild bad Kreuth for creating a pleasant and stimulating atmosphere during the conference.

Science of Synthesis N Heterocyclic Carbenes in Catalytic Organic Synthesis Vol 2

Science of Synthesis  N Heterocyclic Carbenes in Catalytic Organic Synthesis Vol  2 Book
Author : Steven Nolan,Catherine Cazin
Publisher : Georg Thieme Verlag
Release : 2017-06-14
ISBN : 3132414034
Language : En, Es, Fr & De

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Book Description :

The field of N-heterocyclic carbenes, whether in transition-metal catalysis or organocatalysis, is rapidly evolving towards applications, but is also still very active on the catalyst development front. Significant advances have been made over the past two decades and the development of these reactions has dramatically improved the efficiency of organic synthesis. N-Heterocyclic carbene based catalysts are now widely applied in the area of synthesis of both natural products and therapeutic agents. “Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis” presents the most commonly used and significant metal- or non-metal-catalyzed reactions for modern organic synthesis. The basic principles and current state-of-the-art of the methods are covered. Scope, limitations, and mechanism of these reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications. Volume 2 covers the use of NHCs in the various types of metathesis reaction, polymerization, cyclization reactions, oxidation reactions, and carbonylation/carboxylation reactions.

Cobalt Catalysis in Organic Synthesis

Cobalt Catalysis in Organic Synthesis Book
Author : Marko Hapke,Gerhard Hilt
Publisher : John Wiley & Sons
Release : 2020-02-25
ISBN : 3527344500
Language : En, Es, Fr & De

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Book Description :

Provides a much-needed account of the formidable "cobalt rush" in organic synthesis and catalysis Over the past few decades, cobalt has turned into one of the most promising metals for use in catalytic reactions, with important applications in the efficient and selective synthesis of natural products, pharmaceuticals, and new materials. Cobalt Catalysis in Organic Synthesis: Methods and Reactions provides a unique overview of cobalt-catalysed and -mediated reactions applied in modern organic synthesis. It covers a broad range of homogeneous reactions, like cobalt-catalysed hydrogenation, hydrofunctionalization, cycloaddition reactions, C-H functionalization, as well as radical and biomimetic reactions. First comprehensive book on this rapidly evolving research area Covers a broad range of homogeneous reactions, such as C-H activation, cross-coupling, synthesis of heterocyclic compounds (Pauson-Khand), and more Chapters on low-valent cobalt complexes as catalysts in coupling reactions, and enantioselective cobalt-catalyzed transformations are also included Can be used as a supplementary reader in courses of advanced organic synthesis and organometallic chemistry Cobalt Catalysis in Organic Synthesis is an ideal book for graduates and researchers in academia and industry working in the field of synthetic organic chemistry, catalysis, organometallic chemistry, and natural product synthesis.