Advanced Functional Solid Catalysts For Biomass Valorization

Book Description :

Advanced Functional Solid Catalysts for Biomass Valorization presents the basic concepts in catalysis (homogeneous, heterogeneous, and enzymatic) and the properties of various kinds of heterogeneous solid catalysts, including their structure, porosity, particle size, BET surface area, acid-base, and redox properties. Useful information about biorefineries, types of biomass feedstocks, their structures and properties as well as about several potential catalytic routes for biomass upgrading to useful fuels and chemicals is provided in this book. Importantly, this book covers the most recent developments toward functionalization of various solid catalysts, optimization of catalysts’ properties, developing cascade catalytic strategies, exploring reaction kinetics/mechanisms, and evaluating catalysts’ stability/reusability during biomass upgrading. Current challenges and opportunities for the future biorefineries as well as for the design of advanced functional solid catalysts are critically discussed. Describes catalysis as a promising technology for the development of eco-friendly and economically viable strategies for several important energy and environmental applications. Covers heterogeneous solid catalysts because of their versatile benefits in terms of catalysts’ synthesis, production cost, stability, and reusability as compared to homogeneous liquid catalysts. Provides promising strategies for the design of new catalytic materials, such as carbon materials, metal–organic frameworks, zeolites, and mesoporous silicas. Describes functional solid catalysts for developing one-pot cascade processes for efficient biomass valorization and other vital chemical transformations.

Book Description :

Biomass for Bioenergy and Biomaterials presents an overview of recent studies developed specifically for lignocellulose-based production of biofuels, biochemicals, and functional materials. The emphasis is on using sustainable chemistry and engineering to develop innovative materials and fuels for practical applications. Technological strategies for the physical processing or biological conversion of biomass for material production are also presented. FEATURES Offers a comprehensive view of biomass processing, biofuel production, life cycle assessment, techno-economic analysis, and biochemical and biomaterial production Presents details of innovative strategies to pretreat biomass Helps readers understand the underlying metabolic pathways and identify the best engineering strategies for their native strain Highlights different strategies to make biomaterials from biomass Provides insight into the potential economic viability of the biomass-based process This book serves as an ideal reference for academic researchers and engineers working with renewable natural materials, the biorefining of lignocellulose, and biofuels. It can also be used as a comprehensive reference source for university students in metabolic, chemical, and environmental engineering.

Book Description :

This book addresses the needs of students, researchers, as well as engineers and other professionals or readers interested in recent advances of biofuel and efficient waste management. In the context of energy consumption, over 85% of the total consumed energy comes from non-renewable fossil resources. Developing new renewable energy resources, especially biofuel production from wastes, has received increasing attention. The book is organized into three sections, namely Section I: Conventional waste management; Section II: From waste to green energy; and Section III: Case studies and future perspectives. Each section presents topic-specific chapters, which contain comprehensive and advanced knowledge of the subjects. Overall, the book covers the recent advances, breakthroughs, challenges, and future perspectives of waste-to-energy approach using different kinds of wastes as a feedstock for alternative biofuels and other integrated approaches such as wastewater treatment, plastic degradation, and CO2 sequestration in a cost-effective and eco-friendly way. In addition, different routes of waste recycling for enhanced biofuel production and case studies are presented with environmental and economic analysis. The presented case studies and future perspectives under Section III complement the chapters as they are authored by experts from bioenergy businesses who actually encounter real-world problems.

Book Description :

Recent Perspectives in Pyrolysis Research presents and discusses different routes of pyrolytic conversions. It contains exhaustive and comprehensive reports and studies of the use of pyrolysis for energy and materials production and waste management.

