Author : Source Wikipedia,Books Llc
Publisher : Books LLC, Wiki Series
Release : 2010-09
ISBN : 9781155821535
Language : En, Es, Fr & De
Book Description :
Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Pages: 50. Chapters: Radical polymerization, Photoelectrochemical processes, Migratory insertion, Sigmatropic reaction, Solvent effects, Schikorr reaction, Electrophilic aromatic substitution, SN2 reaction, Arrow pushing, Oxidative addition, Elimination reaction, SN1 reaction, Electrocyclic reaction, Indenyl effect, Nucleophilic aromatic substitution, Reaction mechanism, Lindemann mechanism, Allylic rearrangement, Nucleophilic addition, Associative substitution, Electron transfer, Quenching, Cycloaddition, Ene reaction, Dissociative substitution, Autoacceleration, Pericyclic reaction, Radical-nucleophilic aromatic substitution, Nucleophilic acyl substitution, E1cB elimination reaction, Free radical addition, SNi, Walden inversion, ANRORC mechanism, Radical substitution, Electrophilic addition, Protonation, Deprotonation, 2,3-sigmatropic rearrangement, Catalytic cycle, NIH shift, Transmetalation, Sn1CB mechanism, Bartell mechanism, Green-Davies-Mingos rules, Metamorphic reaction, Ei mechanism, Chain disproportionation, Beta scission, Initiation. Excerpt: Free radical polymerization is a method of polymerization by which a polymer is formed from the successive addition of free radical building blocks. Free radicals can be formed via a number of different mechanisms usually involving separate initiator molecules. Following creation of free radical monomer units, polymer chains grow rapidly with successive addition of building blocks onto free radical sites. Free radical polymerization is a key synthesis route for obtaining a wide variety of different polymers and material composites. The relatively non-specific nature of free radical chemical interactions makes this one of the most versatile forms of polymerization available and allows facile reactions of polymeric free radical chain ends and other chemicals or substrates. In 2001, 40 bill...