Book Description :

Biomass conversion into drop-in chemicals using novel heterogeneous bulk- and nano-scale catalysts is currently a hot research topic with the aim of replacing petrochemicals in the chemical industry. Considering the importance of this subject to the scientific community, Advanced Catalysis for Drop-in Chemicals provides the latest developments in the catalytic synthesis of drop-in chemicals mainly from lignocellulose, carbohydrates (cellulose, hemicellulose, C6 and C5 sugars, and their derivatives), lignin, and glycerol. The role of both heterogeneous bulk solid and nanostructured catalysts, along with their advantages and disadvantages for drop-in chemicals synthesis are critically summarized. Addressing the frontiers and prospects for using drop-in chemicals in place of petrochemicals in the chemical industry is also a key topic of this book. Describes fossil fuels, biomass, drop-in chemicals, catalysis, nano- and atomic-scale catalysts Includes pre- and post-treatment strategies for biomass upgrading Provides green catalytic processes for drop-in chemicals synthesis Outlines stabilization of nano- and atomic-scale catalysts Prospects atom-economy catalytic routes for drop-in chemicals synthesis Challenges using drop-in chemicals in place of petrochemicals in the chemical industry

Book Description :

Advanced Biofuel Technologies: Present Status, Challenges and Future Prospects deals with important issues such as feed stock availability, technology options, greenhouse gas reduction as seen by life cycle assessment studies, regulations and policies. This book provides readers complete information on the current state of developments in both thermochemical and biochemical processes for advanced biofuels production for the purpose of transportation, domestic and industrial applications. Chapters explore technological innovations in advanced biofuels produced from agricultural residues, algae, lipids and waste industrial gases to produce road transport fuels, biojet fuel and biogas. Covers technologies and processes of different types of biofuel production Outlines a selection of different types of renewable feedstocks for biofuel production Summarizes adequate and balanced coverage of thermochemical and biochemical methods of biomass conversion into biofuel Includes regulations, policies and lifecycle and techno-economic assessments

Book Description :

The use of solid catalysts for the upgrade of renewable sources gives the opportunity to combine the two main cores of green chemistry, that is, on the one hand, the set-up of sustainable processes and, on the other, the use of biomass-derived materials. Solid catalysts have taken on a leading role in traditional petrochemical processes and could represent a key tool in new biorefinery-driven technologies. This book will cover topics related to the preparation and use of heterogeneous catalytic systems for the transformation of renewable sources, as well as of materials deriving from agro-industrial wastes and by-products. At the same time, the ever-increasing importance of bioproducts, due to the acceptance and request of consumers, makes the upgrade of biomass into chemicals and materials not only an environmental issue, but also an economical advantage.

Book Description :

Biomass conversion into drop-in chemicals using novel heterogeneous bulk- and nano-scale catalysts is currently a hot research topic with the aim of replacing petrochemicals in the chemical industry. Considering the importance of this subject to the scientific community, Advanced Catalysis for Drop-in Chemicals provides the latest developments in the catalytic synthesis of drop-in chemicals mainly from lignocellulose, carbohydrates (cellulose, hemicellulose, C6 and C5 sugars, and their derivatives), lignin, and glycerol. The role of both heterogeneous bulk solid and nanostructured catalysts, along with their advantages and disadvantages for drop-in chemicals synthesis are critically summarized. Addressing the frontiers and prospects for using drop-in chemicals in place of petrochemicals in the chemical industry is also a key topic of this book. • Describes fossil fuels, biomass, drop-in chemicals, catalysis, and nano- and atomic-scale catalysts • Includes pre- and post-treatment strategies for biomass upgrading • Provides green catalytic processes for drop-in chemicals synthesis • Outlines stabilization of nano- and atomic-scale catalysts • Examines using drop-in chemicals in place of petrochemicals in the chemical industry

Book Description :

Nanotechnology for Advanced Biofuels: Fundamentals and Applications highlights emerging techniques for the formulation of fuels using nanotechnology and bio-based concepts. The addition of high-energy nanoparticles and biologically derived molecules in liquid fuel can increase the potential of energy-rich compounds. Key challenges in the production of nanotechnology-based fuels and their combustion or ignition during the operation are covered, along with the emission of oxidized particles and by-products of incomplete combustion and nano-fuels as an emerging field. The bio-based energy-rich fuels are largely diffused in conventionally used fuels. The addition of biofuels and nano-additives to pre-existing fuels can offer opportunities for developing modified fuels in domestic industries with the maximum usage of renewable biomass. This is an important reference source for materials scientists, energy scientists and chemical engineers who want to understand more about how nanotechnology can help create more efficient biofuels. Shows how nano-additives can significantly improve the properties and efficiency of biofuels Provides information to help readers better understand the basic and advanced applications of nano-additive-based biofuels Assesses the challenges of manufacturing nanotechnology-enhanced biofuels on an industrial scale

Book Description :

This book explores the most effective or promising catalytic processes for the conversion of biobased components into high added value products, as platform chemicals and intermediates.

Book Description :

This book is the outcome of contributions by many experts in the field from different disciplines, various backgrounds, and diverse expertise. This book provides information on biomass volume calculation methods and biomass valorization for energy production. The chapters presented in this book include original research and review articles. I hope the research presented in this book will help to advance the use of biomass for bioenergy production and valorization. The key features of the book are: Providing information on biomass volume estimation using direct, nondestructive and remote sensing methods Biomass valorization for energy using thermochemical (gasification and pyrolysis) and biochemical (fermentation) conversion processes.

Book Description :

In recent years, the replacement of non-renewable crude oil by renewable sources has been addressed, particularly in developed countries. Its main driving force has been the increasing demand and limited reserves of fossil fuels, the greenhouse gas effect, and the need of securing energy supplies. Advanced Solid Catalysts for Renewable Energy Production provides emerging research on renewable energy production, catalysts, and environmental effects of increased productivity. While highlighting the challenges for future generations to develop in the sustainable energy age, readers will learn the importance of new approaches not only for synthesizing more active and selective (nano)catalysts, but also, for designing innovative catalytic processes that can eventually meet the growing energy efficiency demand and overcome the environmental issues. This book is an important resource for academicians, university researchers, technology developers, and graduate level students.

Book Description :

A comprehensive, interdisciplinary picture of how lignocellulosic biorefineries could potentially employ lignin valorization technologies.

Book Description :

Biomass, Biofuels, Biochemicals: Recent Advances in Development of Platform Chemicals provides a detailed overview on the experimentally developed methods that facilitate platform chemicals derivation from biomass-based substrates with robust catalyst systems. In addition, the book highlights the green chemistry approach towards platform chemical production. Chapters discuss platform chemicals and global market volumes, the optimization of process schemes and reaction parameters with respect to achieving a high yield of targeted platform chemicals, such as sugars and furonic compounds by modifying the respective catalytic system, the influence of solvents on reaction selectivity and product distribution, and the long-term stability of employed catalysts. Overall, the objectives of the book are to provide the reader with an understanding of the societal importance of platform chemicals, an assessment of the techno-economic viability of biomass valorization processes, catalyst design for a specific reaction, and the design of a catalytic system. Covers recent developments on platform chemicals Provides comprehensive technological developments on specific platform chemicals Covers organic transformations, catalytic synthesis, thermal stability, reaction parameters and solvent effect Includes case studies on the production of a number of chemicals, such as Levulinic acid, glycerol, phenol derivatives, and more

Book Description :

Unconventional energy sources have gained and will continue to gain an increasing share of energy systems around the world. Today, hydrogen is recognized as a non-polluting energy carrier because it does not contribute to global warming if it is produced from renewable sources. Hydrogen is already part of today's chemical industry, but as an energy source, its rare advantages can only be obtained with the help of technologies. Currently, the fuel cell is considered the cleanest sustainable energy. With the development of fuel cells, hydrogen-based energy generation becomes a reality. Hydrogen Fuel Cell Technology for Stationary Applications is an essential publication that focuses on the advantages of hydrogen as a primary energy center and addresses its use in the sustainable future of stationary applications. While highlighting a broad range of topics including cost expectations, production methods, and social impact, this publication explores all aspects of the implementation and dissemination of fuel cell technology in the hope of establishing a sustainable marketplace for it. This book is ideally designed for fuel cell manufacturers, architects, electrical engineers, civil engineers, environmental engineers, advocates, manufacturers, mechanics, researchers, academicians, and students.

Book Description :

Biomass, Biofuels, Biochemical: Circular Bioeconomy: Current Developments and Future Outlook presents the views of experienced academicians and researchers working in the area of the circular bioeconomy. This book presents an assortment of Resource recovery, Waste Biorefineries, Bio-electrochemical systems, Biopolymers and Green solvents, Bio-adsorbents, and Technology transfer topics. Environmental engineers, biotechnologists, science graduates, chemical engineers, industrial experts and policymakers working in these areas will find the information on the circular economy and its important part in developing low carbon and resource-productive economies very informative. Methodologies and beneficial strategic approaches to address the usage of wastes from agriculture, co-products, and by-products are also discussed. Provides information on recent developments in technology transfer and global scenarios of circular bioeconomy as a single point of reference for any query regarding circular economies Covers information on the recovery of resources, waste biorefineries and bio-electrochemical systems, and product development surrounding the circular bioeconomy Includes information on the integration of processes and technologies for the production of biofuels and value-added products Presents strategic integrations of various techniques/bioprocess that are essential in establishing a circular biorefinery

Book Description :

The development of catalysts is the most sophisticated art in chemical sciences. It can be read like a story book when the critical scientific contents are presented in a chronological manner with short and simple sentences. This book will meets these criteria. To address the sustainability issues of existing chemical manufacturing processes or producing new chemicals, researchers are developing alternate catalysts to eliminate toxic chemicals use and by-products formation. Sustainable Catalytic Processes presents critical discussions of the progress of such catalytic development. This book of contemporary research results in sustainable catalysis area will benefit scientists in both industries and academia, and students to learn recent catalysts/process development. Reports the most recent developments in catalysis with a focus on environmentally friendly commercial processes, such as waste water treatment, alternate energy, etc Bridges the theory, necessary for the development of environmentally friendly processes, and their implementation through pilot plant and large scale Contains mainly laboratory scale data and encourages industrial scientists to test these processes on a pilot scale Includes work examples featuring the development of the new catalysts/processes using bio-renewable feedstock satisfactorily addressing environmental concerns Includes one chapter demonstrating real industrial examples motivating the industrial and academic researchers to pursue similar research

Book Description :

This book presents the most up-to-date technologies for the transformation of biomass into valuable fuels, chemicals, materials, and products. It provides comprehensive coverage of the characterization and fractionation of various types of biomass and details the many challenges that are currently encountered during this process. Divided into two sections, this book discusses timely topics such as the characterization of biomass feedstock, pretreatment and fractionation of biomass, and describes the process for conversion of biomass to value-added commodities. The authors bring biomass transformational strategies that are yet to be explored to the forefront, making this innovative book useful for graduate students and researchers in academia, government, and industry.

Book Description :

Heterogeneous catalysis plays a central role in the global energy paradigm, with practically all energy-related process relying on a catalyst at a certain point. The application of heterogeneous catalysts will be of paramount importance to achieve the transition towards low carbon and sustainable societies. This book provides an overview of the design, limitations and challenges of heterogeneous catalysts for energy applications. In an attempt to cover a broad spectrum of scenarios, the book considers traditional processes linked to fossil fuels such as reforming and hydrocracking, as well as catalysis for sustainable energy applications such as hydrogen production, photocatalysis, biomass upgrading and conversion of CO2 to clean fuels. Novel approaches in catalysts design are covered, including microchannel reactors and structured catalysts, catalytic membranes and ionic liquids. With contributions from leaders in the field, Heterogeneous Catalysis for Energy Applications will be an essential toolkit for chemists, physicists, chemical engineers and industrials working on energy.

Book Description :

Biochemicals and Materials Production from Sustainable Biomass Resources provides a detailed overview of the experimentally developed approaches and strategies that facilitate carbon-based materials and fine chemicals derivation from biomass feedstocks with robust catalyst systems and renewed conversion routes. In addition, the book highlights theoretical methods like techno-economic analysis of biobutanol synthesis. As academia and industry are now striving to substitute fossil-based chemicals with alternative renewable resources, second-generation lignocellulosic biomass which does not depend on the food cycle has become increasingly important. Lignocellulosic biomass is composed of three major polymeric components - lignin, cellulose and hemicellulose. The polymers can be degraded into monomeric counterparts through selective conversion routes like hydrolysis of cellulose to glucose and of hemicellulose to xylose. Includes the recent development of biomass-derived high-value chemicals and functional materials Describes theoretical and technical details of specific conversion routes and preparation methods Covers jointly organic transformations, catalytic synthesis, reaction mechanisms, thermal stability, reaction parameters and solvent effects